The dissolution of synthetic Na-boltwoodite in sodium carbonate solutions     

Eugene S. Ilton  Chongxuan Liu  Wassana Yantasee  Zheming Wang  Dean A. Moore  Andrew R. Felmy  John M. Zachara 《Geochimica et cosmochimica acta》2006,70(19):4836-4849

Uranyl silicates such as uranophane and Na-boltwoodite appear to control the solubility of uranium in certain contaminated sediments at the US Department of Energy Hanford site [Liu, C., Zachara, J.M., Qafoku, O., McKinley, J.P., Heald, S.M., Wang, Z. 2004. Dissolution of uranyl microprecipitates in subsurface sediments at Hanford Site, USA. Geochim. Cosmochim. Acta68, 4519-4537.]. Consequently, the solubility of synthetic Na-boltwoodite, Na(UO₂)(SiO₃OH) · 1.5H₂O, was determined over a wide range of bicarbonate concentrations, from circumneutral to alkaline pH, that are representative of porewater and groundwater compositions at the Hanford site and calcareous environments generally. Experiments were open to air. Results show that Na-boltwoodite dissolution was nearly congruent and its solubility and dissolution kinetics increased with increasing bicarbonate concentration and pH. A consistent set of solubility constants were determined from circumneutral pH (0 added bicarbonate) to alkaline pH (50 mM added bicarbonate). Average or 5.85 ± 0.0.26; using the Pitzer ion-interaction model or Davies equation, respectively. These values are close to the one determined by [Nguyen, S.N., Silva, R.J., Weed, H.C., Andrews, Jr., J.E., 1992. Standard Gibbs free energies of formation at the temperature 303.15 K of four uranyl silicates: soddyite, uranophane, sodium boltwoodite, and sodium weeksite. J. Chem. Thermodynamics24, 359-376.] under very different conditions (pH 4.5, Ar atmosphere).  相似文献   

First-Order Inconsistencies Caused by Rogue Trajectories     

John V. Postma  Eugene Yee  John D. Wilson 《Boundary-Layer Meteorology》2012,144(3):431-439

A theoretical requirement of the Interaction by Exchange with the Conditional Mean (IECM) micromixing model is that the mean concentration field produced by it must be consistent with the mean concentration field produced by a traditional Lagrangian stochastic (LS) marked particle model. We examine the violation of this requirement that occurs in a coupled LS–IECM model when unrealistically high particle velocities occur. No successful strategy was found to mitigate the effects of these rogue trajectories. It is our hope that this work will provide renewed impetus for investigation into rogue trajectories and methods to eliminate them from LS models.  相似文献   

The Obolon impact structure,Ukraine, and its ejecta deposits     

Eugene GUROV  Elena GUROVA  Yuri CHERNENKO  Anatoly YAMNICHENKO 《Meteoritics & planetary science》2009,44(3):389-404

Abstract— The Obolon impact structure, 18 km in diameter, is situated at the northeastern slope of the Ukrainian Shield near its margin with the Dnieper‐Donets Depression. The crater was formed in crystalline rocks of the Precambrian basement that are overlain by marine Carboniferous and continental Lower Triassic deposits. The post‐impact sediments comprise marine Middle Jurassic (Bajocian and Bathonian) and younger Mesozoic and Cenozoic deposits. Today the impact structure is buried beneath an about 300‐meter‐thick sedimentary rock sequence. Most information on the Obolon structure is derived from two boreholes in the western part of the crater. The lowest part of the section in the deepest borehole is composed by allogenic breccia of crystalline basement rocks overlain by clast‐rich impact melt rocks and suevites. Abundant shock metamorphic effects are planar deformation features (PDFs) in quartz and feldspars, kink bands in biotite, etc. Coesite and impact diamonds were found in clast‐rich impact melt rocks. Crater‐fill deposits are a series of sandstones and breccias with blocks of sedimentary rocks that are covered by a layer of crystalline rock breccia. Crystalline rock breccias, conglomeratic breccias, and sandstones with crystalline rock debris have been found in some boreholes around the Obolon impact structure to a distance of about 50 km from its center. Those deposits are always underlain by Lower Triassic continental red clay and overlain by Middle Jurassic marine clay. The K‐Ar age of impact melt glasses is 169 Ma, which corresponds to the Middle Jurassic (Bajocian) age. The composition of crater‐fill rocks within the crater and sediments outside the Obolon structure testify to its formation under submarine conditions.  相似文献   

Comparative dissolution kinetics of biogenic and chemogenic uraninite under oxidizing conditions in the presence of carbonate     

