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151.
Ocean Dynamics - Marine resources are outstanding among renewable energy for their wide occurrence and diverse possibilities of exploitation. The tidal resource can be harnessed by the use of both...  相似文献   
152.
Ocean Dynamics - Near-inertial oscillations (NIO) are intermittent motions with a frequency close to the inertial frequency and represent an important fraction of the energy to the currents in the...  相似文献   
153.
This paper reports the initial results of a study of groundwater and coastal waters of southern Brazil adjacent to a 240 km barrier spit separating the Patos Lagoon, the largest coastal lagoon in South America, from the South Atlantic Ocean. The objective of this research is to assess the chemical alteration of freshwater and freshwater–seawater mixtures advecting through coastal permeable sands, and the influence of the submarine discharge of these fluids (SGD) on the chemistry of coastal waters. Here we focus on dissolved iron in this system and use radium isotopic tracers to quantify SGD and cross-shelf fluxes. Iron concentrations in groundwaters vary between 0.6 and 180 μM. The influence of the submarine discharge of these fluids into the surf zone produces dissolved Fe concentrations as high as several micromolar in coastal surface waters. The offshore gradient of dissolved Fe, coupled with results for Ra isotopes, is used to quantify the SGD flux of dissolved Fe from this coastline. We estimate the SGD flux to be 2 × 106 mol day− 1 and the cross-shelf flux to be 3.2 × 105 mol day− 1. This latter flux is equal to about 10% of the soluble atmospheric Fe flux to the entire South Atlantic Ocean. We speculate on the importance of this previously unrecognized iron input to regional ocean production and on the potential significance of this source to understanding variations in glacial–interglacial ocean production.  相似文献   
154.
Hydrogen isotope exchange between water and orthosilicic acid (H4SiO4) was modeled using B3LYP calculations and classical transition-state theory. Configurations of 1, 2, 3 and 7 water molecules and H4SiO4 were used to investigate energetically viable reaction pathways. An upper-bound of 71 kJ/mol was assumed for the zero-point energy corrected barrier (ZPECB) because this is the experimentally determined activation energy for Si-O bond breaking (Rimstidt and Barnes, 1980) and ZPECB is expected to be close to this value. Long range solvation forces were accounted for using the integral equation formalism polarized continuum model (IEFPCM; Cancès et al., 1997). Primary and secondary isotope effects were computed by exchanging hydrogen atoms with deuterium. Results show that reaction mechanisms involving 3 and 7 water molecules have ZPECB of 34 to 38 kJ/mol, whereas those involving 1 and 2 water molecules have ZPECB in excess of the set upper-bound. The lower range of ZPECB with 3 or 7 water molecules is reasonable to explain rapid hydrogen isotope exchange with silicates. Rate constant calculations accounting for tunneling, anharmonicity and scaling factors indicate that the reaction is fast and equilibrium can be assumed under most geologic conditions.  相似文献   
155.
Mitigating the potential large negative impacts of a change in the earth's climate will require strong and definite actions in the different economic sectors, particularly within agriculture and forestry. Specifically, soils deserve a close examination due to their large carbon mitigation potential. The Kyoto protocol establishes the possibility for crediting greenhouse gas emission reductions from forestry and agriculture activities. In most circumstances, particularly those regarding developing countries, greenhouse gas mitigation activities will be carried out through projects. These projects will have to meet a series of criteria, for the carbon benefits to be measurable, transparent, verifiable and certified. These criteria include: establishing credible baselines (without-project or reference scenario), additionality, permanence, quantifying and reducing potential leakage of greenhouse gases across project borders, coping with natural or human induced risks, accurately measuring changes in carbon stocks using carbon accounting techniques, and – in the case of the Clean DevelopmentMechanism – resulting in sustainable development benefits. In this paper we describe the methods and approaches that have been developed to cope with the different criteria and discuss their implications for carbon sequestration in soils. Soil carbon represents the largest carbon pool of terrestrial ecosystems, and has been estimated to have one of the largest potentials to sequester carbon worldwide. However, getting credits from soil carbon sequestration through project activities presents several challenges: the need to monitor small incremental changes in soil carbon content relative to large carbon pools, long-time periods to accrue the full carbon benefits, high local variability of soil carbon content, and relatively costly soil carbon measurement procedures. Also, the responses of soil C stocks to forestry and agriculture activities are complex and need careful attention. Specifically, the time dynamics of soil C responses to land use changes, the diversity of soil types, soil-plant interactions, and the availability of accurate soil C inventories, should be considered to successfully implement LULUCF projects.  相似文献   
156.
