Correlating specific conductivity with total hardness in limestone and dolomite karst waters     

Wies&#x;awa Ewa Krawczyk  Derek C. Ford 《地球表面变化过程与地形》2006,31(2):221-234

Under field conditions modern digital conductivity meters give standardized, rapid and reproducible measurements. Here we investigate the accuracy of their estimates of the composition of karst waters, as total hardness (TH, as mg/L CaCO₃) for limestone and dolomite. These are the fundamental measures of process in carbonate karst geomorphology. PHREEQC theoretical curves for the dissolution of pure calcite/aragonite and dolomite in water at 25 °C are compared with water analyses from karst studies worldwide. Other principal ions encountered are sulphates, nitrates and chlorides (the ‘SNC’ group). From carbonate karsts, 2309 spring, well and stream samples were divided into uncontaminated (SNC < 10%), moderately contaminated (10 < SNC < 20%), and contaminated (SNC > 20%) classes. Where specific conductivity (SpC) is less than 600 µS/cm, a clear statistical distinction can be drawn between waters having little contamination and substantially contaminated waters with SNC > 20%. As sometimes claimed in manufacturers' literature, in ‘clean’ limestone waters TH is close to ¹/2SpC, with a standard error of 2–3 mg/L. The slope of the best‐fit line for 1949 samples covering all SNC classes where SpC < 600 µS/cm is 1·86, very close to the 1·88 obtained for clean limestone waters; however, the value of the intercept is ten times higher. The regression line for clean limestone waters where SpC > 600 µS/cm helps to distinguish polluted waters from clean waters with possible endogenic sources of CO₂. In the range 250 < SpC < 600 µS/cm, dolomite waters can be readily distinguished from limestone waters. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Bellert's general relativity theory     

Ewa Rydzyńska 《Astrophysics and Space Science》1990,173(2):241-249

In this paper, new ideas from our previous paper (Rydzyska, 1989)-i.e., problems connected with the new equivalence principle-have been developed. It is conformed, that certain static particles from Bellert's space-time are equivalent to a free particle from classic Milne's space-time. Mention is made of the algebraic structure of Bellert's space-time from (Rydzyska, 1990b). The space-time interval in this space-time, and its connection with a probability and the physical meaning of this interval and probability, has been defined. In the last section we derive dynamical equations for Bellert's space-time, i.e., we do the foundations of Bellert's general relativity theory.  相似文献   

Decolourisation of Sugar Beet Molasses Vinasse by Ion Exchange     

Małgorzata Krzywonos  Aniceta Łapawa 《洁净——土壤、空气、水》2012,40(12):1408-1414

Sugar beet molasses vinasse is a by‐product of ethanol fermentation from sugar beet molasses. Its dark brown colour, which is attributable to the presence of caramels, melanoidins and invert alkaline degradation products, cannot be removed by biological methods. The novelty of this work lies in the use of conventional strongly alkaline ion‐exchange resins for the decolourisation of sugar beet molasses vinasse. The aim of the study was to determine the efficiency of two strong‐base ion‐exchange resins, Dowex 2 and Wofatit ES, when used for the decolourisation of sugar beet molasses vinasse. Optimal conditions and extent of decolourisation were related to the concentration and pH of the vinasse, the time of reaction with the resin, and also to the dose and type of the resin used. The greatest extent of decolourisation (92%) was achieved with Wofatit ES dosed in the amount of 5 g/100 mL of 25% vinasse with an initial pH of 10. The optimal time of reaction with the resin indispensable for attaining the maximal effect of decolourisation was 1.5 h for both resins. The highest extent of reduction in chemical oxygen demand (43%) during decolourisation of 25% vinasse (pH 10) was obtained with Dowex 2.  相似文献   

Seismic Hazard Evaluation Using Markov Chains: Application to the Japan Area     

F. Alejandro Nava  Claudia Herrera  José Frez  Ewa Glowacka 《Pure and Applied Geophysics》2005,162(6-7):1347-1366

Seismogenic regions within some geographic area are interrelated through tectonics and seismic history, although this relation is usually complex, so that seismicity in a given region cannot be predicted in a straightforward manner from the activity in other region(s). We present a new statistical method for seismic hazard evaluation based on modeling the transition probabilities of seismicity patterns in the regions of a geographic area during a time interval, as a Markov chain. Application of the method to the Japan area renders good results, considering the occurrence of a high probability transition as a successful forecast. For magnitudes M5.5 and time intervals t=0.10 year, the method yields a 78% aftcast (forecast of data already used to evaluate the hazard) success rate for the entire catalog, and an indicative 80% forecast success rate for the last 10 transitions in the catalog. A byproduct of the method, regional occurrence probabilities determined from the transition probabilities, also provides good results; aftcasts of regional activity have a 98% success rate, and those of activity in the highest probability region about 80.5% success rate. All results are superior to those from the null hypotheses (a memory-less Poissonian, fixed-rate, or uniform system) and have vanishingly small probabilities of resulting from purely random guessing.  相似文献   

