Atmospheric input of nitrogen into the North Sea: ANICE project overview     

Gerrit de Leeuw  Leo Cohen  Lise Marie Frohn  Gary Geernaert  Ole Hertel  Bjarne Jensen  Tim Jickells  Laura Klein  Gerard J. Kunz  Soren Lund  Marcel Moerman  Frank Müller  Britta Pedersen  Knut von Salzen  K. Heinke Schlünzen  Michael Schulz  Carsten A. Skjth  Lise-Lotte Sorensen  Lucinda Spokes  Susanne Tamm  Elisabetta Vignati 《Continental Shelf Research》2001,21(18-19)

The aim of the atmospheric nitrogen inputs into the coastal ecosystem (ANICE) project is to improve transport–chemistry models that estimate nitrogen deposition to the sea. To achieve this, experimental and modelling work is being conducted which aims to improve understanding of the processes involved in the chemical transformation, transport and deposition of atmospheric nitrogen compounds. Of particular emphasis within ANICE is the influence of coastal zone processes. Both short episodes with high deposition and chronic nitrogen inputs are considered in the project. The improved transport–chemistry models will be used to assess the atmospheric inputs of nitrogen compounds into the European regional seas (the North Sea is studied as a prototype) and evaluate the impact of various emission reduction strategies on the atmospheric nitrogen loads. Assessment of the impact of atmospheric nitrogen on coastal ecosystems will be based on comparisons of phytoplankton nitrogen requirements, other external nitrogen inputs to the ANICE area of interest and the direct nitrogen fluxes provided by ANICE. Selected results from both the experimental and modelling components are presented here. The experimental results show the large spatial and temporal variability in the concentrations of gaseous nitrogen compounds, and their influences on fluxes. Model calculations show the strong variation of both concentrations and gradients of nitric acid at fetches of up to 25 km. Aerosol concentrations also show high temporal variability and experimental evidence for the reaction between nitric acid and sea salt aerosol is provided by size-segregated aerosol composition measured at both sides of the North Sea. In several occasions throughout the experimental period, air mass back trajectory analysis showed connected flow between the two sampling sites (the Weybourne Atmospheric Observatory on the North Norfolk coast of the UK and Meetpost Noordwijk, a research tower at 9 km off the Dutch coast). Results from the METRAS/SEMA mesoscale chemistry transport model system for one of these cases are presented. Measurements of aerosol and rain chemical composition, using equipment mounted on a commercial ferry, show variations in composition across the North Sea. These measurements have been compared to results obtained with the transport–chemistry model ACDEP which calculates the atmospheric inputs into the whole North Sea area. Finally, the results will be made available for the assessment of the impact of atmospheric nitrogen on coastal ecosystems.  相似文献   

Sensitivity of the thermohaline circulation in coupled oceanic GCM — atmospheric EBM experiments     

Gerrit Lohmann  Rüdiger Gerdes  Deliang Chen 《Climate Dynamics》1996,12(6):403-416

We analyze the sensitivity of the oceanic thermohaline circulation (THC) regarding perturbations in fresh water flux for a range of coupled oceanic general circulation — atmospheric energy balance models. The energy balance model (EBM) predicts surface air temperature and fresh water flux and contains the feedbacks due to meridional transports of sensible and latent heat. In the coupled system we examine a negative perturbation in run-off into the southern ocean and analyze the role of changed atmospheric heat transports and fresh water flux. With mixed boundary conditions (fixed air temperature and fixed surface fresh water fluxes) the response is characterized by a completely different oceanic heat transport than in the reference case. On the other hand, the surface heat flux remains roughly constant when the air temperature can adjust in a model where no anomalous atmospheric transports are allowed. This gives an artificially stable system with nearly unchanged oceanic heat transport. However, if meridional heat transports in the atmosphere are included, the sensitivity of the system lies between the two extreme cases. We find that changes in fresh water flux are unimportant for the THC in the coupled system.  相似文献   

The atmospheric sulfur cycle in ECHAM-4 and its impact on the shortwave radiation   总被引：5，自引：0，他引：5  

