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101.
This paper describes a study of the vertical structure of concentration fluctuations in a neutrally buoyant plume from an elevated point source in slightly convective to moderately stable meteorological conditions at ranges of between 12.5 and 100 m for a range of source heights between 1 and 5 m. Observations were made of concentration fluctuations in a dispersing plume using a vertical array of sixteen very fast-response photoionization detectors placed at heights between 0.5 and 16 m. Vertical profiles of a number of concentration statistics were extracted, namely, mean concentration, fluctuation intensity, intermittency factor, peak-to-mean concentration ratio, mean dissipation rate of concentration variance, and various concentration time and length scales of dominant motions in the plume (e.g., integral macro-scale, in-plume mid-scale and Taylor micro-scale). The profiles revealed a similarity to corresponding crosswind profiles for a fully elevated plume, but showed greater and greater departure from the latter shapes once the plume had grown in the vertical so that its lower dege began to interact progressively more strongly with the ground. The evolution of the concentration probability density function at a fixed range, but with decreasing height from the ground, is similar to that obtained at a fixed height but with increasing distance from the source. Concentration power spectra obtained at different heights all had an extensive inertial-convective subrange spanning at least two decades in frequency, but spectra measured near the ground had a greater proportion of the total concentration variance in the lower frequencies (energetic subrange), with a correspondingly smaller proportion in the higher frequencies (inertial-convective subrange). It is believed that these effects result from the increased mean shear near the surface, and blocking by the surface. The effect of enhanced shear-induced molecular diffusion on concentration fluctuations is examined.  相似文献   
102.
103.
Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L-group is unusually variable and may represent at least 2 sub-groups differing in formation history. Chemical trends in the S/Fe-rich sub-group support textural evidence indicating late loss of a shock-formed Fe-Ni-S melt; the S/Fe-poor sub-group seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock-induced loss from L-chondrites. Data for L5 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.  相似文献   
104.
Baltimore Harbor, a tributary area of the northern Chesapeake Bay, has recelved and is receiving large quantities of chemical pollutants. As part of a cooperative study to explore possible corrective treatment for existing pollution burdens, gross bioassay analyses were performed for sediments from nine representative stations, employing two species of fish, mummichogs (Fundulus heteroclitus) and spot (Leiostomus xanthurus), and one mollusc, the soft-shell clam (Mya arenaria). Acclimated organisms were exposed in static systems to a series of concentrations of suspended sediment from each station, to fuller's earth in suspension, and in control tanks for 48 hours. Parallel analysis of the sediment was performed for the metals, Pb, Cr, Zn, Ca, As, for PCB's and for hexane extracts. The sediments were all substantially polluted with low correlations among components. Twenty-four hour TLm and 48-hour TLm increased proportionately with sediment concentration but display species specificity. The relationships observed permit use of mummichog data to index gross toxicity of sediments throughout the harbor. Further comparison of mummichog 24-hour TLm value with benthie species diversity determined in a previous study permitted zoning of the entire harbor into highly toxic, moderately toxic, low toxic and slightly toxic zones. Gross toxicity of sediments determined by bioassay can therefore be used as an index of the suitability of the sediments for benthic macroinvertebrate communities.  相似文献   
105.
106.
This is the second paper of a four-part series of papers on the development of a general framework for error analysis in measurement-based geographic information systems (MBGIS). In this paper, we discuss the problem of point-in-polygon analysis under randomness, i.e., with random measurement error (ME). It is well known that overlay is one of the most important operations in GIS, and point-in-polygon analysis is a basic class of overlay and query problems. Though it is a classic problem, it has, however, not been addressed appropriately. With ME in the location of the vertices of a polygon, the resulting random polygons may undergo complex changes, so that the point-in-polygon problem may become theoretically and practically ill-defined. That is, there is a possibility that we cannot answer whether a random point is inside a random polygon if the polygon is not simple and cannot form a region. For the point-in-triangle problem, however, such a case need not be considered since any triangle always forms an interior or region. To formulate the general point-in-polygon problem in a suitable way, a conditional probability mechanism is first introduced in order to accurately characterize the nature of the problem and establish the basis for further analysis. For the point-in-triangle problem, four quadratic forms in the joint coordinate vectors of a point and the vertices of the triangle are constructed. The probability model for the point-in-triangle problem is then established by the identification of signs of these quadratic form variables. Our basic idea for solving a general point-in-polygon (concave or convex) problem is to convert it into several point-in-triangle problems under a certain condition. By solving each point-in-triangle problem and summing the solutions, the probability model for a general point-in-polygon analysis is constructed. The simplicity of the algebra-based approach is that from using these quadratic forms, we can circumvent the complex geometrical relations between a random point and a random polygon (convex or concave) that one has to deal with in any geometric method when probability is computed. The theoretical arguments are substantiated by simulation experiments.This project was supported by the earmarked grant CUHK 4362/00H of the Hong Kong Research grants Council.  相似文献   
107.
