Measurement of isoprene and its atmospheric oxidation products in a central Pennsylvania deciduous forest     

Randal S. Martin  Hal Westberg  Eugene Allwine  Lynne Ashman  J. Carl Farmer  Brian Lamb 《Journal of Atmospheric Chemistry》1991,13(1):1-32

Ambient concentrations of isoprene and several of its atmospheric oxidation productsmethacrolein, methylvinyl ketone, formaldehyde, formic acid, acetic acid, and pyruvic acid-were measured in a central Pennsylvania deciduous forest during the summer of 1988. Isoprene concentrations ranged from near zero at night to levels in excess of 30 ppbv during daylight hours. During fair weather periods, midday isoprene levels normally fell in the 5–10 ppbv range. Methacrolein and methylvinyl ketone levels ranged from less than 0.5 ppbv to greater than 3 ppbv with average midday concentrations in the 1 to 2 ppbv range. The diurnal behavior of formaldehyde paralleled that of isoprene with ambient concentrations lowest (1 ppbv) in the predawn hours and highest (>9.0 ppbv) during the afternoon. The organic acids peaked during the midday period with average ambient concentration of 2.5, 2.0, and 0.05 ppbv for formic, acetic, and pyruvic acid, respectively. These data indicate that oxygenated organics comprise a large fraction of the total volatile organic carbon containing species present in rural, forested regions of the eastern United States. Consequently, these compounds need to be included in photochemical models that attempt to simulate oxidant behavior and/or atmospheric acidity in these forested regions.  相似文献   

Eruptive probability calculation for the Yucca Mountain site,USA: statistical estimation of recurrence rates     

Chih-Hsiang Ho  Eugene I Smith  Daniel L Feuerbach  Terry R Naumann 《Bulletin of Volcanology》1991,54(1):50-56

Investigations are currently underway to evaluate the impact of potentially adverse conditions (e.g. volcanism, faulting, seismicity) on the waste-isolation capability of the proposed nuclear waste repository at Yucca Mountain, Nevada, USA. This paper is the first in a series that will examine the probability of disruption of the Yucca Mountain site by volcanic eruption. In it, we discuss three estimating techniques for determining the recurrence rate of volcanic eruption (), an important parameter in the Poisson probability model. The first method is based on the number of events occurring over a certain observation period, the second is based on repose times, and the final is based on magma volume. All three require knowledge of the total number of eruptions in the Yucca Mountain area during the observation period (E). Following this discussion we then propose an estimate of E which takes into account the possibility of polygenetic and polycyclic volcanism at all the volcanic centers near the Yucca Mountain site.Paper financed by the Nuclear Waste Project Office, State of Nevada, USA  相似文献   

Antarctic ecosystem monitoring: quantifying the response of ecosystem indicators to variability in Antarctic krill   总被引：3，自引：0，他引：3  

Reid  Keith; Croxall  John P.; Briggs  Dirk R.; Murphy  Eugene J. 《ICES Journal of Marine Science》2005,62(3):366-373

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A three-dimensional wake impingement model and applications on tandem oscillating foils     

Moqin He  Brain Veitch  Neil Bose  Bruce Colbourne  Pengfei Liu 《Ocean Engineering》2007,34(8-9):1197-1210

Potential flow based vortex numerical methods have been widely used in aerodynamics and hydrodynamics. In these methods, vortices shed from lifting bodies are traced by using vortex filaments or dipole panels. When the wake elements encounter a downstream body, such as a rudder behind a propeller or a stator behind a rotor, a treatment is necessary to divert the wake elements to pass by the body. This treatment is vital to make wake simulations realistic and to satisfy the non-penetration condition during wake body interaction. It also helps to avoid pure numerical disturbances such as when a vortex filament or an edge of a dipole panel passes through the collection point of a body element; this is a singularity for induced velocity and it will introduce a large numerical disturbance. This necessary treatment for three-dimensional problems with geometrical complexity has not been found to date. In this study, a wake impingement model was developed to divert wake elements to slip over the body surface, model the vortex/body interaction, and predict forces on fluctuating components. The model was also tested on configurations of oscillating foils in tandem with an existing panel method code. Simulation results with the wake impingement model are shown to be in closer agreement with limited published experimental data than those without the model. With the established wake impingement model, force fluctuations on the after body due to the wake vortex impingement were investigated based on a series of simulations. The series varied several parameters including distance between two foils, oscillating frequency, span, rear foil pitch angle, swap angle and vertical position.  相似文献   

