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141.
Ohne ZusammenfassungDas Manuskript wurde in etwas ausführlicherer Form von der Naturw.-Mathem. Fakultät der Ruprecht Karl-Universität in Heidelberg im Februar 1953 als Dissertation angenommen.  相似文献   
142.
Zusammenfassung Aus Windprofilmessungen in feststehenden H?hen über den Wellenk?mmen lassen sich keine zuverl?ssigen Schlüsse über die effektive Schubkraft des Windes an der Meeresoberfl?che ziehen. Der Grund liegt im wesentlichen in der verschiedenartigen vertikalen Windgeschwindigkeitsverteilung über Wellenbergen und Wellent?lern und in der Tatsache, da? die Windprofilmessungen im wesentlichen nur das Windprofil über den Bergen widerspiegeln. Der Versuch, die Windprofilmessungen zu „reduzieren“, ist mit zu gro?en Fehlern behaftet, zeigt aber qualitativ eine systematische Erh?hung der aus Windmessungen berechneten Reibungsfaktoren an. Damit kann der Anschlu? an die aus Windstaubeobachtungen ermittelten Reibungsfaktoren gewonnen werden, so da? der vermeintliche „Sprung“ von einer „glatten“ zu einer „rauhen“ Grenzfl?che verschwindet, und eine „kritische Windgeschwindigkeit“, die diesen Sprung angeben soll, gar nicht existiert.
On the problem of the “critical wind velocity” at the air — sea boundary surface
Summary From the measurements of wind profiles at fixed heights above the wave crests no reliable conclusions can be drawn with regard to the wind's effective shearing force at the sea surface. This is essentially due to the diversified vertical distribution of the wind speed above the waves' crests and troughs as well as to the fact that when measuring wind profiles above the waves it is mainly the profiles above the wave crests that are obtained. Attempts to “reduce” wind profiles have proved to be subject to considerable errors; however, they show qualitatively a systematic increase of the frictional factors as computed from wind measurements. This links up with the frictional factors ascertained from observations of the wind effect so that the supposed “leap” from a “smooth” to a “rough” boundary surface and the “critical wind speed” corresponding to this leap do not exist at all.
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143.
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145.
Surface samples, mostly from abyssal sediments of the South Atlantic, from parts of the equatorial Atlantic, and of the Antarctic Ocean, were investigated for clay content and clay mineral composition. Maps of relative clay mineral content were compiled, which improve previous maps by showing more details, especially at high latitudes. Large-scale relations regarding the origin and transport paths of detrital clay are revealed. High smectite concentrations are observed in abyssal regions, primarily derived from southernmost South America and from minor sources in Southwest Africa. Near submarine volcanoes of the Antarctic Ocean (South Sandwich, Bouvet Island) smectite contents exhibit distinct maxima, which is ascribed to the weathering of altered basalts and volcanic glasses. The illite distribution can be subdivided into five major zones including two maxima revealing both South African and Antarctic sources. A particularly high amount of Mg- and Fe-rich illites are observed close to East Antarctica. They are derived from biotite-bearing crystalline rocks and transported to the west by the East Antarctic Coastal Current. Chiorite and well-crystallized dioctaedral illite are typical minerals enriched within the Subantarctic and Polarfrontal-Zone but of minor importance off East Antarctica. Kaolinite dominates the clay mineral assemblage at low latitudes, where the continental source rocks (West Africa, Brazil) are mainly affected by intensive chemical weathering. Surprisingly, a slight increase of kaolinite is observed in the Enderby Basin and near the Filchner-Ronne Ice shelf.

The investigated area can be subdivided into ten, large-scale clay facies zones with characteristic possible source regions and transport paths. Clay mineral assemblages of the largest part of the South Atlantic, especially of the western basins are dominated by chlorite and illite derived from the Antarctic Peninsula and southernmost South America and supported by advection within the Circumantarctic Deep Water flow. In contrast, the East Antarctic provinces are relatively small. Assemblages of the eastern basins north of 30°S are strongly influenced by African sources, controlled by weathering regimes on land and by a complex interaction of wind, river and deep ocean transport. The strong gradient in clay mineral composition at the Brazilian slope indicate a relatively low contribution of tropically derived assemblages to the western basins.  相似文献   

146.
