Geological evolution of Mount Etna volcano (Italy) from earliest products until the first central volcanism (between 500 and 100 ka ago) inferred from geochronological and stratigraphic data     

Stefano Branca  Mauro Coltelli  Emanuela De Beni  Jan Wijbrans 《International Journal of Earth Sciences》2009,98(1):239-239

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Chemical and structural study of 1M- and 2M 1-phlogopites coexisting in the same Kasenyi kamafugitic rock (SW Uganda)     

Maria Lacalamita  Ernesto Mesto  Fernando Scordari  Emanuela Schingaro 《Physics and Chemistry of Minerals》2012,39(8):601-611

In the present work, crystal chemical variations between 1M and 2M ₁ phlogopites coexisting in the same rock sample from kamafugite of Kasenyi (southwest Uganda, west branch of the East African Rift) were explored by electron probe microanalyses, single crystal X-ray diffraction and M?ssbauer spectroscopy. Chemical analyses revealed close similarity both within and between the two polytypic arrangements as well as high TiO₂ (~4.9?wt%) and Al₂O₃ (~12.9?wt%), and low Cr₂O₃ (~0.8?wt%), F (~0.3?wt%) and BaO (~0.2?wt%) contents. Room temperature ⁵⁷Fe M?ssbauer investigation proved that the studied mica is a tetraferriphlogopite with: ^IVFe³⁺?=?19(1)?%, ^VIFe²⁺?=?58(1)?%, ^VIFe³⁺?=?23(1)?%. Single crystal refinement showed that both polytypes have narrow range of variation in terms of some relevant unit cell parameters and similar values in terms of mean bond lengths, mean atomic numbers and distortion parameters. Similar substitutions were active in the structure of the 1M and 2M ₁ studied phlogopites. However, in 2M ₁ polytypes the oxy-type substitutions were found to occur to a greater extent. Comparison of unit layer of 1M mica (in the 2M ₁ setting) with that of the 2M ₁ ones showed that the 2M ₁ polytypes are affected to different extent by relative shifts of the upper and lower triads of octahedral oxygens along the ±b directions. This effect did not cause any symmetry lowering in the T-O-T layer of the studied samples.  相似文献   

Impact of ocean acidification on the carbonate sediment budget of a temperate mixed beach     

Simone Simeone  Emanuela Molinaroli  Alessandro Conforti  Giovanni De Falco 《Climatic change》2018,150(3-4):227-242

The production of sediments by carbonate-producing ecosystems is an important input for beach sediment budgets in coastal areas where no terrigenous input occurs. Calcifying organisms are a major source of bioclastic carbonate sediment for coastal systems. Increased levels of CO₂ in the atmosphere are leading to an increase in the partial pressure of CO₂ on ocean seawater, causing ocean acidification (OA), with direct consequences for the pH of ocean waters. Most studies of OA focus on its impact on marine ecosystems. The impact of OA on carbonate-producing ecosystems could be to reduce the amount of sediments supplied to temperate coastal systems. The aim of this study was to quantify the effect of the predicted OA on the long-term sediment budget of a temperate Mediterranean mixed carbonate beach and dune system. Based on projections of OA we estimated a fall of about 31% in the present bioclastic carbonate sediment deposition rate, with the biggest decreases seen in the dunes (? 46%). OA is also expected to affect the carbonate sediment reservoirs, increasing the dissolution of CaCO₃and causing net sediment loss from the system (~ 50,000 t century^?1). In the long-term, OA could also play a primary role in the response of these systems to sea-level rise. Indeed, the reduction in the quantity of carbonate sediments provided to the system may affect the speed with which the system is able to adapt to sea-level rise, by increasing wave run-up, and may promote erosion of dunes and subaerial beaches.  相似文献   

Red micas from basal ignimbrites of Mt. Vulture (Italy): interlayer content appraisal by a multi-methodic approach     

Fernando Scordari  Emanuela Schingaro  Gennaro Ventruti  Maria Lacalamita  Luisa Ottolini 《Physics and Chemistry of Minerals》2008,35(3):163-174