Recent volumetric changes in salt marsh soils     

R. Eugene Turner  Charles S. Milan  Erick M. Swenson 《Estuarine, Coastal and Shelf Science》2006,69(3-4):352

Salt marsh sediment volume decreases from organic decomposition, compaction of solids, and de-watering, and each of these processes may change with age. Variability in the vertical accretion rate within the upper 2 m was determined by assembling results from concurrent application of the ¹³⁷Cs and ²¹⁰Pb dating techniques used to estimate sediment age since 1963/1964, and 0 to ca 100+ years before present (yBP), respectively. The relationship between ²¹⁰Pb and the ¹³⁷Cs dated accretion rates (Sed₂₁₀ and Sed₁₃₇, respectively) was linear for 45 salt marsh and mangrove environments. Sed₂₁₀ averaged 75% of Sed₁₃₇ suggesting that vertical accretion over the last 100+ years is driven by soil organic matter accumulation, as shown for the pre ¹³⁷Cs dated horizon. The ratio of Sed₂₁₀/Sed₁₃₇ declines with increasing mineral content. A linear multiple regression equation that includes bulk density and Sed₁₃₇ to predict Sed₂₁₀ described 97% of the variance in Sed₂₁₀. Sediments from Connecticut, Delaware and Louisiana coastal environments dated with ¹⁴C indicate a relatively constant sediment accretion rate of 0.13 cm year⁻¹ for 1000–7000 yBP, which occurs within 2 m of today's marsh surface and equals modern sea level rise rates. Soil subsidence is not shown to be distinctly different in these vastly different coastal settings. The major reason why the Sed₁₃₇ measurements indicate higher accretion rates than do the Sed₂₁₀ measurements is because the former apply to younger sediments where the effects of root growth and decomposition are greater than in the latter. The most intense rates of change in soil volume in organic-rich salt marshes sediments is, therefore, neither in deep or old sediments (>4 m; >1000 years), but within the first several hundreds of years after accumulation. The average changes in organic and inorganic constituents downcore are nearly equal for 58 dated sediment cores from the northern Gulf of Mexico. These parallel changes downcore are best described as resulting from compaction, rather than from organic matter decomposition. Thus most of the volumetric changes in these salt marsh sediments occurs in the upper 2 m, and declines quickly with depth. Extrapolation forwards or backwards, using results from the ²¹⁰Pb and the ¹³⁷Cs dating technique appear to be warranted for the types of samples from the environments described here.  相似文献   

A numerical simulation of boundary-layer flows near shelterbelts   总被引：9，自引：6，他引：9  

Hao Wang  Eugene S. Takle 《Boundary-Layer Meteorology》1995,75(1-2):141-173

We have developed a shelterbelt boundary-layer numerical model to study the patterns and dynamic processes relating to flow interaction with shelterbelts. The model simulates characteristics of all three zones of airflow passing over and through shelterbelts: the windward windspeed-reduction zone, the overspeeding zone above the shelterbelt, and the leeward windspeed-reduction zone. Locations of the maximum windspeed reduction and recirculation zone, as well as the leeward windspeed-recovery rate are well simulated by the model. Where comparisons with field measurements and wind-tunnel experiments were possible, the model demonstrated good performance for flows over and through shelters ranging from almost completely open to almost solid. The dynamic pressure resulting from the convergence and divergence of the flow field alters the perturbation pressure field. The disturbed pressure controls not only the formation of the separated flow but also the location of maximum windspeed reduction, streamline curvature, speed-up over the shelterbelt, and leeward windspeed recovery rate. The interaction of pressure with the flow produces complex flow patterns, the characteristics of which are determined, to a great extent, by shelterbelt structure.  相似文献   

Ground-Water Age Distribution in Madrid Basin, Spain   总被引：1，自引：0，他引：1  

M. Ramon Llamas  Eugene S. Simpson  Pedro E. Martinez Alfaro 《Ground water》1982,20(6):688-695

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Dependence of fishery species on salt marshes: The role of food and refuge     

