Comparative dissolution kinetics of biogenic and chemogenic uraninite under oxidizing conditions in the presence of carbonate     

Kai-Uwe Ulrich  Eugene S. Ilton  Jonathan O. Sharp  Rizlan Bernier-Latmani  John R. Bargar 《Geochimica et cosmochimica acta》2009,73(20):6065-7290

The long-term stability of biogenic uraninite with respect to oxidative dissolution is pivotal to the success of in situ bioreduction strategies for the subsurface remediation of uranium legacies. Batch and flow-through dissolution experiments were conducted along with spectroscopic analyses to compare biogenic uraninite nanoparticles obtained from Shewanella oneidensis MR-1 and chemogenic UO_2.00 with respect to their equilibrium solubility, dissolution mechanisms, and dissolution kinetics in water of varied oxygen and carbonate concentrations. Both materials exhibited a similar intrinsic solubility of ∼10⁻⁸ M under reducing conditions. The two materials had comparable dissolution rates under anoxic as well as oxidizing conditions, consistent with structural bulk homology of biogenic and stoichiometric uraninite. Carbonate reversibly promoted uraninite dissolution under both moderately oxidizing and reducing conditions, and the biogenic material yielded higher surface area-normalized dissolution rates than the chemogenic. This difference is in accordance with the higher proportion of U(V) detected on the biogenic uraninite surface by means of X-ray photoelectron spectroscopy. Reasonable sources of a stable U(V)-bearing intermediate phase are discussed. The observed increase of the dissolution rates can be explained by carbonate complexation of U(V) facilitating the detachment of U(V) from the uraninite surface. The fraction of surface-associated U(VI) increased with dissolved oxygen concentration. Simultaneously, X-ray absorption spectra showed conversion of the bulk from UO_2.0 to UO_2+x. In equilibrium with air, combined spectroscopic results support the formation of a near-surface layer of approximate composition UO_2.25 (U₄O₉) coated by an outer layer of U(VI). This result is in accordance with flow-through dissolution experiments that indicate control of the dissolution rate of surface-oxidized uraninite by the solubility of metaschoepite under the tested conditions. Although U(V) has been observed in electrochemical studies on the dissolution of spent nuclear fuel, this is the first investigation that demonstrates the formation of a stable U(V) intermediate phase on the surface of submicron-sized uraninite particles suspended in aqueous solutions.  相似文献   

New snow metrics for a warming world     

Anne W. Nolin  Eric A. Sproles  David E. Rupp  Ryan L. Crumley  Mariana J. Webb  Ross T. Palomaki  Eugene Mar 《水文研究》2021,35(6):e14262

Snow is Earth's most climatically sensitive land cover type. Traditional snow metrics may not be able to adequately capture the changing nature of snow cover. For example, April 1 snow water equivalent (SWE) has been an effective index for streamflow forecasting, but it cannot express the effects of midwinter melt events, now expected in warming snow climates, nor can we assume that station-based measurements will be representative of snow conditions in future decades. Remote sensing and climate model data provide capacity for a suite of multi-use snow metrics from local to global scales. Such indicators need to be simple enough to “tell the story” of snowpack changes over space and time, but not overly simplistic or overly complicated in their interpretation. We describe a suite of spatially explicit, multi-temporal snow metrics based on global satellite data from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and downscaled climate model output for the U.S. We describe and provide examples for Snow Cover Frequency (SCF), Snow Disappearance Date (SDD), At-Risk Snow (ARS), and Frequency of a Warm Winter (FWW). Using these retrospective and prospective snow metrics, we assess the current and future snow-related conditions in three hydroclimatically different U.S. watersheds: the Truckee, Colorado Headwaters, and Upper Connecticut. In the two western U.S. watersheds, SCF and SDD show greater sensitivity to annual differences in snow cover compared with data from the ground-based Snow Telemetry (SNOTEL) network. The eastern U.S. watershed does not have a ground-based network of data, so these MODIS-derived metrics provide uniquely valuable snow information. The ARS and FWW metrics show that the Truckee Watershed is highly vulnerable to conversion from snowfall to rainfall (ARS) and midwinter melt events (FWW) throughout the seasonal snow zone. In comparison, the Colorado Headwaters and Upper Connecticut Watersheds are colder and much less vulnerable through mid- and late-century.  相似文献   

WHITHER GEOGRAPHY?     

