Molecular characterization of dissolved organic matter associated with the Greenland ice sheet   总被引：1，自引：0，他引：1  

Maya P. Bhatia  Krista Longnecker  Elizabeth B. Kujawinski 《Geochimica et cosmochimica acta》2010,74(13):3768-9950

Subsurface microbial oxidation of overridden soils and vegetation beneath glaciers and ice sheets may affect global carbon budgets on glacial-interglacial timescales. The likelihood and magnitude of this process depends on the chemical nature and reactivity of the subglacial organic carbon stores. We examined the composition of carbon pools associated with different regions of the Greenland ice sheet (subglacial, supraglacial, proglacial) in order to elucidate the type of dissolved organic matter (DOM) present in the subglacial discharge over a melt season. Electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry coupled to multivariate statistics permitted unprecedented molecular level characterization of this material and revealed that carbon pools associated with discrete glacial regions are comprised of different compound classes. Specifically, a larger proportion of protein-like compounds were observed in the supraglacial samples and in the early melt season (spring) subglacial discharge. In contrast, the late melt season (summer) subglacial discharge contained a greater fraction of lignin-like and other material presumably derived from underlying vegetation and soil. These results suggest (1) that the majority of supraglacial DOM originates from autochthonous microbial processes on the ice sheet surface, (2) that the subglacial DOM contains allochthonous carbon derived from overridden soils and vegetation as well as autochthonous carbon derived from in situ microbial metabolism, and (3) that the relative contribution of allochthonous and autochthonous material in subglacial discharge varies during the melt season. These conclusions are consistent with the hypothesis that, given sufficient time (e.g., overwinter storage), resident subglacial microbial communities may oxidize terrestrial material beneath the Greenland ice sheet.  相似文献   

Homogeneity of water content in obsidian from the coso volcanic field: Implications for obsidian hydration dating     

Christopher M. Stevenson  Elizabeth Knaus  James J. Mazer  John K. Bates 《Geoarchaeology》1993,8(5):371-384

Users of the obsidian hydration dating method have routinely assumed that artifacts which originate from the same geological flow will be of the same chemical composition and thus hydrate at the same rate under equivalent conditions of temperature and relative humidity. Recent laboratory experimentation into the hydration process has shown that the intrinsic water content of the glass is the dominant factor in establishing the rate of hydration. Water content determinations on a large suite of samples from numerous prehistoric quarries within the Coso volcanic field, California, indicated that water content values, and thus hydration rate, varied significantly on a within flow basis. It is recommended that water determinations be made on individual artifacts prior to obsidian hydration dating. © 1993 John Wiley & Sons, Inc.  相似文献   

Petrologic and experimental evidence for the movement and heating of the pre-eruptive Minoan rhyodacite (Santorini, Greece)   总被引：1，自引：1，他引：0  

Elizabeth Cottrell  James E. Gardner  Malcolm J. Rutherford 《Contributions to Mineralogy and Petrology》1999,135(4):315-331

Hydrothermal experiments combined with petrologic observations form the basis for a new two-stage model for the evolution of the pre-eruption Minoan magma chamber at Santorini, Greece. Ninety-nine percent of the erupted volume is two-pyroxene, rhyodacitic magma that had been stored at a temperature of ∼885 °C, based on magnetite-ilmenite and QUILF geothermometry. The rest of the volume is basaltic to andesitic magma, which occurs as <10 cm scoria clasts and as small inclusions in rhyodacite pumices. Petrologic observations show that these magmas mixed at different scales and at different times (i.e., multiple batches of mafic magma). Hydrothermal experiments were carried out on samples of rhyodacite and a mafic scoria in order to determine magma storage conditions and the mixing history of the two magmas. At 885 °C, the rhyodacite must have been stored at water-saturated pressures of ∼50 MPa, based on its phase assemblage, matrix-glass composition, and crystal content. However, glass inclusions inside rhyodacitic plagioclase phenocrysts contain more than 6 wt% H₂O, indicating they formed at pressures >200 MPa. In addition, the composition of the plagioclase hosts (An_{56 ± 6}) of the inclusions require temperatures of 825 ± 25 °C at pressures >200 MPa. This demonstrates that the Minoan rhyodacitic magma underwent a two-stage evolution, first crystallizing at ∼825^∘C and >200 MPa, and then rinsing to a shallow ∼50 MPa storage region with a concomitant rise in temperature to ∼885 °C. We suggest that the episodic intrusion of mafic magmas provided the necessary heat and perhaps contributed to the ascent of the magma to shallow crustal depths where it reequilibrated before the cataclysmic eruption. Phase equilibria suggest that much of the heating of the rhyodacite occurred in the shallow storage region. Thermal budget calculations suggest that the rhyodacite magma could have been heated by intrusions of basalt rising at reasonable upwelling rates and injected into the storage zone over several hundred years. Preservation of amphibole in the mafic scoria indicate that injection of mafic magma continued up until days before the cataclysmic eruption, perhaps triggering the event. Received: 30 September 1997 / Accepted: 5 October 1998  相似文献   