Dissolved organic nitrogen (DON), dissolved organic carbon (DOC) and inorganic nutrient concentrations were determined in samples from an area encompassing the Northeast Water Polynya from June to August 1993. In June, still ice-covered polynya area surface waters (PySW) had significantly higher (p<0.05) DOC concentrations (110 μM, n=68) than surface water outside the polynya area (96 μM, n=6). Melting ice and ice algae are suggested as DOC sources. DOC concentrations found in this study are consistent with other studies showing higher DOC concentrations in the Arctic than in other ocean areas. As the productive season progressed, DOC concentrations in Polynya surface water (PySW) decreased (p<0.05) from 110 to 105 μM, while DON concentrations increased (p<0.05) from 5.6 to 6.1 μM, causing a significant decrease (p<0.05) in the C : N ratios of DOM from spring (C : N ratio 20) to summer (C : N ratio 17). We found a significant (p<0.05) decrease in the DOM C : N ratio in all water masses within the polynya area as the productive season progressed. DON was the largest fraction of total dissolved nitrogen (TDN) in PySW and surface waters outside the polynya area. TDN was calculated as the sum of DON, nitrate, nitrite and ammonium concentrations. DON increased (p<0.05) from 62% to 73% of TDN in PySW from spring to summer, a result of increasing DON concentrations and decreasing inorganic nitrogen concentrations over the productive season. The seasonal accumulation of DON and the corresponding decrease in nitrate concentrations in waters with primary production indicate that it is important to take the DON pool into account when estimating export production from nitrate concentration decreases in surface waters. PySW TDN concentrations decreased (p<0.05) from 9.1 (n=61) to 8.6 μM (n=60) from spring (May 25 through June 19) to summer (July 1 through July 27). The seasonal decrease in surface water TDN concentrations corresponded to increases in TDN concentrations in deeper water masses within the Polynya. Most of the TDN increase in deep water was in the form of DON. A possible explanation is that PON was dissolved (partially remineralized) in the water column at mid depths, causing increases in the DON concentration. Transfer of N from PySW (with a short residence time in the polynya area) to Polynya Intermediate Water and deep waters of the Norske and Westwind Trough with multi-year residence times keeps N from leaving the polynya area. In spring, nutrients from degradation of OM in PyIW could support primary production. The role of PyIW as an OM trap could be important in supporting primary production in the polynya area.  相似文献   
147.
The course of crystallization of basalt forming clinopyroxenes in the olivine-basalt-hawaiite-mugearite-trachyte-and basanitoid (= basanite)-series from the Hocheifel area (Western Germany) has been presented by the author in two earlier papers (Hucken-holz, 1965 a, 1965 b). The present paper deals with the evolution of clinopyroxenes from the ankaramites in the same area. The ankaramites are richer in olivines and clinopyroxenes than the normal olivine basalts and may be a product of accumulation of olivines and clinopyroxenes in an olivine basalt magma. The first clinopyroxene formed in the ankaramites is a greenish chromian salite Ca47.1 Mg40.9 Fe12.0 which is preserved in the cores of the phenocrysts. Strongly zoned brown titansalite Ca45 Mg42Fe13 surrounds the chromian salite (HF 5) or appears in independent microphenocrysts (HF53). The groundmass clinopyroxene is titansalite Ca45Mg37Fe18 with a small optic axial angle. Phenocrysts of nickel-rich olivine Fe12–14 and chrome spinell were formed together with chromium clinopyroxene. The same minerals together with orthopyroxenes have been observed in the olivine basalts, hawaiites and basanitoids (= basanites). This paragenesis indicates high pressure and high temperature in the alkali basalts of the Hocheifel during an initial stage of magmatic evolution. With the decrease of pressure, mineral reaction occurred with the alkali basalt melt. The high pressure clinopyroxenes of the ankaramites and basanitoids (= basanites) were changed to a larger extent than the clinopyroxenes of the olivine basalts and hawaiites or were completely destroyed (HF 53) because they are in contact with the hot magma for a longer period of time. This favours the reaction between the solids and the melt, and the high pressure garnet and/or enstatite components in the clinopyroxenes are substituted by Ca-Tschermak’s and titanaugite molecules.   相似文献   
148.
We describe the fabrication of organically modified sol–gel (ORMOSIL) planar optodes for mapping the two-dimensional oxygen distribution in sediments. All sensor foils were based on the use of ruthenium(II)-tris-(4,7-diphenyl-1,10-phenantrolin)-perchlorate, which is a fluorescent dye quenched dynamically by oxygen. Sensors made with different sol–gel immobilisation matrices, different concentrations of precursors and indicator dye, as well as different types of scattering particles co-immobilised in the sensor foil were investigated systematically. Optimal sensor performance was obtained with dye concentrations of 2–10 mmol/kg in an immobilisation matrix made of diphenyldiethoxy-silan and phenyltriethoxy-silan precursors with addition of organically coated TiO2 particles. The sensors exhibited a good mechanical stability and a high sensitivity from 0% to 100% oxygen, which remained constant over at least 36 days. The planar optodes were used with a fluorescent lifetime imaging system for direct mapping of the spatio-temporal variation in oxygen distribution within marine sediment inhabited by the polychaete Hediste diversicolor. The measurements demonstrated the spatio-temporal heterogeneity of the oxygen distribution in bioturbated sediments due to burrow structures and non-constant irrigation activity of the polychaete, which is difficult to resolve with microsensors or with traditional biogeochemical techniques.  相似文献   
149.
