Constraints of stable isotopes on the origin of alunite from advanced argillic alteration systems in Bulgaria     

C. Lerouge  A. Kunov  C. Flhoc  S. Georgieva  A. Hikov  J.L. Lescuyer  R. Petrunov  N. Velinova 《Journal of Geochemical Exploration》2006,90(3):166-182

Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H₂S/SO₄ ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H₂S/SO₄ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems.  相似文献   

Neoproterozoic alkaline magmatism at Sivamalai, southern India     

D. Upadhyay  S. Jahn-Awe  C. Pin  J.L. Paquette  I. Braun 《Gondwana Research》2006,10(1-2):156

The Sivamalai alkaline complex lies at the southern margin of the Cauvery Shear System that separates the Archaean and Proterozoic domains of the Southern Granulite Terrain in India. U–Pb TIMS dating of zircon from a pegmatitic syenite sample in the complex yields a concordant age of 590.2 ± 1.3 (2σ) Ma which is interpreted to date the intrusion of the alkaline rocks. A lower concordia intercept at 168 ± 210 Ma defined by two grains with high common lead may indicate post-magmatic disturbances due to recrystallisation which is also evident in the CL images of the zircons. EPMA dating of monazite from a post-kinematic pegmatite which intrudes the crystalline basement hosting the alkaline rocks yields an age of 478 ± 29 (2σ) Ma and provides a lower bracket for the main phase of tectonism in this part of the Southern Granulite Terrain. The Pan-African high-grade metamorphism and ductile deformation has thus most likely affected the alkaline rocks. This is supported by the presence of a metamorphic foliation and extensive recrystallisation textures seen in the rocks. The major and trace element concentrations measured on selected samples reveals the presence of both enriched and depleted rock types. The enriched group includes ferrosyenite and nepheline syenite while the depleted group has only nepheline syenites. The trace element depletion of some nepheline syenites is interpreted to be a result of fractional crystallization involving the removal of accessory phases like zircon, titanite, apatite and allanite.  相似文献   

Experimental evaluation of biases associated with sampling estuarine fishes with seines     

Mark A. Steele  Stephen C. Schroeter  Henry M. Pace 《Estuaries and Coasts》2006,29(6):1172-1184

Beach seines are widely used to estimate the density and species richness of fishes in estuaries. We evaluated the causes and extent of bias in estimates from seines using a series of field experiments in small estuaries in southern California, USA. Seining in spatially paired areas that were either enclosed by block nets or not, revealed that seines used without block nets und erestimated density by more than 4-fold and species richness by more than 2-fold relative to blocked areas. Seining in paired blocked areas with seines of two lengths revealed that net length affected estimates of density, but not species richness; a 7.6-m long seine produced 1.6-fold higher estimates of total density than did a 15.2-m long seine due to increased catches of demersal fishes, but not midwater species. Paired sampling in blocked areas also revealed that many fishes initially evaded capture by the seine. Estimates of density but not species richness were significantly higher in areas through which a seine was swept 5 times compared to once. This was due to higher catches of demersal fishes but not midwater fishes in areas seined 5 times. Repeated seining through blocked areas revealed that the vast majority (90% or more) of species and individuals of midwater fishes were captured within the first 5 sweeps, compared to only about 50% of the individuals of demersal species. A mark-recapture study in blocked areas revealed lower probabilities of capture for demersal species relative to midwater species.  相似文献   

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales     

C. F. Jago  A. K. Ishak  S. E. Jones  M. R. G. Goff 《Estuaries and Coasts》2006,29(2):197-208

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.  相似文献   

Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents: a hypothesis     

Nils G Holm  Marion Dumont  Magnus Ivarsson  Cécile Konn 《Geochemical transactions》2006,7(1):7-7

Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150°C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other – brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor.  相似文献   

Sampling characteristics and biases of enclosure traps for sampling fishes in estuaries     

Mark A. Steele  Stephen C. Schroeter  Henry M. Page 《Estuaries and Coasts》2006,29(4):630-638