Eugene Van Cleef 《The Professional geographer》1971,23(4):344-346

  相似文献   

Mars: Evidence for dynamic processes from mariners 6 and 7     

Wolfgang E. Elston  Eugene I. Smith 《Icarus》1973,19(2):180-194

Mariners 6 and 7 photographs of the equatorial region of Mars document a three-stage evolution of that part of the Martian surface: (1) High- and intermediate-albedo cratered terrains in Meridiani Sinus, Margaritifer Sinus-Thymiamata, Deucalionis Regio-Sabaeus Sinus, and Hellespontus; (2) low-albedo moderately cratered terrain and dark crater fill in Meridiani Sinus, Thymiamata, and Deucalionis Regio-Sabaeus Sinus and possible volcanism in the Hellas-Hellespontus border; and (3) high-albedo surficial deposits, banked-up crater fill, a possible bright-ray crater in Meridiani Sinus, chaotic terrain on the edge of the Margaritifer Sinus mesa, featureless terrain in Hellas and Edom, sinuous channel-like reentrants on scarps at the Hellas-Hellespontus boundary. Regional faulting seems to have occurred following formation of the old cratered plains and prior to formation of low-albedo plains in Meridiani Sinus and also prior to formation of canyon-like reentrants and featureless terrain along the Hellas-Hellespontus boundary.Mars has had a complex history of dynamic evolution, possibly analogous to the more stable regions of Earth. Its geochemical differentiation and thermal regime should account for long-term postaccretional tectonic and volcano-tectonic processes as well as for fluid media on its surface sufficient to cause erosion, including the cutting of large canyons.  相似文献   

An integrated web-based air pollution decision support system – a prototype     

Yee Leung  Kwong-Sak Leung  Man-Hong Wong  Terrence Mak  Kwan-Yau Cheung  Leung-Yau Lo 《International journal of geographical information science》2018,32(9):1787-1814

To efficiently and effectively monitor and mitigate air pollution in the urban environment, it is of paramount importance to integrate into a unified whole air pollutant concentration databases coming from different sources including the ground-based stations, mobile sensors, remote sensing, atmospheric-chemical-transport models and social media for the analysis and unraveling of the complex air pollution processes in space and time. This study constructs and implements for the first time a prototype of the fully integrated air pollution decision support system (APDSS) that put together in an integrated manner all relevant multi-scale, multi-type and multi-source data for decision-making on urban air pollution. The prototype contains the main system that handles the multi-source, multi-type and multi-scale databases, queries, visualization and data mining algorithms and the integrated modules that individually and holistically capitalize on the power of the ground-based stations, ground and aerial mobile sensors, satellite-borne remote-sensing technologies, atmospheric-chemical-transport models and social media. It renders a solid scientific foundation and system development methodology for the study of the spatiotemporal air pollution profiles crucial to the mitigation of urban air pollution. Real-life applications of the prototype are employed to illustrate the functionality of the APDSS.  相似文献   

Numerical Study of Dual-Plume Interference in a Turbulent Boundary Layer     

Shahin N. Oskouie  Bing-Chen Wang  Eugene Yee 《Boundary-Layer Meteorology》2017,164(3):419-447

Direct numerical simulation is used to investigate the interference arising from the dispersion of passive scalar plumes released from a pair of point sources in a fully-developed wall-bounded shear flow. Four different lateral separations of the two sources for both near ground-level and elevated releases are considered. The downwind evolution of the correlation between the plume concentrations along the centreline between the two sources and the behaviour of the lateral profiles of the correlation at various locations downwind of the two sources are examined in detail. Differences in the exceedance probability over a high concentration level for a single plume and the total plume are highlighted and studied, and the effects of destructive and constructive interferences on the exceedance probabilities for the total plume are used to explain these differences. One significant result is that all higher-order (third-order and above) moments of the total concentration can be inferred from the application of a clipped-gamma distribution using the information embodied in only the first- and second-order concentration moments of each single plume, and in the cross-correlation coefficient of the instantaneous concentration of the two plumes.  相似文献   

Book Review     

Victor A. Brumberg  Eugene V. Brumberg:  John D. Hadjidemetriou 《Celestial Mechanics and Dynamical Astronomy》1999,75(4):301-301

The aim of this book is to present techniques for the study of motion of solar system objects in highly eccentric orbits. Instead of using the usual anomalies (mean, true, eccentric), the authors define and use a new kind of anomaly, the elliptic anomaly.In this way, it is possible, in a theory using perturbation series expansions, to make the ratio: (accuracy)/(number of needed terms), higher than in the classical techniques. The book consists of six chapters. The first chapter deals with the elliptic anomaly in the two-body problem and the second chapter presents the general technique to construct first-order perturbation theory in elliptic function expansions. The next three chapters deal with applications of the new technique to artificial satellites and asteroids, in highly eccentric orbits. The last chapter describes the basic algorithms of the theory.The tools developed in the book demand the use of computer algebra, which is implemented by means of Mathematica 3.0.The book is well written and the new technique is clearly presented and related to the existing techniques, making it useful to all those who use analytical or semi-analytical methods for the study of highly eccentric motion. Celestial Mechanics at High Eccentricities, Gordon and Breach Publishers, US$95, GBP 59, EUR 79, ISBN 90-5699-212-0  相似文献   

Biogenic silica from the BDP93 drill site and adjacent areas of the Selenga Delta, Lake Baikal, Siberia     

