A molecular dynamics study of natural organic matter: 1. Lignin, kerogen and soot     

Lu Zhang  Eugene J. LeBoeuf   《Organic Geochemistry》2009,40(11):1132-1142

Molecular dynamics (MD) simulations were performed on molecular models of a spectrum of natural organic matter (NOM) samples represented by two lignin samples (a softwood lignin and a hardwood lignin), a kerogen (Green River Shale kerogen) and a soot sample (n-hexane soot). Simulated thermodynamic properties of each model, including glass transition temperature (T_g), thermal expansion coefficient (α), density (ρ) and solubility parameter (δ) were compared against experimental data for corresponding samples. Results revealed relatively good agreement for glass transition temperature and solubility parameter for softwood lignin, Green River Shale kerogen and n-hexane soot models. An unexpectedly low solubility parameter for a hardwood lignin model suggests, however, certain model deficiencies in terms of intermolecular interactions. In addition, a lower density for a n-hexane soot model relative to the sample was attributed to the small cluster size and poor parallel stacking of aromatic clusters in the model. Discussion of the results is provided in the context of utilizing thermodynamic properties as constraints for improved structural modeling of NOM.  相似文献   

Salinity history of coastal marshes reconstructed from diatom remains     

Michael L. Parsons  Quay Dortch  R. Eugene Turner  Nancy N. Rabalais 《Estuaries and Coasts》1999,22(4):1078-1089

Sediment cores were collected from three Louisiana coastal marsh ponds, dated with radioisotopes, and analyzed for diatom remains to determine if long-term salinity changes were evident in the sediment record. A diatom-based salinity index formulated from a statistical comparison of available salinity data and changing diatom assemblages demonstrated that diatom remains appear to preserve salinity signals in coastal brackish and salt marsh environments. The salinity index was applied to sediment cores spanning the late 1600s to the 1990s and provided a more complete record of salinity than field data, which were temporally and spatially incomplete. The salinity reconstructions indicated that salinity has increased at two sites and decreased at a third since the early 1900s. The salinity changes are less than 1‰ per decade in all cases, and may be due to natural variability as depicted by the wide range of salinities observed between the late 1600s and 1900. Salinity regimes may be very localized (<2 km from a hydrologic source), indicating single-site studies may not be applicable to regional inferences. This study demonstrates that diatoms can be used to reconstruct past salinity in coastal marsh environments and can provide a useful tool with which to study the changing hydrology of river-influenced ecosystems.  相似文献   

Temperature variation in Guangdong Province, China     

YAN Yuk Yee 《地理学报(英文版)》1999,(2)

1IntroductionThereisgrowingawarenessofclhatechange,andnumerousresearchonclhatictrendsandvallabilityatglobalorregionalscalehasbenconductedMoStstudieshaveconcen~onthelong-tenntrendsintemperatUI'eandPeripiboonpiousstudiesonhendSPherictempo~bendshavebeenconducted.AngellandKorshover(1977ac1978)StUdiedthetemperatUresinthenodsmhelinSPhereandstatedthattherewasadeClineoftemperatUreSinthe1960sandaslightw~gwasObservedafter197ill;l.OtherauthorssuchasLamb(1982)andJonesetal.(1982and1986a)SUPPOrted…  相似文献   

Necessary and sufficient conditions for the existence of a solution to the one-dimensional magnetotelluric inverse problem     

E. Yee  K. V. Paulson 《Geophysical Journal International》1988,93(2):279-293

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THE MILLS,NEW MEXICO,CHONDRITE — A NEW FIND     

G. R. Levi-Donati  Eugene Jarosewich 《Meteoritics & planetary science》1974,9(2):145-155

A mineralogical and chemical analysis has been performed on a slice of the Mills, New Mexico, chondrite, which was found in August 1970. The mineralogical composition is olivine Fa_19.5, bronzite, Fs_17.4, plagioclase, nickel-iron, troilite and ilmenite. The chemical analysis confirms that Mills is a typical bronzite, H5 chondrite, with considerable degree of weathering, as indicated by the presence of large amounts of Fe₂O₃. A comparison with other stones found in the same New Mexico region by Nininger may show a possible relation between Mills and previous finds.  相似文献   

Rümker hills: a lunar volcanic dome complex     

Eugene I. Smith 《Earth, Moon, and Planets》1974,10(2):175-181

The Rümker Hills, a volcanic dome-flow complex in the northern Oceanus Procellarum, is characterized by overlapping plains-forming units with lobate scarps, volcanic domes, a 60 km ring, and a scarp which separates the plateau from surrounding mare materials. Plains-forming units are interpreted as fluid volcanic flows, and domes as viscous extrusions. One dome may be a stratovolcano. The ring system is discordant with regional structural trends and probably has a local origin. The Rümker Hills is the closest lunar analog to the large martian shield structures revealed on the Mariner 9 photographs of Mars.  相似文献   

Energy transfer in oxygen-hydrogen collisions     

D.L. Cooper  J.H. Yee  A. Dalgarno 《Planetary and Space Science》1984,32(7):825-830

A formula is obtained for the rate coefficient for the production of a particle with a specific energy in an elastic collision with the atoms of a thermal gas. Accurate calculations are carried out of the energy transfer in elastic collisions of oxygen and hydrogen atoms. The fractions of hydrogen atoms with sufficient energy to escape from Venus produced in collisions of oxygen atoms with energies of 2.6 eV in a gas of atomic hydrogen at 100, 200 and 300 K are respectively 5.1, 6.9 and 8.5%.The mutual diffusion coefficient D of oxygen and hydrogen atoms is obtained. It can be represented by Dn = 7.25 × 10¹⁷T^0.71cm^?1s^?1 where n is the total atom density and T is the temperature.  相似文献   