We evaluated the sampling characteristics of enclosure traps in estuaries in southern California, USA. Using enclosure traps that sampled 0.25, 0.5, and 1-m² footprints, we found that enclosure trap size significantly affected estimates of fish density and the precision of these estimates. The highest estimates were produced by the 0.5-m² trap and the lowest by the 0.25-m² trap. Precision of the density estimates improved with increasing trap size, while the proportion of zero values in the data sets decreased and estimates of species richness increased. The largest trap was difficult to use in the field and often did not function properly; thus we concluded that intermediate enclosure trap sizes offered the best compromise between statistical and logistical considerations. By examination of burrows in sediment cores taken in fished out enclosure traps, we found no evidence to support the widely held view that burrow-dwelling fishes evaded capture by hiding in burrows. We also used mark-recapture techniques to estimate recovery efficiency in 0.43-m² enclosure traps. Recovery efficiency averaged 91% and did not differ significantly among estuaries or sampling stations within estuaries. Based on extensive netting within enclosure traps, we determined that in areas with dense fish populations (>90 fish 0.43-m⁻²), netting could be ceased after the first sweep that captured no fish with only a trivial effect on the estimate of density. In more sparsely populated areas, netting had to continue until 2–3 sweeps had captured no fish in order to obtain estimates of density that were within 90% of the actual values present. Overall, we found enclosure traps to be effective tools for sampling small, abundant fishes in shallow estuaries in southern California, but we recommend that care be taken when choosing trap size and sampling (netting) effort within traps in order to optimize their sampling characteristics.  相似文献   

Reply to comment on our paper “evolution of tidal creek networks in a high sedimentation environment: A 5-year experiment at Tijuana Estuary, California”     

John C. Callaway  Katy J. Wallace  Joy B. Zedler 《Estuaries and Coasts》2006,29(6):1268-1270

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Effects of Hurricane Ivan on water quality in Pensacola Bay, Florida     

James D. Hagy  John C. Lehrter  Michael C. Murrell 《Estuaries and Coasts》2006,29(6):919-925

Pensacola Bay, Florida, was in the strong northeast quadrant of Hurricane Ivan when it made landfall on September 16, 2004 as a category 3 hurricane on the Saffir-Simpson scale. We present data describing the timeline and maximum height of the storm surge, the extent of flooding of coastal land, and the magnitude of the freshwater inflow pulse that followed the storm. We computed the magnitude of tidal flushing associated with the surge using a tidal prism model. We also evaluated hurricane effects on water quality using water quality surveys conducted 20 and 50 d after the storm, which we compared with a survey 14 d before landfall. We evaluated the scale of hurricane effects relative to normal variability using a 5-yr monthly record. Ivan's 3.5 m storm surge inundated 165 km² of land, increasing the surface area of Pensacola Bay by 50% and its volume by 230%. The model suggests that 60% of the Bay's volume was flushed, initially increasing the average salinity of Bay waters from 23 to 30 and lowering nutrient and chlorophylla concentrations. Additional computations suggest that wind forcing was sufficient to completely mix the water column during the storm. Freshwater discharge from the largest river increased twentyfold during the subsequent 4 d, stimulating a modest phytoplankton bloom (chlorophyll up to 18 μg l⁻¹) and maintaining hypoxia for several months. Although the immediate physical perturbation was extreme, the water quality effects that persisted beyond the first several days were within the normal range of variability for this system. In terms of water quality and phytoplankton productivity effects, this ecosystem appears to be quite resilient in the face of a severe hurricane effect.  相似文献   

Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems     

R.E. Villanueva  R.M. Prol-Ledesma  M.A. Torres-Vera  C. Canet  M.A. Armienta  C.E.J. de Ronde 《Journal of Geochemical Exploration》2006,89(1-3):414

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.  相似文献   

Temperature–composition–time (T–X–t) data from authigenic K-feldspar: An integrated methodology for dating fluid flow events     

Darren F. Mark  John Parnell  Simon P. Kelley  Sarah C. Sherlock 《Journal of Geochemical Exploration》2006,89(1-3):259

Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data.  相似文献