What can be deduced from open cluster metallicity measurements?     

Chris Koen  Fred Lombard 《Monthly notices of the Royal Astronomical Society》2007,382(2):693-698

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New insight into the structure of nanocrystalline ferrihydrite: EXAFS evidence for tetrahedrally coordinated iron(III)   总被引：1，自引：0，他引：1  

Fabien Maillot  Yuheng Wang  Philippe Ildefonse  Corinne Chaneac 《Geochimica et cosmochimica acta》2011,75(10):2708-9890

Ferrihydrite (Fh) is a short-range ordered nanocrystalline iron(III) (oxyhydr)oxide that has been recognized to play an important role in contaminant sequestration and in iron cycling in geological and biological systems. Despite intensive research for the two last decades, the structure of Fh is still a subject of debate. In the present study, we report extended X-ray absorption fine structure (EXAFS) spectroscopy data collected on a large set of ferrihydrites and model compounds samples including especially nano-crystalline maghemite (Mh), goethite (Gt), and akaganeite (Aka). This set of EXAFS data recorded at cryogenic temperature over a wide energy range allows us to precisely determine the Fe-O mean distance (〈Fe-O〉) in the first coordination shell of iron for this large set of iron (oxyhydr)oxides. Our EXAFS analysis includes both classical shell-by-shell fits of Fourier-filtered and unfiltered data as well as analysis of Fe-O distance distribution in the first coordination shell of iron using the Landweber iteration method. 〈Fe-O〉 determined by these complementary EXAFS analyses are similar: 〈Fe-O〉 is shorter in Mh (1.96 ± 0.01 Å) that contains 37.5% of tetrahedral iron, than in Gt (2.01 ± 0.01 Å), Aka (2.00 ± 0.01 Å) and hematite (Hm) (2.01 ± 0.01 Å) that do not contain tetrahedral iron. 〈Fe-O〉 for the five Fh samples investigated (1.97 ± 0.01 Å) was found to be slightly longer than in Mh and significantly shorter than those in Gt, Aka and Hm. This short 〈Fe-O〉 distance in Fh indicates the presence of significant amount of tetrahedrally coordinated iron(III) in all Fh samples studied, which ranges between 20 ± 5% and 30 ± 5% of total iron. In addition, our analysis of Fe-Fe distances observed by EXAFS is consistent with a Keggin-like motif at a local scale (∼5 Å) in the Fh structure.  相似文献   

Influence of sample location and livestock numbers on Sporormiella concentrations and accumulation rates in surface sediments of Lake Allos, French Alps     

David Etienne  Bruno Wilhelm  Pierre Sabatier  Jean-Louis Reyss  Fabien Arnaud 《Journal of Paleolimnology》2013,49(2):117-127

Spores of coprophilous fungi, especially Sporormiella, are often well preserved in lake sediment cores. It has been hypothesized that such spores can be used to quantify past livestock abundance. The quantitative relationship between fungal spore abundance and livestock populations, however, is not well established, nor are the mechanisms of spore transport and deposition in lacustrine systems. Multiple cores from Lake Allos, a large high-elevation lake in the French Alps, were used to map the modern abundance of Sordaria and Sporormiella spores throughout the lake. We observed high spatial heterogeneity with respect to spore numbers. No correlation with the distance from shoreline was found. There was, however, a relation with distance from the two main lake inlets. These results were used to select two fungi-rich sediment cores to investigate grazing pressure over the last two centuries. Comparisons were made between spore influx and historic data on livestock densities in the catchment. A sharp decrease in Sporormiella influx ca. 1894–1895 was associated with a reported reduction in sheep in the Allos catchment at that time. Mean influx of Sporormiella decreased by a factor of three between the nineteenth and twentieth centuries, reflecting a reduction in the reported number of animals in the Lake Allos catchment, from 6,000 to 2,000. This study confirmed that Sporormiella spore abundance in lake sediments can be used as a proxy for catchment herbivore numbers in paleoecological reconstructions. Nevertheless, our data indicate that before spore accumulation can be used to infer past domestic herbivore density, one must understand the processes of coprophilous spore transfer from the catchment to the lake and the influence of core location on spore numbers in the sediment.  相似文献   

A 70 Ma record of suprasolidus conditions in the large,hot, long‐duration Grenville Orogen          下载免费PDF全文

François Turlin  Clara Deruy  Aurélien Eglinger  Olivier Vanderhaeghe  Anne‐Sylvie André‐Mayer  Marc Poujol  Abdelali Moukhsil  Fabien Solgadi 《地学学报》2018,30(3):233-243