Total suspended matter was collected along the Yangtze River (Changjiang) and in the East China Sea in April to May and in September 2003, respectively, to study origin and fate of particulate organic nitrogen. Concentrations of particulate organic carbon (POC), nitrogen (PN) and hydrolyzable particulate amino acids (PAA; d- and l-enantiomers) were higher in the Yangtze Estuary than in the river and decreased offshore towards the shelf edge. In the coastal area, higher values of PAA were observed in the surface layer than in the bottom water. Stable carbon isotope ratios (δ13C) of POC increased from − 24.4‰ in the river to values around − 21‰ on the East China Sea Shelf. Dominant amino acids were aspartic acid + aspartine (Asx), glutamic acid + glutamine (Glx), glycine, alanine and serine. The proportions of Asx, Glx and isoleucine were higher in the marine than in the riverine samples contrary to the distributions of glycine, alanine, threonine and arginine. The proportions of d-amino acids were highest in the riverine suspended organic matter (6% of PAA) decreasing towards the shelf edge (1.5% of PAA). d-arginine, not reported in natural aquatic samples so far, was the most abundant d-amino acid in the river. The amino acid composition of the particulate organic matter (POM) in the Yangtze River indicates an advanced stage of degradation of POM. Highly degraded organic matter from soils is probably a main source of POM in the Yangtze River, but the relatively high δ13C values and low C/N ratios (7.7 ± 1.6) also indicate contribution from anthropogenic sources. The degraded riverine material was a dominant organic matter source in the estuary, where aquatic primary production had only a small overall contribution. In the East China Sea, gradual settling of riverine organic matter and the addition of fresher phytoplankton impacted the amino acid composition and δ13C values, and on the outer shelf relatively fresh phytoplankton-derived organic matter dominated.  相似文献   
150.
The Baltic Shield of northern Europe is transsected by approximately N-S and NW-SE striking Proterozoic fault and fracture zones that were remobilized during the Late Precambrian opening of the Iapetus ocean and the SE-directed thrusting of the Caledonian nappes in Mid-Paleozoic time. Remobilizations of these older structures account for a distinct subsidence history and sedimentological evolution over each fault-bounded basement segment during opening of the Iapetus and for a distinct metamorphic and structural development found within each block during overthrusting of the Caledonian nappes and the exhumation of the orogen. The two fault sets define basement blocks with rhombus-like plan sections which had individual subsidence histories during Iapetus rifting as is expressed by their Late Precambrian (Riphean and Vendian) to Silurian sedimentary cover of contrasting thickness and facies. This contrasting subsidence history of the various basement blocks may have contributed to differences in thrusting level, thrust excision (nappe size), and tectonic style. Correlative Caledonian nappes from adjacent faultbounded basement blocks were thrust diachronously resulting in transport transverse to the general thrusting direction. Thrusting oblique to the NW-SE fault zones and orogen parallel extension resulted in lateral-ramp folds in the cover and reactivation along the NW-SE faults imbricated the overlying nappes. The extent of basement imbrication and duplex formation is variable in the different segments. Within single segments, the basement imbrication and duplex-formation defined basement highs that roughly align in two parallel zones within the orogen. The site of the basement duplexes is probably controlled by older N-S fracture zones while the pinch- and-swell structure parallel to the orogen is caused by the individual deformation and thrusting behavior of the basement and cover sequences that are bound by the NW-SE fault zones. Thus the Caledonian orogen appears to have inherited the Precambrian structural grain of the underlying, Baltic Shield.