Local vs. Regional Groundwater Flow Delineation from Stable Isotopes at Western North America Springs          下载免费PDF全文

Abraham E. Springer  Elizabeth M. Boldt  Katie M. Junghans 《Ground water》2017,55(1):100-109

The recharge location for many springs is unknown because they can be sourced from proximal, shallow, atmospheric sources or long‐traveled, deep, regional aquifers. The stable isotope (¹⁸O and ²H) geochemistry of springs water can provide cost‐effective indications of relative flow path distance without the expense of drilling boreholes, conducting geophysical studies, or building groundwater flow models. Locally sourced springs generally have an isotopic signature similar to local precipitation for that region and elevation. Springs with a very different isotopic composition than local meteoric inputs likely have non‐local recharge, representing a regional source. We tested this local vs. regional flow derived hypothesis with data from a new, large springs isotopic database from studies across Western North America in Arizona, Nevada, and Alberta. The combination of location‐specific precipitation data with stable isotopic groundwater data provides an effective method for flow path determination at springs. We found springs in Arizona issue from a mix of regional and local recharge sources. These springs have a weak elevation trend across 1588 m of elevation where higher elevation springs are only slightly more depleted than low elevation springs with a δ¹⁸O variation of 5.9‰. Springs sampled in Nevada showed a strong elevation‐isotope relationship with high‐elevation sites discharging depleted waters and lower elevation springs issuing enriched waters; only a 2.6‰ difference exists in ¹⁸O values over an elevation range of more than 1500 m. Alberta's springs are mostly sourced from local flow systems and show a moderate elevation trend of 1200 m, but the largest range in δ¹⁸O, 7.1‰.  相似文献   

Microplastic Contamination in Karst Groundwater Systems     

Samuel V. Panno  Walton R. Kelly  John Scott  Wei Zheng  Rachel E. McNeish  Nancy Holm  Timothy J. Hoellein  Elizabeth L. Baranski 《Ground water》2019,57(2):189-196

Groundwater in karst aquifers constitutes about 25% of drinking water sources globally. Karst aquifers are open systems, susceptible to contamination by surface-borne pollutants. In this study, springs and wells from two karst aquifers in Illinois, USA, were found to contain microplastics and other anthropogenic contaminants. All microplastics were fibers, with a maximum concentration of 15.2 particles/L. The presence of microplastic was consistent with other parameters, including phosphate, chloride and triclosan, suggesting septic effluent as a source. More studies are needed on microplastic sources, abundance, and impacts on karst ecosystems.  相似文献   

Finite element analysis of the seismic response of ancient columns     

Konstantinos Papadopoulos  Elizabeth Vintzileou  Ioannis N. Psycharis 《地震工程与结构动力学》2019,48(13):1432-1450

This paper presents a numerical study of the response to earthquake actions of eight ancient Greek multidrum columns, which were chosen as representative of a broad spectrum of the ancient columns preserved to date. The study was conducted using the FE software Abaqus, in three steps. At first, the software efficiency to predict the rocking response of dry-stone structures was verified. Afterwards, various numerical models of one typical ancient multidrum column were seismically excited. Records of four real earthquakes differing in frequency content were used for the excitation of the models. Each column model was different from the others at least in one geometric or modeling parameter. Although the examined parameters affected the numerical results, their variation did not alter significantly the overall behavior of the column. In the last step of the study, numerical models of eight columns were seismically excited using four seismic records. In these analyses, among the simulation approaches tested in the second step, the simpler one was adopted. On the basis of the numerical results, conclusions were drawn regarding the seismic resistance of the columns and its correlation with the dynamic characteristics of the columns (size, slenderness, and frequency parameter) and with the basic intensity measures and frequency content indicator of the seismic motions (PHA, PHV, PHD, and T_g). Thus, criteria of seismic collapse for the multidrum columns are proposed, which can be used for the approximate assessment of the seismic vulnerability of free-standing ancient columns, provided that the columns are in good preservation state.  相似文献   

Soil management in pre‐Hispanic raised field systems: Micromorphological evidence from Hacienda Zuleta,Ecuador     

Clare Wilson  Ian A. Simpson  Elizabeth J. Currie 《Geoarchaeology》2002,17(3):261-283