Petrochronology of magmatic monazite and apatite from a single paragneiss leucosome derived by in situ partial melting documents the thermal evolution of the Allochthonous Belt of the central Grenville Province. Monazite records suprasolidus metamorphism from ca. 1080 to 1020 Ma under high temperature up to 850°C. Apatite from the same leucosome yields an age of 960 Ma, consistent with cooling of this crustal segment down to subsolidus conditions of ca. 450°C. A pegmatitic granite dyke, with lobate contacts, previously dated at ca. 1005 Ma (Turlin et al., 2017 ) is interpreted to intrude the paragneisses at a temperature of ca. 650°C close to the wet‐solidus. These data document slow cooling at a rate of 2–6°C/Ma for the middle crust of this part of the Grenville hinterland marked by protracted suprasolidus conditions for at least 70 Ma. It supports the definition of the Grenville Orogen as a large, hot, long‐duration orogen.  相似文献   

Diachronic metamorphic and structural evolution of the Connecticut Valley–Gaspé trough,Northern Appalachians     

Morgann Perrot  Alain Tremblay  Gilles Ruffet  Loic Labrousse  Félix Gervais  Fabien Caroir 《Journal of Metamorphic Geology》2020,38(1):3-27

The Connecticut Valley–Gaspé (CVG) trough represents a major, orogen-scale Silurian–Devonian basin of the Northern Appalachians. From Gaspé Peninsula to southern New England, the CVG trough has experienced a contrasting metamorphic and structural evolution during the Acadian orogeny. Along its strike, the CVG trough is characterized by increasing strain and polyphase structures, and by variations in the intensity of regional metamorphism and contrasting abundance of c. 390–370 Ma granitic intrusions. In southern Quebec and northern Vermont, a series of NW–SE transects across the CVG trough have been studied in order to better understand these along-strike variations. Detailed structural analyses, combined with phase equilibria modelling, Raman spectrometry, and muscovite ⁴⁰Ar/³⁹Ar dating highlight a progressive and incremental deformation involving south–north variation in the timing of metamorphism. Deformation evolves from a D₁ crustal thickening event which originates in Vermont and progresses to southern Québec where it peaked at 0.6 GPa/380°C at c. 375 Ma. This was followed by a D₂ event associated with continuous burial in Vermont from 378 to 355 Ma, which produced peak metamorphic conditions of 0.85 GPa/380°C and exhumation in Quebec from 368 to 360 Ma. The D₃ compressional exhumation event also evolved from south to north from 345 to 335 Ma. D₁ to D₃ deformation events form part of a continuum with an along-strike propagation rate of ~50 km/Ma During D₁, the burial depth varied by more than 15 km between southern Quebec and Vermont, and this can be attributed to the occurrence of a major crustal indenter, the Bronson Hill Arc massif, in the New England segment of the Acadian collision zone.  相似文献   

New insights into the origin and evolution of Lake Vida,McMurdo Dry Valleys,Antarctica — A noble gas study in ice and brines     

Jessica L. Malone  M. Clara Castro  Chris M. Hall  Peter T. Doran  Fabien Kenig  Chris P. McKay 《Earth and Planetary Science Letters》2010,289(1-2):112-122

Unlike other lakes in the McMurdo Dry Valleys, Antarctica, Lake Vida has a thick (~ 19 m) ice cover sealing a liquid brine body of unusually high salinity (~ 245 g/L) from the atmosphere. To constrain the conditions under which the atypical Lake Vida ice cover formed and evolved, 19 ice samples were collected down to a depth of ~ 14 m, together with three brine samples trapped in the ice at ~ 16 m for analysis of helium, neon, argon, krypton, and xenon concentrations. The broad pattern of noble gas concentrations for Lake Vida samples is fundamentally different from that of air saturated water (ASW) at 0 °C and an elevation of 340 m for salinities of 0 (ice) and 245 g/L (brine). Overall, ice samples are enriched in He and depleted in Ne with saturation relative to ASW averages of 1.38 and 0.82, respectively, and strongly depleted in Ar, Kr, and Xe with relative saturations of 0.10, 0.06, and 0.05, respectively. By contrast, brine samples are generally depleted in He and Ne (relative saturation averages of 0.33 and 0.27, respectively) but enriched in Ar, Kr, and Xe, with relative saturation averages of 1.45, 3.15, and 8.86, respectively. A three-phase freezing partitioning model generating brine, ice and bubble concentrations for all stable noble gases was tested and compared with our data. Measured brine values are best reproduced for a salinity value of 175 g/L, a pressure of 1.1 atm, and a bubble volume of 20 cm³ kg^?1. Sensitivity tests for ice + bubble samples show an ideal fit for bubble volumes of ~ 1–2 cm³ kg^?1. Our results show that the conditions under which ice and brine formed and evolved at Lake Vida are significantly different from other ice-covered lakes in the area. Our brine data suggest that Lake Vida may be transitioning from a wet to a dry-based lake, while the ice + bubble data suggest at least partial re-equilibration of residual liquid with the atmosphere as ice forms at the top of Lake Vida ice cover.  相似文献   