Kai-Uwe Ulrich  Eugene S. Ilton  Jonathan O. Sharp  Rizlan Bernier-Latmani  John R. Bargar 《Geochimica et cosmochimica acta》2009,73(20):6065-7290

The long-term stability of biogenic uraninite with respect to oxidative dissolution is pivotal to the success of in situ bioreduction strategies for the subsurface remediation of uranium legacies. Batch and flow-through dissolution experiments were conducted along with spectroscopic analyses to compare biogenic uraninite nanoparticles obtained from Shewanella oneidensis MR-1 and chemogenic UO_2.00 with respect to their equilibrium solubility, dissolution mechanisms, and dissolution kinetics in water of varied oxygen and carbonate concentrations. Both materials exhibited a similar intrinsic solubility of ∼10⁻⁸ M under reducing conditions. The two materials had comparable dissolution rates under anoxic as well as oxidizing conditions, consistent with structural bulk homology of biogenic and stoichiometric uraninite. Carbonate reversibly promoted uraninite dissolution under both moderately oxidizing and reducing conditions, and the biogenic material yielded higher surface area-normalized dissolution rates than the chemogenic. This difference is in accordance with the higher proportion of U(V) detected on the biogenic uraninite surface by means of X-ray photoelectron spectroscopy. Reasonable sources of a stable U(V)-bearing intermediate phase are discussed. The observed increase of the dissolution rates can be explained by carbonate complexation of U(V) facilitating the detachment of U(V) from the uraninite surface. The fraction of surface-associated U(VI) increased with dissolved oxygen concentration. Simultaneously, X-ray absorption spectra showed conversion of the bulk from UO_2.0 to UO_2+x. In equilibrium with air, combined spectroscopic results support the formation of a near-surface layer of approximate composition UO_2.25 (U₄O₉) coated by an outer layer of U(VI). This result is in accordance with flow-through dissolution experiments that indicate control of the dissolution rate of surface-oxidized uraninite by the solubility of metaschoepite under the tested conditions. Although U(V) has been observed in electrochemical studies on the dissolution of spent nuclear fuel, this is the first investigation that demonstrates the formation of a stable U(V) intermediate phase on the surface of submicron-sized uraninite particles suspended in aqueous solutions.  相似文献   

New snow metrics for a warming world     

Anne W. Nolin  Eric A. Sproles  David E. Rupp  Ryan L. Crumley  Mariana J. Webb  Ross T. Palomaki  Eugene Mar 《水文研究》2021,35(6):e14262

Snow is Earth's most climatically sensitive land cover type. Traditional snow metrics may not be able to adequately capture the changing nature of snow cover. For example, April 1 snow water equivalent (SWE) has been an effective index for streamflow forecasting, but it cannot express the effects of midwinter melt events, now expected in warming snow climates, nor can we assume that station-based measurements will be representative of snow conditions in future decades. Remote sensing and climate model data provide capacity for a suite of multi-use snow metrics from local to global scales. Such indicators need to be simple enough to “tell the story” of snowpack changes over space and time, but not overly simplistic or overly complicated in their interpretation. We describe a suite of spatially explicit, multi-temporal snow metrics based on global satellite data from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and downscaled climate model output for the U.S. We describe and provide examples for Snow Cover Frequency (SCF), Snow Disappearance Date (SDD), At-Risk Snow (ARS), and Frequency of a Warm Winter (FWW). Using these retrospective and prospective snow metrics, we assess the current and future snow-related conditions in three hydroclimatically different U.S. watersheds: the Truckee, Colorado Headwaters, and Upper Connecticut. In the two western U.S. watersheds, SCF and SDD show greater sensitivity to annual differences in snow cover compared with data from the ground-based Snow Telemetry (SNOTEL) network. The eastern U.S. watershed does not have a ground-based network of data, so these MODIS-derived metrics provide uniquely valuable snow information. The ARS and FWW metrics show that the Truckee Watershed is highly vulnerable to conversion from snowfall to rainfall (ARS) and midwinter melt events (FWW) throughout the seasonal snow zone. In comparison, the Colorado Headwaters and Upper Connecticut Watersheds are colder and much less vulnerable through mid- and late-century.  相似文献   

WHITHER GEOGRAPHY?     

