Iron in silicate glasses of granitic composition: a Mössbauer spectroscopic study     

Beate Spiering  Friedrich A. Seifert 《Contributions to Mineralogy and Petrology》1985,90(1):63-73

⁵⁷Fe Mössbauer spectra of natural glasses (pumices and obsidians) and of synthetic glasses of granitic composition have been analyzed. — Ferric iron is found in tetrahedral coordination if enough M⁺-cations are available to balance the charge of both M⁺Fe³⁺O₂ and M⁺AlO₂ complexes. In other compositions the ratio of tetrahedrally to octahedrally coordinated Fe³⁺ depends on the ratio of mono-to divalent cations. — Ferrous iron occurs in two distinctly different octahedral sites. The existence of these sites can be attributed to different anionic units adjacent to Fe²⁺. The degree of polymerization of these units is reflected in the quadrupole splitting. The anionic units adjacent to Fe²⁺ are depolymerized for increasing mean Z/r ² of the network modifiers, which do not stabilize M³⁺ in the tetrahedra by local charge balance. — Increasing pressure diminishes the geometric differences between these types of ferrous iron-oxygen-octahedra, which gives rise to a more even distribution of Fe²⁺ among these sites and thereby to an ordering in the network of melts.  相似文献   

Methoden zur Weltklimatologie der Hydrometeore. Der Anteil des festen Niederschlags am Gesamtniederschlag     

Univ.-Prof. Dr. Friedrich Lauscher 《Theoretical and Applied Climatology》1976,24(3):129-176

  相似文献   

The transformation of amorphous silica to crystalline silica under hydrothermal conditions     

Peter Bettermann  Friedrich Liebau 《Contributions to Mineralogy and Petrology》1975,53(1):25-36

Hydrothermal syntheses were made mainly in the binary system SiO₂-H₂O in a temperature range between 300 ° C and 500 ° C and pressures from 0.2 kbar up to 4.0 kbar with various starting materials. In this way the transformation behavior of different amorphous silicas via cristobalite and keatite to quartz were observed. This behavior depends mainly on the parameters: pressure, temperature, run duration and state of the starting material. Four reaction paths have been observed: in most experiments the complete reaction sequence “amorphous silica→cristobalite→keatite→quartz” took place. Less often the reactions: “amorphous silica→cristobalite→quartz” and: “amorphous silica→keatite→quarts” were observed. Very few samples were found with a direct transition of amorphous silica into quartz at high pressures. A kinetic model is given in form of a pressure-temperature-time diagram of the system SiO₂-H₂O under hydrothermal conditions.  相似文献   

Über einen Keuperton von Zaisersweiher bei Maulbronn     

Dr. Friedrich Lippmann 《Contributions to Mineralogy and Petrology》1954,4(1-2):130-134

Zusammenfassung Durch röntgenographisehe und differentialthermoanalytische Untersuchungen wurde in einem roten Keuperton (km 3) von Zaisersweiher bei Maulbronn ein quellfähiges chloritisches Mineral (Corrensit) als Hauptbestandteil gefunden, das sick durch doppelten Basisabstand (28 Å) auszeichnet. Daneben treten Illit (Glimmer) und Quarz auf. Nebengemengteile sind Hämatit und Feldspat.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.  相似文献   

Sc- and REE-bearing ixiolite and associated minerals from the Sosedka pegmatite vein in the Malkhan pegmatite field, central Transbaikal region     

E. V. Badanina  V. V. Gordienko  A. Wiechowski  G. Friedrich 《Geology of Ore Deposits》2008,50(8):772-781

Composition and localization of REE mineralization in miarolitic pegmatites and its role in the pegmatite formation were studied at the Malkhan gem deposit (jewel-quality tourmaline, morganite, danburite, and hambergite) in the central Transbaikal region. The chemical composition of Ti-, Ta-, Nb- and REE-bearing minerals, their relationships with rock-forming and accessory minerals indicate that two geochemically specialized stages of pegmatite formation are distinguished. The early stage gave rise to the crystallization of quartz-feldspar aggregates including K-feldspar block zone with Sc and REE mineralization. The rare-metal (Li, Cs, F, B, Be) albite-lepidolite-cleavelandite complex with pockets of gem mineralization was formed at the late stage.  相似文献   

Über interne Gezeitenwellen und ihre Stabilitätsbedingungen     

A. Defant 《Meteorology and Atmospheric Physics》1948,1(1):39-61

  相似文献   

News from the Lower Ionosphere: A Review of Recent Developments   总被引：1，自引：1，他引：0  

M. Friedrich  M. Rapp 《Surveys in Geophysics》2009,30(6):525-559

Current knowledge concerning the lower ionosphere (D- and E-region) is reviewed with an emphasis on new aspects of empirical results. Starting with an overview of experimental techniques and corresponding data bases, both regarding charged as well as the most relevant neutral constituents of this altitude range, the ionospheric variability is discussed both concerning regular (e.g. diurnal and seasonal) as well as irregular variations (e.g. driven by the variability of nitric oxide). We then turn to ‘new players’ in the lower ionosphere, i.e. charged aerosol particles such as mesospheric ice particles in noctilucent clouds or polar mesospheric summer echoes and meteor smoke particles originating from ablated meteoric matter. These species have received considerable attention in recent years, in part because it is speculated that observations of their properties might be useful for the detection of climate change signals. The available experimental data base regarding these species is reviewed and we show that there is now compelling evidence for the ubiquitous presence of these very heavy charge carriers throughout the lower ionosphere. While many fundamental details regarding these charged species are not yet completely understood, this emphasizes that charged aerosol particles may not be neglected in a comprehensive treatment of the lower ionospheric charge balance and related phenomena. Finally, we close with suggestions for future research.  相似文献   