The circumstellar imager: Direct detection of extra-solar planetary systems     

Christ Ftaclas  Andreas L. Nonnenmacher  Richard J. Terrile  Steven H. Pravdo  George D. Gatewood  Eugene H. Levy 《Astrophysics and Space Science》1994,212(1-2):441-452

The Astrometric Imaging Telescope (AIT) is designed to probe the circumstellar environment by both direct imaging and indirect astrometric measurements. The Circumstellar Imager (CI) is a coronagraphic camera and is the direct imaging component of the AIT. The CI is designed to obtain high-sensitivity images of the circumstellar region. It provides crucial non-inferential information relating to the frequency, origin, and evolution of planetary systems and all forms of circumstellar matter. Such imaging is usually limited by the scattered and diffracted light halos of the star itself, which are greatly suppressed in the CI by mating a novel high-efficiency coronagraph with a phasecompensated optical system. For faint point sources in the circumstellar region, the CI will have a sensitivity in excess of 5 magnitudes fainter than the as-designed Hubble Space Telescope (HST). Laboratory data are shown for the coronagraph, which, in a diffraction-limited environment, is capable of suppressing the stellar diffraction sidelobes by several orders of magnitude without significant sacrifice of field of view. In order to realize the high rejection levels inherent in the coronagraph design, it is necessary to limit scatter in the optical systems, imposing a mid-spatial frequency figure error requirement an order of magnitude smaller than that of the HST. Experimental data directed toward meeting this requirement are also shown.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.  相似文献   

Probability distributions of concentration fluctuations of a weakly diffusive passive plume in a turbulent boundary layer   总被引：4，自引：0，他引：4  

Eugene Yee  D. J. Wilson  B. W. Zelt 《Boundary-Layer Meteorology》1993,64(4):321-354

Results are presented from an experimental investigation of turbulent dispersion of a saline plume of large Schmidt number (Sc=830) in a turbulent boundary-layer shear flow simulated in a laboratory water channel. The dispersion measurements are obtained in a neutrally buoyant plume from an elevated point source over a range of downstream distances, where both plume meandering and fine-structure variations in the instantaneous plume are important. High-resolution measurements of the scalar fluctuations in the plume are made with a rake of conductivity probes from which probability distributions of concentration at various points throught the plume are extracted from the time series.Seven candidate probability distributions were tested, namely, the exponential, lognormal, clipped normal, gamma, Weibull, conjugate beta, andK-distributions. Using the measured values of the conditional mean concentration, , and the conditional fluctuation intensity,i _p , the Weibull distribution provided the best match to the skewness and kurtosis over all downstream fetches. The skewness and kurtosis were always overpredicted by the lognormal probability density function (pdf), and underpredicted by the gamma pdf. The conjugate beta distribution for which the model parameters are determined using a method of moments based on the fluctuation intensity,i _p , and skewness,S _p , was capable of modeling the distribution of scalar concentration over a wide range of positions in the plume.  相似文献   

Multiscaling properties of concentration fluctuations in dispersing plumes revealed using an orthonormal wavelet decomposition     

Eugene Yee  R. Chan  P. R. Kosteniuk  C. A. Biltoft  J. F. Bowers 《Boundary-Layer Meteorology》1996,77(2):173-207

The dynamical characteristics of concentration fluctuations in a dispersing plume over the energetic and inertial-convective range of scales of turbulent motion are studied using a multiscale analysis technique that is based on an orthonormal wavelet representation. It is shown that the Haar wavelet concentration spectrum is similar to the Fourier concentration spectrum in that both spectra exhibit an extensive inertial-convective subrange spanning about two decades in frequency, with a scaling exponent of -5/3. Analysis of the statistical properties (e.g., fluctuation intensity, skewness, and kurtosis) of the concentration wavelet coefficients (i.e., the concentration discrete detailed signal) suggests that the small scales are always more intermittent than the large scales. The degree of intermittency increases monotonically with decreasing scale within the inertial-convective subrange, reaching a plateau at the very small scales associated with the beginning of the near-dissipation subrange. The probability density function (pdf) of the concentration discrete detailed signal displays stretched exponential tails with an intermittency exponent (tail slope) q that increases as ^a , where is the scale or dilation and a is a power-law exponent that is dependent on downwind distance, plume height, and stratification strength with typical values in the range from about 0.25 to 0.35. It is shown that the concentration variance cascade process requires a phase coherency of eddies between different scales at the small-scale end of the inertial-convective subrange.The variation of the concentration wavelet statistics with height above the ground is investigated. The increased mean shear near the ground smooths the fine-scale plume structure for scales within the inertial-convective subrange, producing a weaker spatiotemporal intermittency in the concentration field compared to that measured higher up in the plume. The pdf of the concentration detailed signal at a fixed scale possesses less elongated tails with decreasing height z. The intermittency exponent q is found to decrease roughly linearly with increasing z.Finally, the results of the wavelet decomposition are combined to provide a conceptual model of the turbulent transport, stirring, and mixing regimes in a dispersing plume. The implications of the results for contaminant texture in a plume are discussed.  相似文献