Heavy metal pollution is common in rivers in the vicinity of mining areas. In these polluted environments, the survival of alien species with a high tolerance to metals may be favored. The Tinto River (Southwest Iberian Peninsula) is an excellent natural laboratory for the study of plants’ responses to acidic and metal polluted sediments. This work analyzes the tolerance of the alien species Spartina densiflora to low pH and high metal loads in the Tinto River. The main aim of this study was to determine if this alien species can invade landward along the banks of the Tinto River. S. densiflora seeds were able to germinate in heavy metal polluted aerobic sediments even at pH 2. However, these conditions decreased S. densiflora final germination, altered germination dynamics, decreased aerial and subterranean growth rates, and prevented its establishment. 相似文献
Trace and rare earth element contents were determined by SIMS technique in clinopyroxene and mica crystals from minette lamprophyric enclaves in a potassic syenite host. This co-mingled system was crystallized at high pressures, which varied about 3–5 GPa, as indicated by the presence of K-clinopyroxenes and pyrope-rich garnet with measurable amounts of K2O and Na2O, among the near-liquidus phases. Major and trace element composition of these lamprophyric enclaves is quite similar to those observed in silica-rich lamproites, suggesting that similar sources were involved in their origin. In a general view, the concentrations of most trace and rare earth elements in clinopyroxene of the studied enclaves are higher than those referred to by other authors. Clinopyroxene/melt partition coefficient for most trace elements are close to determinations in alkali-basalts and lamproites from Leucite Hills, with considerable differences relative to Gaussberg lamproites. Furthermore, these partition data are completely different from those determined for potassic lavas crystallized under crustal pressures. Spidergrams for clinopyroxenes exhibit negative-Sr anomalies relative to LREE, which have been associated by most authors to crystallization under low-pressures, out of garnet stability field. The presence of pyrope together with K-clinopyroxene excludes such hypotheses for the studied enclaves. Y and HREE are concentrated in clinopyroxene, whilst the other trace elements have Kd<1. LIL elements, except Rb, have incompatible (Kd<1) behavior in phlogopite. The high partition coefficient for Nb (Kd>3) determined in the studied phlogopite is unusual in lamproites, lamprophyres, and basalts, but frequently observed in phlogopite from metasomatic mantle samples, as well as in acid magmas. This partition value may indicate the lack of other mineral phase with high partition for this element during crystallization, and may be enhanced by the liquid composition progressively closer to alkali feldspar, an unsuitable structure for six-coordinated cations. Ce/Yb, Rb/Sr, and Zr/Hf ratios in clinopyroxene and mica suggest that the minettic magma could produce the host Piquiri potassic syenite by fractional crystallization. This hypothesis is not consistent with Ba concentrations in clinopyroxene and mica, which suggest that a Ba-bearing phase (e.g. alkali feldspar) should be among the fractionated phases in order to produce the potassic syenites. 相似文献
The lichen Evernia prunastri has been employed for biomonitoring the atmospheric deposition of heavy metals at urban, rural and industrial sites in Central Italy. Lichen samples have been collected in a control site 1500 m a. s. l. (Parco Nazionale dAbruzzo, Central Italy) and subsequently transplanted at urban site (Cassino city center), at rural location 7 km away from Cassino (S. Elia Fiumerapido) and at industrial location (Piedimonte S. Germano) surrounding an automobile factory. Once defined the surface of impact relevant to this work, the lichen samples were transplanted at the four cardinal points of each site. Studies of bioaccumulation of Pb, Cd, Cr, Cu and Zn in lichen samples were performed five times at regular intervals between November 2000–December 2001. Microwave digestion of the samples and graphite furnace atomic absorption spectrometry were employed for the heavy metal determinations. Suitable certified reference materials (CRM) were used for validation of the analytical methodology. Results showed the ability of Evernia prunastri to accumulate the heavy metals under study. As expected, the area chosen as control site showed significantly (Friedman test, cluster analysis) lower impact in comparison to the other sites and the rural site showed smaller impact than the urban and the industrial sites. 相似文献
By solving a Wheeler-De Witt ‘extended’ equation in the Brans-Dicke theory, we have found that the probability distribution