Geomorphometric feature analysis using morphometric parameterization and artificial neural networks   总被引：3，自引：0，他引：3  

Amir Houshang Ehsani  Friedrich Quiel 《Geomorphology》2008,99(1-4):1-12

This paper presents a semi-automatic method using an unsupervised neural network to analyze geomorphometric features as landform elements. The Shuttle Radar Topography Mission (SRTM) provided detailed digital elevation models (DEMs) for all land masses between 60°N and 57°S. Exploiting these data for recognition and extraction of geomorphometric features is a challenging task. Results obtained with two methods, Wood's morphometric parameterization and the Self Organizing Map (SOM), are presented in this paper.Four morphometric parameters (slope, minimum curvature, maximum curvature and cross-sectional curvature) were derived by fitting a bivariate quadratic surface with a window size of 5 by 5 to the SRTM DEM. These parameters were then used as input to the two methods. Wood's morphometric parameterization provides point-based features (peak, pit and pass), line-based features (channel and ridge) and area-based features (planar). Since point-based features are defined as having a very small slope when their neighbors are considered, two tolerance values (slope tolerance and curvature tolerance) are introduced. Selection of suitable values for the tolerance parameters is crucial for obtaining useful results.The SOM as an unsupervised neural network algorithm is employed for the classification of the same morphometric parameters into ten classes characterized by morphometric position (crest, channel, ridge and plan area) subdivided by slope ranges. These terrain features are generic landform element and can be used to improve mapping and modeling of soils, vegetation, and land use, as well as ecological, hydrological and geomorphological features. These landform elements are the smallest homogeneous divisions of the land surface at the given resolution. The result showed that the SOM is an efficient scalable tool for analyzing geomorphometric features as meaningful landform elements, and uses the full potential of morphometric characteristics.  相似文献   

On Modeling Dry Deposition of Long-Lived and Chemically Reactive Species over Heterogeneous Terrain     

G. Tetzlaff  R. Dlugi  K. Friedrich  G. Gross  D. Hinneburg  U. Pahl  M. Zelger  N. Mölders 《Journal of Atmospheric Chemistry》2002,42(1):123-155

An explicit multi-layer subgrid-scheme was developed for ameso-/-scale model to consider subgrid-scale surface heterogeneity, dry deposition, biogenic and anthropogenic emission of trace gases. Since dry deposition measurements of highly reactive trace species are scarce we try to evaluate this scheme by heuristic principles. The results of simulations conducted for a 5×5 km² resolution with and without thisscheme are evaluated by using results of a model run with 1×1 km²resolution, which is taken as a `grand thruth' and which has the same resolution as the subgrid. The explict multi-layer subgrid scheme provides a similar distribution of dry deposition fluxes as the much more computationally expensive simulation with the 1×1 km² resolution.Dry deposition fluxes determined from observations give evidence that the explicit multi-layer subgrid scheme which does not require a constant flux approximation for a layer of several decameters leads to an improvement in determining the exchange between the atmosphere and the ground.Results of simulations with a microscale model show that the inhomogeneity at forest edges leads to an increase of the turbulent transports of up to a factor 4 compared to horizontally homogeneous terrain, which is assumed to be the conditions of the subgrid cells (and which is usually the assumption for the entire grid cell in mesoscale models). Inhomogeneity inside an extended stand of trees causes an overall increase of 5–10% withhigh local extremes, i.e. such an inhomogeneity results to an underestimation of dry deposition in meso-/-scale models. The effects are most pronounced for a wind direction perpendicular to the forest edge.  相似文献   

An experimental evaluation of mineral-specific comminution     

Mark J. Cintala  Friedrich Hrz 《Meteoritics & planetary science》1992,27(4):395-403

Abstract— Early “regolith-evolution” experiments using fragmental, polycrystalline gabbro targets displayed mineral-specific comminution trends, with feldspar being significantly fractionated into the finest grain sizes. Since planetary regoliths are similar mixtures of lithic and monomineralic detritus, the comminution of monomineralic grains is important in understanding the evolution of such regoliths. Particulate targets of monomineralic feldspar, olivine, pyroxene, and quartz therefore were subjected to at least 25 impacts each to complement the previous gabbro-based investigations. Stainless-steel projectiles 3.18 mm in diameter were launched at the targets at nominal velocities of 1.4 km s^?1, depositing an average of about 2.6 × 10⁶ ergs per g of target per impact. The quartz and feldspar comminuted most readily, while olivine and pyroxene were the most resistant. In addition, the feldspar and quartz were virtually indistinguishable in terms of any measure of comminution used here. The behavior of the olivine differed somewhat from that of the pyroxene, but the variation between these two minerals was much less than the difference between them and the tectosilicates. The apparent energy required to create new surfaces through comminution was about a factor of two higher for the mafic minerals. Densities of pre-existing cracks and other crystal defects depend on sample preparation techniques, among other things, and appear to play a notable role in the early evolution of these “regoliths.” It is probable that the history of a particular regolith's parent rocks will exert a comparable influence on the early stages of evolution of a planetary regolith. The trends for the individual targets in these monomineralic series duplicated those exhibited by the gabbro charges, leading to the general conclusion that mineral-specific comminution will occur during repetitive impact of planetary surfaces, whether they comprise freshly excavated, large blocks, or highly comminuted, clastic fines containing substantial fractions of monomineralic debris. This mineral-specific behavior will cause small grain sizes in planetary regoliths to be substantially fractionated relative to coarse regolith components, and especially relative to their source rocks.  相似文献