8000 yr of black carbon accumulation in a colluvial soil from NW Spain   总被引:1,自引:0,他引:1  
Analytical pyrolysis-GC/MS and solid-state 13C NMR (nuclear magnetic resonance) were applied to the NaOH-extractable organic matter fraction of a colluvial soil from Galicia (NW Spain) that represents more than 8500 yr of accumulation. While molecular indicators of vegetation change were looked for, it seemed likely that any such signal was disturbed by the intense fire regime of the area. This conclusion was drawn from (1) the presence of three charcoal layers, (2) the high proportion of aryl C in NMR spectra (non-quantitative) and (3) the prevalence of benzenes and polycyclic aromatic hydrocarbons (PAHs) in the chromatograms (38 ± 6% of total identified peak area), also in charcoal-poor samples. If this conclusion is accurate, the area has been subjected to burning episodes for at least 8000 yr. Additionally, the results indicate that biomass burning residues (black carbon; BC) may become NaOH extractable after long periods of degradation in mineral soil. These results add to our knowledge of the long-term fate of BC in soil, which is a potential agent in the global C cycle.  相似文献   
157.
Journal of Paleolimnology - We report organic carbon (OC) accumulation rates in three freshwater ecosystems in southern Brazil, along the largest shallow coastal lagoon ecosystem in the world, the...  相似文献   
158.
We study the foreshocks and aftershocks of the 1 April 2014 Iquique earthquake of Mw 8.1. Most of these events were recorded by a large digital seismic network that included the Northern Chile permanent network and up to 26 temporary broadband digital stations. We relocated and computed moment tensors for 151 events of magnitude Mw?≥?4.5. Most of the foreshocks and aftershocks of the Iquique earthquake are distributed to the southwest of the rupture zone. These events are located in a band of about 50 km from the trench, an area where few earthquakes occur elsewhere in Chile. Another important group of aftershocks is located above the plate interface, similar to those observed during the foreshock sequence. The depths of these events were constrained by regional moment tensor (RMT) solutions obtained using the records of the dense broad band network. The majority of the foreshocks and aftershocks were associated to the interplate contact, with dip and strike angles in good agreement with the characteristics of horst and graben structures (>2000 m offset) typical of the oceanic Nazca Plate at the trench and in the outer rise region. We propose that the spatial distribution of foreshocks and aftershocks, and its seismological characteristics were strongly controlled by the rheological and tectonics conditions of the extreme erosive margin of Northern Chile.  相似文献   
159.
160.
If cooled-down neutron stars have a thin atomic crystalline–iron crust, they must diffract X-rays of appropriate wavelength. If the diffracted beam is to be visible from Earth (an extremely rare but possible situation), the illuminating source must be very intense and near the reflecting star. An example is a binary system composed of two neutron stars in close orbit, one of them inert, the other an X-ray pulsar. (Perhaps an “anomalous” X-ray pulsar or magnetar, not powered by gas absorption from the companion or surrounding space, would be the cleanest example.) The observable to be searched for is a secondary peak added (quasi-) periodically to the main X-ray pulse. The distinguishing feature of this secondary peak is that it appears at wavelengths related by simple integer numbers, λ,λ/2,λ/3,…,λ/n because of Bragg’s diffraction law.  相似文献   
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