108.
The cataclysmic eruption of Mount St. Helens on May 18, 1980, resulted in a large, north-facing amphitheater, with a steep headwall rising 700 m above the crater floor. In this deeply shaded niche a glacier, here named the Amphitheater glacier, has formed. Tongues of ice-containing crevasses extend from the main ice mass around both the east and the west sides of the lava dome that occupies the center of the crater floor. Aerial photographs taken in September 1996 reveal a small glacier in the southwest portion of the amphitheater containing several crevasses and a bergschrund-like feature at its head. The extent of the glacier at this time is probably about 0.1 km2. By September 2001, the debris-laden glacier had grown to about 1 km2 in area, with a maximum thickness of about 200 m, and contained an estimated 120,000,000 m3 of ice and rock debris. Approximately one-third of the volume of the glacier is thought to be rock debris derived mainly from rock avalanches from the surrounding amphitheater walls. The newly formed Amphitheater glacier is not only the largest glacier on Mount St. Helens but its aerial extent exceeds that of all other remaining glaciers combined.  相似文献   
109.
110.
A decoupling in MORB of measured Th/U (κ = 2.5) from that calculated by Pb isotopes (κ = 3.8) for the depleted asthenosphere is well established, and has been referred to as the second Pb paradox (Kramers, J.D., and Tolstikhin, I.N., 1997. Two terrestrial lead isotope paradoxes, forward transport modelling, core formation and the history of the continental crust. Chem. Geol., 139, 75–110.) or the kappa conundrum (Elliott, T., Zindler, A., and Bourdon, B., 1999. Exploring the kappa conundrum: the role of recycling in the lead isotope evolution of the mantle. Earth Planet. Sci. Lett., 169, 129–145.). More controversial has been the cause and timing of this phenomenon, although a higher return flux of U6+ relative to Th4+ and(or) the recycling of crustal Pb into the mantle have become the preferred explanations of most workers. Such a combined mechanism effectively operating over the past 2.5 Ga was modelled in plumbotectonics (Zartman, R.E., and Haines, S., 1988. The plumbotectonics model for Pb isotopic systematics among major terrestrial reservoirs—a case for bi–directional transport. Geochim. Cosmochim. Acta, 52, 1327–1339. 709.33.), and found to be quantitatively feasible.A large TIMS, SIMS and LA-ICPMS database of Th and U concentrations for kimberlite-hosted zircon, particularly from Cr-poor megacrystic suites, now exists (Kinny et al., 1989, Berryman et al., 1999, Griffin et al., 2000 and Spetsius et al., 2002; Appendix A and Appendix B, this work). Six suites comprising 10 or more zircon grains with ages between 90 and 2550 Ma reveal consistent patterns when plotted on Th/U vs. U diagrams. We interpret these patterns as resulting from fractional crystallization of a melt with kimberlite affinity presumably derived from the asthenosphere, permitting the extrapolation to an initial Th/U at the time zircon crystallization began. A two-fold decrease is seen in this ratio over the past 2.5 Ga, suggesting that during this time a similar change has occurred in the parent silicate melt. Estimates of Th and U distribution coefficients between zircon and coexisting melt permit calculation of Th/U in the melt, which, for these highly incompatible elements, presumably is the same as for its mantle source rock. Kimberlitic zircon may thus indeed give evidence of a reduction in κ, tentatively calculated as from 4 to 2, since the Archean for the depleted asthenosphere.  相似文献   
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