Eugene Van Cleef 《The Professional geographer》1971,23(4):344-346

  相似文献   

Mars: Evidence for dynamic processes from mariners 6 and 7     

Wolfgang E. Elston  Eugene I. Smith 《Icarus》1973,19(2):180-194

Mariners 6 and 7 photographs of the equatorial region of Mars document a three-stage evolution of that part of the Martian surface: (1) High- and intermediate-albedo cratered terrains in Meridiani Sinus, Margaritifer Sinus-Thymiamata, Deucalionis Regio-Sabaeus Sinus, and Hellespontus; (2) low-albedo moderately cratered terrain and dark crater fill in Meridiani Sinus, Thymiamata, and Deucalionis Regio-Sabaeus Sinus and possible volcanism in the Hellas-Hellespontus border; and (3) high-albedo surficial deposits, banked-up crater fill, a possible bright-ray crater in Meridiani Sinus, chaotic terrain on the edge of the Margaritifer Sinus mesa, featureless terrain in Hellas and Edom, sinuous channel-like reentrants on scarps at the Hellas-Hellespontus boundary. Regional faulting seems to have occurred following formation of the old cratered plains and prior to formation of low-albedo plains in Meridiani Sinus and also prior to formation of canyon-like reentrants and featureless terrain along the Hellas-Hellespontus boundary.Mars has had a complex history of dynamic evolution, possibly analogous to the more stable regions of Earth. Its geochemical differentiation and thermal regime should account for long-term postaccretional tectonic and volcano-tectonic processes as well as for fluid media on its surface sufficient to cause erosion, including the cutting of large canyons.  相似文献   

Numerical Study of Dual-Plume Interference in a Turbulent Boundary Layer     

Shahin N. Oskouie  Bing-Chen Wang  Eugene Yee 《Boundary-Layer Meteorology》2017,164(3):419-447

Direct numerical simulation is used to investigate the interference arising from the dispersion of passive scalar plumes released from a pair of point sources in a fully-developed wall-bounded shear flow. Four different lateral separations of the two sources for both near ground-level and elevated releases are considered. The downwind evolution of the correlation between the plume concentrations along the centreline between the two sources and the behaviour of the lateral profiles of the correlation at various locations downwind of the two sources are examined in detail. Differences in the exceedance probability over a high concentration level for a single plume and the total plume are highlighted and studied, and the effects of destructive and constructive interferences on the exceedance probabilities for the total plume are used to explain these differences. One significant result is that all higher-order (third-order and above) moments of the total concentration can be inferred from the application of a clipped-gamma distribution using the information embodied in only the first- and second-order concentration moments of each single plume, and in the cross-correlation coefficient of the instantaneous concentration of the two plumes.  相似文献   

Book Review     

Victor A. Brumberg  Eugene V. Brumberg:  John D. Hadjidemetriou 《Celestial Mechanics and Dynamical Astronomy》1999,75(4):301-301

The aim of this book is to present techniques for the study of motion of solar system objects in highly eccentric orbits. Instead of using the usual anomalies (mean, true, eccentric), the authors define and use a new kind of anomaly, the elliptic anomaly.In this way, it is possible, in a theory using perturbation series expansions, to make the ratio: (accuracy)/(number of needed terms), higher than in the classical techniques. The book consists of six chapters. The first chapter deals with the elliptic anomaly in the two-body problem and the second chapter presents the general technique to construct first-order perturbation theory in elliptic function expansions. The next three chapters deal with applications of the new technique to artificial satellites and asteroids, in highly eccentric orbits. The last chapter describes the basic algorithms of the theory.The tools developed in the book demand the use of computer algebra, which is implemented by means of Mathematica 3.0.The book is well written and the new technique is clearly presented and related to the existing techniques, making it useful to all those who use analytical or semi-analytical methods for the study of highly eccentric motion. Celestial Mechanics at High Eccentricities, Gordon and Breach Publishers, US$95, GBP 59, EUR 79, ISBN 90-5699-212-0  相似文献   

Biogenic silica from the BDP93 drill site and adjacent areas of the Selenga Delta, Lake Baikal, Siberia     

Steven M. Colman  John A. Peck  Josephine Hatton  Eugene B. Karabanov  John W. King 《Journal of Paleolimnology》1999,21(1):9-17

Biogenic silica contents of sediments on the lower Selenga Delta and Buguldeika saddle in Lake Baikal show distinct fluctuations that reflect changes in diatom productivity, and ultimately, climate. The pattern of the upper 50 m of the section, dating from about 334 ka, is similar to that of the marine oxygen-isotope record, increasingly so as the younger sediments become progressively finer grained and less locally derived with time. The last two interglaciations are marked by biogenic silica abundances similar to those of the Holocene. The equivalent of marine oxygen-isotope stage 3 is distinctly intermediate in character between full glacial and full interglacial biogenic silica values. Following near-zero values during the last glacial maximum, biogenic silica began to increase at about 13 ka. The rise in biogenic silica to Holocene values was interrupted by an abrupt decrease during Younger Dryas time, about 11 to 10 14C ka.  相似文献