The crystal chemistry of red phlogopites from Mt. Vulture (Italy) ignimbrites has been studied by electron microprobe, secondary ion mass spectrometry (SIMS), single crystal structural investigation and Fourier transform infrared (FTIR) spectroscopy. The analysed phlogopite has Fe/(Fe + Mg) ∼ 0.35, TiO₂ (wt%): 2.8–5.0 and H₂O (wt%): 1.24–3.37. Infrared spectra revealed the presence of bands due to the NH₄⁺ and H₂O stretching and bending vibrations. The samples belong to the 1M polytype. The bimodal behaviour of several structural parameters allows red micas to be clustered into two distinct groups: K⁺ ↔ NH₄⁺, H₂O and M³⁺-vacancy substitutions dominate in the first group; M^3+,4+-oxy, in the second group. It has to be pointed out that quantitative analysis of hydrogen (via SIMS) together with the characterization of the local environment of the anionic site (via FTIR) are fundamental in assessing the correct structural formula and the substitution mechanisms in micas. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Hypothesis testing methods to detect spoofing attacks: a test against the TEXBAT datasets     

Troglia Gamba  Micaela  Truong  Minh Duc  Motella  Beatrice  Falletti  Emanuela  Ta  Tung Hai 《GPS Solutions》2017,21(2):577-589

GPS Solutions - The hazardous effects of spoofing attacks on the global navigation satellite system (GNSS) receiver are well known. Technologies and algorithms to increase the awareness of GNSS...  相似文献   

Dramatic decrease of pelagic carbonate production by nannoplankton across the Early Toarcian anoxic event (T-OAE)     

Emanuela Mattioli  Bernard Pittet  Laurent Petitpierre  Samuel Mailliot 《Global and Planetary Change》2009,65(3-4):134-145

In this account we present estimates of nannofossil fluxes in four sections and one borehole all belonging to the Early Jurassic western Tethys. This study aims to map the distribution of pelagic carbonate production across the Early Toarcian anoxic event (T-OAE), and to understand which environmental parameters did control such production. Our results indicate important changes in carbonate production by nannoplankton occurring within the western Tethys and its variations through time. Nannofossil fluxes (specimens per m² per year) are extremely low during the T-OAE in all the studied settings. Higher fluxes are encountered in the westernmost part of the Tethys Ocean before the T-OAE, whilst pelagic carbonate production shifted towards the northern margin of the Tethys after the recovery from anoxic conditions. The dramatic decrease in nannoplankton production during the T-OAE has been interpreted in previous works as a biocalcification crisis related to high pCO₂ in the atmosphere/hydrosphere system. Although a high pCO₂ may have lowered the carbonate saturation state of Early Jurassic oceans and finally hampered biocalcification, we speculate that the most important effects of CO₂ increase were indirect, and affected pelagic producers via changes on climate and sea-level. Namely, it seems that precipitation/evaporation budgets and continental runoff that controlled nutrient levels and salinity in surface oceanic waters were important factors for pelagic biocalcifiers.  相似文献   

Stream-scanning laser system, electric sensing counter and settling grain size analysis: a comparison using reference materials and marine sediments     

Emanuela Molinaroli  Giovanni De Falco  Sandro Rabitti  Rosana Asunta Portaro 《Sedimentary Geology》2000,130(3-4):269-281

Surface and deep-sea core sediments and two sets of standards were measured by three different techniques — Galai Cis-1 laser system, Coulter Counter TA II, and Micromeritics SediGraph 5000D — in order to compare the Galai results with the other two. The differences between the three types of measuring device turned out to be greater in sediments than in standards, and were attributed to the physical properties, shape, density and composition of the particles (complexity of the matrix). Comparison of moment statistics showed that the Galai determines coarser grain sizes than the Coulter and finer than the SediGraph, particularly as regards analysis of surface sediments. The relationships between Galai and SediGraph were estimated using analysis of variation/residuals within individual intervals. The analysis showed a higher variability of residuals for the coarser fractions (8–16 μm and 16–32 μm) with respect to the finer (2–4 μm and 4–8 μm) fractions. The <2 μm SediGraph fraction, with a cut-off at 0.49 μm, showed good correspondence with the <2.5 μm Galai analysis.  相似文献   