Soils‐based evidence derived from thin section micromorphology is used to explore contrasts in pre‐Hispanic and Hispanic arable land management practices associated with raised fields in an inter‐Andean valley of Ecuador. Differences in textural pedofeature characteristics suggest that, where they are found in the same locality, camellón systems were more intensively manured and cultivated than wachu systems. Both, however, were more intensively managed than traditional Hispanic arable fields. The importance of the camellón in pre‐Hispanic agriculture is emphasized by soils‐based evidence that highlights the efforts made to clear these fields of volcanic ash after the Quilotoa eruption of ca. A.D. 1280. This research suggests that, in an andosol context, pre‐Hispanic and Hispanic arable land management practices leave relict and fossil soil micromorphology features that can be used to interpret land use intensities. © 2002 Wiley Periodicals, Inc.  相似文献   

Study of X-ray transients with Scanning Sky Monitor (SSM) onboard AstroSat     

M. C. Ramadevi  B. T. Ravishankar  Abhilash R. Sarwade  S. Vaishali  Nirmal Kumar Iyer  Anuj Nandi  V. Girish  Vivek Kumar Agarwal  Blessy Elizabeth Baby  Mohammed Hasan  S. Seetha  Dipankar Bhattacharya 《Journal of Astrophysics and Astronomy》2018,39(1):11

Scanning Sky Monitor (SSM) onboard AstroSat is an X-ray sky monitor in the energy range 2.5–10 keV. SSM scans the sky for X-ray transient sources in this energy range of interest. If an X-ray transient source is detected in outburst by SSM, the information will be provided to the astronomical community for follow-up observations to do a detailed study of the source in various other bands. SSM instrument, since its power-ON in orbit, has observed a number of X-ray sources. This paper discusses observations of few X-ray transients by SSM. The flux reported by SSM for few sources during its Performance Verification phase (PV phase) is studied and the results are discussed.  相似文献   

Reproductive biology of the leatherjacket,Meuschenia scaber (Monacanthidae) (Forster 1801) in the Hauraki Gulf,New Zealand     

Valerio Visconti  Elizabeth D. L. Trip  Marc H. Griffiths  Kendall D. Clements 《新西兰海洋与淡水研究杂志》2018,52(1):82-99

The leatherjacket Meuschenia scaber is widely distributed in Australasian waters, and is a valued bycatch of inshore bottom trawl fisheries although little is known of its life history. Here, we describe the reproductive biology of the species based on 651 leatherjackets sampled in the Hauraki Gulf, New Zealand, between July 2014 and March 2016. The maximum total length (L_T) recorded for females and males were 320 and 315?mm, respectively, with both sexes present in all size classes. Monthly analysis of gonad condition revealed a clear spawning season from late austral winter to early summer (August–December), and histological analysis of the ovaries revealed that M. scaber is an indeterminate serial spawning gonochorist. The estimated sizes at sexual maturity (L₅₀) for females (189.9?mm L_T) and males (188.4?mm L_T) did not differ significantly. Relatively small testes, sexual dimorphism and underwater observation of nesting suggest that M. scaber is a paired spawner.  相似文献   

Distribution of diffuse flow megafauna in two sites on the Eastern Lau Spreading Center, Tonga     

Elizabeth L. Podowski  Tom S. Moore  Kevin A. Zelnio  George W. Luther III  Charles R. Fisher 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2041-2056

Hydrothermal vent environments are characterized by large gradients of toxic chemicals and high temperatures, which play a significant role in defining species’ distributions. We used high-resolution imagery and spatially explicit in-situ physico-chemical measurements analyzed within a Geographic Information System (GIS) in order to characterize the spatial relations among different groups of megafauna, temperature, and chemistry within two discrete vent communities (40 and 50 m²) on the Eastern Lau Spreading Center (ELSC). Chemical (sulfide and O₂ concentrations) and temperature data were obtained from approximately 75 different locations within each community using in-situ instruments. All data were integrated into a GIS, which served as a visualization tool and enabled the data to be analyzed in a spatial context. Our results confirm the importance of abiotic variables in defining the distributions of some fauna and elucidate several biological associations that are consistent between the two communities. The provannid snail, Alviniconcha spp., appears to actively avoid temperatures above 32–46 °C and/or sulfide concentrations exceeding approximately 260 μM. Slightly higher average sulfide concentrations and temperatures were measured among aggregations of Ifremeria nautilei compared to aggregations of the mussel Bathymodiolus brevior; however, the presence of mixed aggregations of the two species indicates an overlap in requirements. The brachyuran crab, Austinograea spp., was consistently observed directly on symbiont-containing species, particularly Alviniconcha spp. The solitary snail, Eosipho desbruyeresi, was rarely observed on biological substrata, but was often (60% of its population at the most active site) within 5 cm of symbiont-containing fauna, indicating a tolerance and preference for proximity to areas of high productivity. Densities and coverage of species differed substantially between the two communities despite high species overlap. Symbiont-containing species covered much larger areas at the more hydrothermally active site, ABE1, while shrimp and anemones occurred in relatively higher densities within the less-active site, TM1. This is the first study to thoroughly characterize realized distributions of megafauna at vent sites along the ELSC.  相似文献