predicts: i) An initial value for the Brans-Dicke scalar field φ ∼ ρ1/2_VAC in the beginning of the inflation, where ρVAC is the vacuum density energy (this gives a planck mass ∼ ρ1/4_VAC) ii) Large values for the Brans-Dicke parameter w. On the other hand it is shown that by taking into account the dynamical
behaviour of φ and the matter scalar field σ we can formulate a ‘creation boundary condition’ where in the ‘beginning’ of
the Universe (R =0, ‘nothing’ for some authors) we have a dynamical σ already ‘created’. This could be the energetic mechanism
which makes Universe tunnels the potential barrier to evolve classically after. Besides we have found the possibility of a
cosmological uncertainty principle.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
Excess 210Pb in a core from a Mexican Coastal Lagoon, which has no connection with the sea shows a small but measurable decay over the length of the core, when different approaches were compared (excess and corrected 210Pb activity with depth, total and inorganic cumulative weights) significant differences in the values for the sedimentation rate are obtained. The best coefficient correlation was calculated when corrected 210Pb activity for the uneven distribution of organic matter and cumulative inorganic weight is considered (, R = ?0·86; ω = 0·51 cm yr?1 for the top 13 cm, R = ?0·90 and 1·52 cm yr?1 for the interval 14–46 with R = ?0·96).Time frames in the sedimentary column were in agreement between the 210Pb calculated time and the appearance of shells fragments probably associated with the disturbances caused by the 1961 hurricane Tara.The surface accumulation rate is equivalent to a mean deposition of 262·5 g m?2 yr?1 or organic matter which is minor but comparable to some salt marshes of United States. 相似文献
A numerical technique called Summary Representation was used to solve the problem of seepage through a leaky sheetpile; this particular method was selected owing to its accuracy and computational speed. Seepage parameters were evaluated quantitatively and the influence of the leakiness of sheetpiles in a porous medium underlain by an impervious horizontal stratum was determined. The case of a single sheetpile was first considered, and the effect of the depth of penetration and coefficient of leakiness on the total rate of flow and on the values of the exit gradient was analysed. Next, the flow under an impervious dam was considered to assess the accuracy of the method. Finally, the case of seepage under a dam with leaky sheetpiles at both ends was studied, including the effect of the leaky sheetpiles on the uplift pressure acting along the foundation of the dam. Patterns of seepage through the flow line deformation that is caused by the leakiness of the sheetpiles. 相似文献
We determine seismic strain rate of tectonic earthquakes along the Central America Volcanic Arc. We then compare this result to those obtained from earthquakes related to the convergence of the Cocos and Caribbean plates and to earthquakes in the back-arc region of northern Central America.
The seismic strain-rate tensor for shallow-focus earthquakes along the Central America volcanic arc since 1700, has a compressive eigenvector with a magnitude of 0.7 × 10−8 year−1, and oriented in a 357° azimuth. The extensive eigenvector is oriented in a 86° azimuth, with a magnitude of 0.82 × 10−8 year−1. When only Centroid Moment-tensor solutions (CMT) are considered, the respective eigenvectors are 1.2 × 10−8 year−1 and 1.0 × 10−8 year−1.
The compressive eigenvector from the seismic strain-rate tensor for earthquakes along the Cocos-Caribbean convergent margin is 2.0 × 10−8 year−1, plunging at 25°, and oriented in a 29° azimuth. Its magnitude and direction are similar to those of the compressive eigenvector for earthquakes along the volcanic arc. The extensive eigenvector along the convergent margin, on the other hand, has a large vertical component. The compressive and extensive eigevenvectors are 4.9 × 10−8 year−1 and 4.6 × 10−8 year−1, using only CMTs as the database.
Earthquakes along the grabens of northern Central America yield a seismic strain-rate tensor whose extensive eigenvector has a magnitude of 2.4 × 10−8 year−1, oriented in a 109° azimuth. Magnitude and direction are similar to those of the extensive eigenvector for earthquakes along the volcanic arc. The compressive eigenvector along the grabens is practically vertical.
Similarities in magnitudes and directions for compressive and extensive eigenvectors suggest to us that the strain field along the Central America volcanic arc is the result of compression along the convergent Cocos-Caribbean margin, and extension in the back-arc region, along the grabens of northern Central America. This field is resolved as strike-slip faulting along the arc. 相似文献