Impact of forecasted land use changes on flood risk in the Polish Carpathians     

Marcin Szwagrzyk  Dominik Kaim  Bronwyn Price  Agnieszka Wypych  Ewa Grabska  Jacek Kozak 《Natural Hazards》2018,94(1):227-240

Flooding is a major environmental hazard in Poland with risks that are likely to increase in the future. Land use and land cover (LULC) have a strong influencing on flood risk. In the Polish Carpathians, the two main projected land use change processes are forest expansion and urbanization. These processes have a contradictory impact on flood risk, which makes the future impact of LULC changes on flooding in the Carpathians hard to estimate. In this paper, we investigate the impact of the projected LULC changes on future flood risk in the Polish Carpathians for the test area of Ropa river basin. We used three models of spatially explicit future LULC scenarios for the year 2060. We conduct hydrological simulations for the current state and for the three projected land use scenarios (trend extrapolation, ‘liberalization’ and ‘self-sufficiency’). In addition, we calculated the amount of flood-related monetary losses, based on the current flood plain area and both actual and projected land use maps under each of the three scenarios. The results show that in the Ropa river, depending on scenario, either peak discharge decreases due to the forest expansion or the peak discharge remains constant—the impact of LULC changes on the hydrology of such mountainous basins is relatively low. However, the peak discharges are very diverse across sub-catchments within the modeling area. Despite the overall decrease of peak discharge, there are areas of flow increase and there is a substantial projected increase in flood-related monetary losses within the already flood-prone areas, related to the projected degree of urbanization.  相似文献   

Effects of sample disturbance and heterogeneity on the triaxial behaviour of a Canadian oil sand at ambient and high temperatures     

Ewa Piotrowska  Morteza Mohamadi  Richard Wan 《Acta Geotechnica》2018,13(2):457-471

The present paper investigates the mechanical behaviour of oil sand specimens in triaxial compression tests at both ambient and elevated temperatures. The emphasis is particularly on core sample disturbance and on the multiphase/strongly heterogeneous nature of the material that introduces difficulties in achieving an objective characterization of its shear behaviour. First, the effect of sample disturbance on the behaviour of the oil sand is studied. Tests are performed on both disturbed and recompressed specimens. Recompression to large stress prior to shearing improves evaluation of the initial stiffness and associated volumetric changes of the oil sand, strongly affected by sample disturbance. A method for the correction of test results obtained from disturbed specimens is also proposed. The corrected results are in good agreement with those pertaining to recompressed specimens. Furthermore, a general classification of the tested oil sands into lean and rich in bitumen, where the former shows much softer and weaker behaviour, is considered to help in addressing the variability in sample composition. As for thermal aspects, the experimental results indicate that both strength and stiffness exhibit a limited temperature dependency. The temperature does not affect lean oil sand specimens, whereas heating considerably increases deformability of rich specimens.  相似文献   

Time-dependent shear velocities in channel routing     

PAWEŁ M. ROWIŃSKI  WŁODZIMIERZ CZERNUSZENKO  JEAN-MARC MARC 《水文科学杂志》2013,58(6):881-895

Abstract

The main aim of this study is the experimental investigation of friction velocities and shear stresses in rivers under unsteady flow conditions. Special measurements of mean velocities and other hydraulic parameters were made in two small lowland rivers in central Poland. Four controlled flood waves were released and analysed in the selected reaches. The main hydrometric characteristics and the relationship between water level and discharge were established. Friction velocities were obtained directly from the full St Venant equations of motion, as well as from only the steady momentum equation, and their time-dependent forms were established. Both these approaches provided similar results when the unsteadiness parameter was relatively low. It appeared that real friction velocities were much larger than those obtained from the common uniform flow formula. The passing hydrograph influenced the value of the shear velocity significantly.  相似文献   

Assessing medicinal qualities of groundwater from the Busko-Zdrój area (Poland) using the probabilistic method     

Katarzyna Wątor  Ewa Kmiecik  Barbara Tomaszewska 《Environmental Earth Sciences》2016,75(9):804

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Bioavailability and mobility of mercury in selected soil profiles     

Szymon Łucjan Różański  Jose Matias Peñas Castejón  Gregorio García Fernández 《Environmental Earth Sciences》2016,75(13):1065

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EPR and magnetism of the nanostructured natural carbonaceous material shungite     

Maria Aldona Augustyniak-Jabłokow  Yurii V. Yablokov  Bartłomiej Andrzejewski  Wojciech Kempiński  Szymon Łoś  Krzysztof Tadyszak  Mikhail Y. Yablokov  Valentin A. Zhikharev 《Physics and Chemistry of Minerals》2010,37(4):237-247

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.  相似文献