Donald F. Boesch  R. Eugene Turner 《Estuaries and Coasts》1984,7(4):460-468

Salt marshes are widely believed to serve as nurseries for many fishes and crustaceans of fishery value as a result of the high production of vascular plant detritus and the protection from predation offered by shallow, spatially complex habitats. Comparisons of the yields of species which reside in salt marsh habitats during critical life history stages (such as penaeid shrimp) with the area of such habitats and their greater densities in flooded marshes and associated tidal creeks support the premise that marshes enhance the yield of such species. A range of evidence, including the amount of detrital export from marshes, the poor nutritive value of vascular plant detritus, and natural diets, casts doubt on the notion that production of fishery species is based on the direct consumption of marsh grass detritus or predominantly on food chains based on this detritus. Vascular plants and associated algae may, however, contribute to the production of prey species. The limited observations available support the hypothesis that salt marshes offer significant escape from mortality due to predation, but there have been yet few experimental tests of this hypothesis. Knowledge of relative importance of the food and refuge functions in support of living resources is of practical value in marsh and fisheries management. Better understanding of these roles is important to the effective evaluation of the effects of coastal habitat modifications on fisheries resources and design of alterations to minimize the losses of these values.  相似文献   

Avian cholera and organochlorine residues in an American oystercatcher     

Lawrence J. Blus  Louis N. Locke  Eugene Cromartie 《Estuaries and Coasts》1978,1(2):128-129

Pasteurella multocida, the causative bacterium of avian cholera, was isolated from cultures of the liver and heart blood of a female, adult American oystercatcher (Haematopus palliatus) found dead on the Cape Romain National Wildlife Refuge, South Carolina, in May 1973. This is apparently the first record of avian cholera in the oystercatcher. Low levels of DDE were identified in tissues of the oystercatcher.  相似文献   

Particulate dispersion into and within a forest     

Gilbert S. Raynor  Janet V. Hayes  Eugene C. Ogden 《Boundary-Layer Meteorology》1974,7(4):429-456

Particulate dispersion into and within a 10- to 13-m tall pine forest was studied experimentally at Brookhaven National Laboratory using stained ragweed pollen and other tracers ranging from 14 to 54 m in diam. Seventy-two continuous point source releases lasting 20 to 40 min were made at various distances from within the forest edge to 60 m upwind and at heights of 1.75 to 14.0 m. In most experiments, differently colored ragweed pollen was released simultaneously from three locations. Thirty-six longer tests were made using pollen from area sources of ragweed and three with pollen from distant sources. All tests were made during the day with steady winds and unstable lapse rates outside the forest. The sampling network consisted of 119 rotoslide samplers mounted at heights from 0.5 to 21.0 m at 57 positions extending 100 m into the forest. Deposition was sampled by greased microscope slides at each sampling position. Meteorological measurements were taken in and near the forest.Data were classified by particle characteristics; by source type, distance and height; and by meteorological parameters. Isopleths were drawn on scale diagrams of the sampling grid to illustrate concentration patterns. Changes in centerline concentration, crosswind integrated concentration, mass flux, plume width, plume height, deposition, and deposition velocity were related to distance within the forest and other variables. Results were compared to those of similar releases over open terrain and those of previous forest dispersion studies elsewhere.The plume approaching the forest is broadened both vertically and horizontally by increased turbulence at the forest edge and flows mainly into the trunk space and above the forest. Lateral spread is slow within the forest, but vertical spreading beyond the entrance region is greater than in the open. Particles become mixed uniformly below the canopy while appreciable interchange takes place through this layer. Concentration within the forest decreases at a faster rate than in the open, but change in total mass flux within and above the forest is not significantly different. Loss of material takes place by impaction near the forest edge and in the tree tops and by deposition within the forest. Most loss takes place to the foliage rather than the ground, and larger particles are lost faster than smaller ones.This research was carried out under the auspices of the New York State Museum and Science Service and the U.S. Atomic Energy Commission and was partially supported by Research Grant No. R-800677 from the Division of Meteorology, U.S. Environmental Protection Agency.  相似文献