Is there evolution in the infrared Tully–Fisher relation? Comparing two linear regressions     

Chris Koen  Fred Lombard 《Monthly notices of the Royal Astronomical Society》2009,395(3):1657-1661

In a recent paper, Puech and co-workers compared K -band Tully–Fisher relations derived for nearby and distant galaxies, respectively. They concluded that the two relations differ, and deduced that there is evolution in the Tully–Fisher relations. The statistical comparison between the two regression lines is re-examined, and it is shown that the statistical test used gives non-significant results. It is argued that better results can be obtained by comparing the 'inverse' Tully–Fisher relations, and it is demonstrated by two different methods that the nearby- and distant-sample relations do indeed differ at a very high significance level. One of the statistical methods described is non-parametric, and can be applied very generally to compare linear regressions from two different samples.  相似文献   

A Case Study of CO<Subscript>2</Subscript>, CO and Particles Content Evolution in the Suburban Atmospheric Boundary Layer Using a 2-μm Doppler DIAL,a 1-μm Backscatter Lidar and an Array of In-situ Sensors     

Fabien Gibert  Irène Xuéref-Rémy  Lilian Joly  Martina Schmidt  Juan Cuesta  Kenneth J. Davis  Michel Ramonet  Pierre H. Flamant  Bertrand Parvitte  Virginie Zéninari 《Boundary-Layer Meteorology》2008,128(3):381-401

A network of remote and in-situ sensors was deployed in a Paris suburb in order to evaluate the mesoscale evolution of the daily cycle of CO₂ and related tracers in the atmospheric boundary layer (ABL) and its relation to ABL dynamics and nearby natural and anthropogenic sources and sinks. A 2-μm heterodyne Doppler differential absorption lidar, which combines measurements of, (1) structure of the atmosphere, (2) radial velocity, and (3) CO₂ differential absorption was a particularly unique element of the observational array. We analyse the differences in the diurnal cycle of CO, CO₂, lidar reflectivity (a proxy for aerosol content) and H₂O using the lidar, airborne measurements in the free troposphere and ground-based measurements made at two sites located few kilometres apart. We demonstrate that vertical mixing dominates the early morning drawdown of CO and aerosol content trapped in the former nocturnal layer but not the H₂O and CO₂ mixing ratio variations. Surface fluxes, vertical mixing and advection all contribute to the ABL CO₂ mixing ratio decrease during the morning transition, with the relative importance depending on the rate and timing of ABL rise. We also show evidence that when the ABL is stable, small-scale (0.1-km vertical and 1-km horizontal) gradients of CO₂ and CO are large. The results illustrate the complexity of inferring surface fluxes of CO₂ from atmospheric budgets in the stable boundary layer.  相似文献   

Laser Ablation (193 nm), Purification and Determination of Very Low Concentrations of Solar Wind Nitrogen Implanted in Targets from the GENESIS Spacecraft     

Laurent Zimmermann  Pete Burnard  Bernard Marty  Fabien Gaboriaud 《Geostandards and Geoanalytical Research》2009,33(2):183-194

The GENESIS space mission recovered ions emitted by the Sun during a 27 month period. In order to extract, purify and determine the very low quantities of solar nitrogen implanted in the GENESIS targets, a new installation was developed and constructed at the CRPG (Nancy, France). It permitted the simultaneous determination of nitrogen and noble gases extracted from the target by laser ablation. The extraction procedure used a 193 nm excimer laser that allowed for surface contamination in the outer 5 nm to be removed, followed by a step that removed 50 nm of the target material, extracting the solar nitrogen and noble gases implanted in the target. Following purification using Ti and Zr getters for noble gases and a Cu-CuO oxidation cycle for N₂, the extracted gases were analysed by static mode (pumps closed) mass spectrometry using electron multiplier and Faraday cup detectors. The nitrogen blanks from the purification section and the static line (30 minutes) were only 0.46 picomole and 0.47 picomole, respectively.  相似文献   

Les minéraux techniques naturels : connaissance,typologie et propriétés d'usageNatural technical minerals: investigation,typology and utilisation properties     

Jacques Yvon  Jean-Maurice Cases  Frédéric Villiéras  Laurent Michot  Fabien Thomas 《Comptes Rendus Geoscience》2002,334(9):717-730

By nature minerals are heterogeneous materials for many of their properties. These properties also vary according to composition and structure fluctuations, compared to definitions. Technical minerals are used in applications where their performances depend on intrinsic properties and processing conditions. It is possible to base rankings on simple criteria, allowing estimating the abilities of minerals for each utilisation. The research of the corresponding mechanisms concerns the molecular level. These questions are discussed for kaolins, raw materials for baked clays, talqueous materials and montmorillonites. To cite this article: J. Yvon et al., C. R. Geoscience 334 (2002) 717–730.  相似文献