Steven M. Colman  John A. Peck  Josephine Hatton  Eugene B. Karabanov  John W. King 《Journal of Paleolimnology》1999,21(1):9-17

Biogenic silica contents of sediments on the lower Selenga Delta and Buguldeika saddle in Lake Baikal show distinct fluctuations that reflect changes in diatom productivity, and ultimately, climate. The pattern of the upper 50 m of the section, dating from about 334 ka, is similar to that of the marine oxygen-isotope record, increasingly so as the younger sediments become progressively finer grained and less locally derived with time. The last two interglaciations are marked by biogenic silica abundances similar to those of the Holocene. The equivalent of marine oxygen-isotope stage 3 is distinctly intermediate in character between full glacial and full interglacial biogenic silica values. Following near-zero values during the last glacial maximum, biogenic silica began to increase at about 13 ka. The rise in biogenic silica to Holocene values was interrupted by an abrupt decrease during Younger Dryas time, about 11 to 10 14C ka.  相似文献   

Water Resources Implications of Global Warming: A U.S. Regional Perspective   总被引：8，自引：1，他引：7  

Dennis P. Lettenmaier  Andrew W. Wood  Richard N. Palmer  Eric F. Wood  Eugene Z. Stakhiv 《Climatic change》1999,43(3):537-579

The implications of global warming for the performance of six U.S. water resource systems are evaluated. The six case study sites represent a range of geographic and hydrologic, as well as institutional and social settings. Large, multi-reservoir systems (Columbia River, Missouri River, Apalachicola-Chatahoochee-Flint (ACF) Rivers), small, one or two reservoir systems (Tacoma and Boston) and medium size systems (Savannah River) are represented. The river basins range from mountainous to low relief and semi-humid to semi-arid, and the system operational purposes range from predominantly municipal to broadly multi-purpose. The studies inferred, using a chain of climate downscaling, hydrologic and water resources systems models, the sensitivity of six water resources systems to changes in precipitation, temperature and solar radiation. The climate change scenarios used in this study are based on results from transient climate change experiments performed with coupled ocean-atmosphere General Circulation Models (GCMs) for the 1995 Intergovernmental Panel on Climate Change (IPCC) assessment. An earlier doubled-CO₂ scenario from one of the GCMs was also used in the evaluation. The GCM scenarios were transferred to the local level using a simple downscaling approach that scales local weather variables by fixed monthly ratios (for precipitation) and fixed monthly shifts (for temperature). For those river basins where snow plays an important role in the current climate hydrology (Tacoma, Columbia, Missouri and, to a lesser extent, Boston) changes in temperature result in important changes in seasonal streamflow hydrographs. In these systems, spring snowmelt peaks are reduced and winter flows increase, on average. Changes in precipitation are generally reflected in the annual total runoff volumes more than in the seasonal shape of the hydrographs. In the Savannah and ACF systems, where snow plays a minor hydrological role, changes in hydrological response are linked more directly to temperature and precipitation changes. Effects on system performance varied from system to system, from GCM to GCM, and for each system operating objective (such as hydropower production, municipal and industrial supply, flood control, recreation, navigation and instream flow protection). Effects were generally smaller for the transient scenarios than for the doubled CO₂ scenario. In terms of streamflow, one of the transient scenarios tended to have increases at most sites, while another tended to have decreases at most sites. The third showed no general consistency over the six sites. Generally, the water resource system performance effects were determined by the hydrologic changes and the amount of buffering provided by the system's storage capacity. The effects of demand growth and other plausible future operational considerations were evaluated as well. For most sites, the effects of these non-climatic effects on future system performance would about equal or exceed the effects of climate change over system planning horizons.  相似文献   

Advection of passive scalars induced by a bay-trapped nonstationary vortex     

Eugene A. Ryzhov  Konstantin V. Koshel 《Ocean Dynamics》2018,68(3):411-422

A simple model of fluid particle advection induced by the interaction of a point vortex and incident plane flow occurring near a curved boundary is analyzed. The use of the curved boundary in this case is aimed at mimicking the geometry of an isolated bay of a circular shape. An introduction of such a boundary to the model results in the appearance of retention zones, where the vortex can be permanently trapped being either stationary or periodically oscillating. When stationary, it induces a steady velocity field that in turn ensures regular advection of nearby fluid particles. When the vortex oscillates periodically, the induced velocity field turns unsteady leading to the manifestation of chaotic advection of fluid particles. We show that the size of the fluid region engaged into chaotic advection increases almost monotonically with the increased magnitude of the vortex oscillations provided the magnitude remains relatively small. The monotonicity is accounted for the fact that the frequency of the vortex oscillations incommensurable with the proper frequency of fluid particle rotations in the steady state. Another point of interest is that it is demonstrated that bounded regions, in which the vortex may be trapped, can appear even at a significant distance from the bay. Making use of a Lagrangian indicator, examples of fluid particle advection induced by the periodic motion of the vortex inside the bay are adduced.  相似文献