Zusammenfassung Der Baltische Schild Nordeuropas ist von im Proterozoikum angelegten Verwerfungen und Scherzonen mit nördlichem sowie und nordwestlichem Streichen durchzogen, welche während der spätpräkambrischen Öffnung des Iapetus-Ozeanes und der anschließenden, südöstlich gerichteten Überschiebung der kaledonischen Decken im ausgehenden Alt-Paläozoikum reaktiviert worden sind. Die Wiederbelebung dieses ererbten, durch steilstehende Störungen gekennzeichneten, rhombenförmigen Strukturmusters führte zu unterschiedlichen Absenkungsraten der Störungsbegrenzten Grundgebirgsblöcke und steuerte somit die Ablagerungsbedingungen in entstehenden Sedimentationströgen während der Öffnungsphase des Iapetus-Ozeans. Durch diesen Prozeß lassen sich latterale Unterschiede in Mächtigkeit und Fazies der jungpräkambrischen bis altpaläozoischen Deckensedimente entlang dem Nordwestrande des damaligen Kontinentes Baltica, sowie Differenzen in der metamorphen und strukturellen Entwicklung der durch Störungen begrenzten Blöcke während der Überschiebung der kaledonischen Decken und der Hebung des Gebirges erklären. Vertikale Blockverschiebungen und Kippungen von Blöcken relativ zueinander können beobachtete Unterschiede in den Abscherungs- und Überschiebungsniveaus, sowie unterschiedliche tektonische Baustile auf und vor (vor allem) zwischen Blöcken erklären helfen. Untereinander korrelierbare kaledonische Deckensegmente haben, in Bezug auf Transportrichtung und Strecke, voneinander unterschiedliche Wege oberhalb ihrer Untergrundsegmente zurückgelegt. Während dieser Überschiebung auf ein sich simultan veränderndes Relief ist es dabei zu Teilbewegungen schräg zur Hauptüberschiebungsrichtung gekommen, was seinerseits zu seitlichen Verzahnungen benachbarter Deckensegmente geführt hat. Die NWSE streichenden Blockgrenzen haben während lokaler Überschiebungen leicht schräg zu dieser Hauptrichtung als Widerlager und Rampen (lateral ramps) für die darübergleitenden Decken gewirkt, welche sich ihrerseits bei diesem Prozeß in orogentransversale Falten gelegt haben. Je nach ihrer Lage und Neigung sind die verschiedenen Segmente während der Kollisionsphase des kaledonischen Orogens in unterschiedlichem Grade von internen Störungen betroffen worden. Die durch intensive Internscherung hervorgerufenen Krustenverdickungen zeigen eine perlschnurartige Anordnung in zwei orogenparallele zonen, deren Anlage sich auf unterliegende und mitverfrachtete N-S Störungszonen zurückführen lassen kann. Das Anschwellen und Ausdünnen (pinch- and-swell) von tektonischen Einheiten entlang der Längsrichtung des Orogens läßt sich durch unterschiedliche Deformationsverhalten innerhalb der durch NW-SE Störungen begrenzten Segmente erklären. Die Kaledoniden Skandinaviens haben offensichtlich das strukturelle Gepräge ihrer präkaledonischen Unterlage ererbt.

Résumé Le bouclier baltique est traversé par des fractures protérozoïques orientées approximativement N-S et NW-SE. Ces failles furent réactivées d'abord au Précambrien tardif lors de l'extension correspondant à l'ouverture de l'Océan lapétus, ensuite au Protérozoïque moyen lors du charríage des nappes calédoniennes vers le SE. La réactivation de ces vieilles structures explique qu'on observe pour chaque bloc du socle faillé une subsidence et une sédimentation différente pendant la phase d'extension (ouverture du lapétus), ainsi qu'une évolution métamorphique et structurale distincte pendant le charriage des nappes calédoniennes et l'exhumation de l'orogène. Les deux groupes de failles définissent dans le socle des blocs à sections rhombiques qui présentaíent chacun une subsidence particulière pendant l'ouverture du lapétus, comme l'indiquent les variations d'épaisseur et de facies de leur couverture sédimentaire tardi-précambrienne (vendienne) à silurienne. Cette subsidence variable selon les blocs pourrait avoir contribué à induire des différences dans les niveaux de décollement et de charriage des nappes, ainsi que dans le style tectonique. Les unités tectonostratigraphiques des blocs adjacents furent charriées de façon diachronique avec comme résultat un transport transverse par rapport à la direction dominante du charriage. Ce déplacement oblique vers les zones de failles NW-SE et l'extension parallèle de l'orogène ont produit des plis transversaux dans la couverture; la réactivation des failles NW-SE s'est traduite par l'imbrication des nappes surincombantes. L'importance de cette imbrication et de la formation de duplex est variable selon les différents segments du socle. Pour chaque segment particulier, l'imbrication du socle et la formation de duplex ont engendré des culminations de socle alignés selon deux zones parallèles dans l'orogène. La position des duplex est probablement régie par de vieilles failles N-S alors que la structure en «pinch- and-swell» le long de l'orogène est causée par le caractère individuel de la déformation et du charriage du socle et de sa couverture, propre à chaque bloc limité par des failles NW-SE. L'orogenèse calédonienne a été ainsi fortement afffectée par les structures précambriennes du bouclier baltique sous-jacent.

, lapetus - . , , , , , lapetus. - - , , . , , , . , , . , . NW-SE (»side-wall ramps«) , . . , , , ; , , , - . (pinck- and-swell) , , NW-S . , - .
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