Deriving Star Formation Histories: Evolutionary or Population Synthesis Codes versus Color-Magnitude Diagrams     

Danielle Alloin  Carme Gallart  Emmanuel Fleurence  Emanuela Pompei  Daniel Raimann  Uta Fritze- Von Alvensleben  Sukyoung Yi 《Astrophysics and Space Science》2002,281(1-2):109-113

The goal of this project is to analyze the integrated-light spectrum of a region in the LMC bar, for which HST images are already available yielding color-magnitude diagrams reaching the oldest main-sequence turnoff. Then, we can derive the star formation history in this field through evolutionary/population synthesis of the integrated light from 330 to 990 nm by a variety of independent methods and compare the results with the - in principle - more reliable results derived from the analysis of the color-magnitude diagram (CMD). This confrontation is the key ‘truth-test’ needed for the understanding of the abilities and the limitations of the evolutionary/population synthesis methods that must be applied of necessity to unresolved nearby and far-away galaxies. We report here on the observational part of the project. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Variation of paleo-productivity and terrigenous input in the Eastern Arabian Sea during the past 100 ka     

Ahmad Mir Ishfaq  J. N. Pattan  V. M. Matta  V. K. Banakar 《Journal of the Geological Society of India》2013,81(5):647-654

A 4.1 m long sediment core from the Eastern Arabian Sea (EAS) is studied using multiple geochemical proxies to understand the variation of productivity and terrigenous matter supply during the past 100 ka. The temporal variation in element concentration and fluxes of CaCO₃, organic carbon (C_org) and Barium excess (Ba_exc), together, in general indicate a higher productivity during the cold climate and highest during the Last Glacial Maximum (LGM) in particular. This cold climate-increased productivity coupling may be attributed to the shoaling of nutricline due to enhanced convective mixing resulting from the intensified winter monsoon. Increased linear sedimentation rates and fluxes of Al, Fe, Mg, Ti, Cr, Cu, Zn, and V during the cold period also suggest increased input of terrigenous matter supporting intensified winter winds. However, the presence of large abundance of structurally unsupported elemental content (e.g.: Mg-86%, Fe-82% and Al-53%) indicate increased input of terrigenous material which was probably enhanced due to intense winter monsoon.  相似文献   

Inverse analysis of stochastic moment equations for transient flow in randomly heterogeneous media     

Monica Riva  Alberto Guadagnini  Shlomo P. Neuman  Emanuela Bianchi Janetti  Bwalya Malama 《Advances in water resources》2009

We present a nonlinear stochastic inverse algorithm that allows conditioning estimates of transient hydraulic heads, fluxes and their associated uncertainty on information about hydraulic conductivity (K) and hydraulic head (h  ) data collected in a randomly heterogeneous confined aquifer. Our algorithm is based on Laplace-transformed recursive finite-element approximations of exact nonlocal first and second conditional stochastic moment equations of transient flow. It makes it possible to estimate jointly spatial variations in natural log-conductivity (Y=lnK)$(Y=\ln K)$, the parameters of its underlying variogram, and the variance–covariance of these estimates. Log-conductivity is parameterized geostatistically based on measured values at discrete locations and unknown values at discrete “pilot points”. Whereas prior values of Y at pilot point are obtained by generalized kriging, posterior estimates at pilot points are obtained through a maximum likelihood fit of computed and measured transient heads. These posterior estimates are then projected onto the computational grid by kriging. Optionally, the maximum likelihood function may include a regularization term reflecting prior information about Y. The relative weight assigned to this term is evaluated separately from other model parameters to avoid bias and instability. We illustrate and explore our algorithm by means of a synthetic example involving a pumping well. We find that whereas Y and h can be reproduced quite well with parameters estimated on the basis of zero-order mean flow equations, all model quality criteria identify the second-order results as being superior to zero-order results. Identifying the weight of the regularization term and variogram parameters can be done with much lesser ambiguity based on second- than on zero-order results. A second-order model is required to compute predictive error variances of hydraulic head (and flux) a posteriori. Conditioning the inversion jointly on conductivity and hydraulic head data results in lesser predictive uncertainty than conditioning on conductivity or head data alone.  相似文献