J. Feichter  U. Lohmann  I. Schult 《Climate Dynamics》1997,13(4):235-246

 The atmospheric general circulation model ECHAM-4 is coupled to a chemistry model to calculate sulfate mass distribution and the radiative forcing due to sulfate aerosol particles. The model simulates the main components of the hydrological cycle and, hence, it allows an explicit treatment of cloud transformation processes and precipitation scavenging. Two experiments are performed, one with pre-industrial and one with present-day sulfur emissions. In the pre-industrial emission scenario SO₂ is oxidized faster to sulfate and the in-cloud oxidation via the reaction with ozone is more important than in the present-day scenario. The atmospheric sulfate mass due to anthropogenic emissions is estimated as 0.38 Tg sulfur. The radiative forcing due to anthropogenic sulfate aerosols is calculated diagnostically. The backscattering of shortwave radiation (direct effect) as well as the impact of sulfate aerosols on the cloud albedo (indirect effect) is estimated. The model predicts a direct forcing of −0.35 W m^-2 and an indirect forcing of −0.76 W m^-2. Over the continents of the Northern Hemisphere the direct forcing amounts to −0.64 W m^-2. The geographical distribution of the direct and indirect effect is very different. Whereas the direct forcing is strongest over highly polluted continental regions, the indirect forcing over sea exceeds that over land. It is shown that forcing estimates based on monthly averages rather than on instantaneous sulfate pattern overestimate the indirect effect but have little effect on the direct forcing. Received: 16 October 1996/Accepted: 24 October 1996  相似文献   

Reconstructing estuarine conditions: oyster shells as recorders of environmental change, Southwest Florida   总被引：1，自引：0，他引：1  

Donna M. Surge  Kyger C Lohmann  Glenn A. Goodfriend   《Estuarine, Coastal and Shelf Science》2003,57(5-6):737-756

Live-collected shells of the oyster, Crassostrea virginica, contain geochemical records of modern temperature and salinity, so records of prehistoric conditions may be obtained from subfossil shells. Restoration of channelized watersheds in Florida is receiving much attention, and plans for targeted watersheds require information about estuarine conditions before channelization. Lack of historical records necessitates alternative methods to understand pre-disturbance conditions. A ¹⁴C-calibrated, amino-acid geochronology based on racemization of glutamic acid yielded ages ranging from 190–1220 AD and from 1270–1860 AD for subfossil oysters from Blackwater River (near-natural watershed) and for Faka-Union Bay (channelized watershed), respectively. δ¹⁸O and δ¹³C values of subfossil shells from Blackwater River indicate salinity and summer temperatures similar to present. Winter temperatures recorded in shells from 190, 590, 720, and 1050 AD appear 1–5 °C colder than present winter temperatures, whereas the shell from 1220 AD records winter temperatures similar to modern winter temperatures. These temperature shifts may indicate change in climate or natural seasonal variation of winter temperature from year to year. Subfossils from Faka-Union Bay may reflect a complicated hydrology, which cannot be evaluated by isotopic compositions alone and demonstrates the need for development of independent elemental proxies for temperature and salinity. Decreases in δ¹³C from subfossil to modern shells may in part result from CO₂ added to the atmosphere from fossil fuel burning (the Suess effect). Subfossil δ¹³C that is >1‰ more positive than modern shells suggest a change in the dominant carbon sources from terrestrial C₄ or aquatic plants to C₃ plants (mangroves).  相似文献   

The Baltic Sea Experiment BALTEX: A brief overview and some selected results of the authors     

Ehrhard Raschke  Ute Karstens  Ralph Nolte-Holube  Rüdiger Brandt  Hans-Jörg Isemer  Dag Lohmann  Manfred Lobmeyr  Burkhardt Rockel  Rolf Stuhlmann 《Surveys in Geophysics》1998,19(1):1-22

The mechanisms responsible for the transfer of energy and water within the climate system are under worldwide investigation within the framework of the Global Energy and Water Cycle Experiment (GEWEX) to improve the predictability of natural and man-made climate changes at short and long ranges and their impact on water resources. Five continental-scale experiments have been established within GEWEX to enable a more complete coupling between atmospheric and hydrological models. One of them is the Baltic Sea Experiment (BALTEX).In this paper, the goals and structure of BALTEX are outlined. A short overview of measuring and modelling strategies is given. Atmospheric and hydrological model results of the authors only are presented. These include also the validation of precipitation using station measurements as well as validation of modelled cloud cover with cloud estimates from satellite data. Furthermore, results of a large-scale grid based hydrological model to be coupled to atmospheric models are presented.This research has never been possible without the contribution of research groups and operational institutions from all 10 member countries. We concentrate here on results obtained at the GKSS research center.  相似文献   

Alteration of a pelagic chalk below a paleokarst surface,Oxford, South Island,New Zealand     

Gerrit J. van der Lingen  David Smale  D.W. Lewis 《Sedimentary Geology》1978,21(1):45-66

A small isolated outlier of Lower Oligocene chalk, which grades upwards into what was originally a sandy marl, has been truncated by a paleokarst surface, which is overlain by cross-bedded, well-sorted glauconitic sands. A sandy clay horizon (probably originally tuffaceous) and a basaltic lava flow of probable Miocene age cap the local sequence. Below the paleokarst surface and roughly parallel to it, the original sediment has been intensely altered to an average depth of 1.5 m. The alteration front is sharply defined, even where it extends along the walls of glauconitic sand-filled fissures in the chalk.In the alteration zone, the chalk has been entirely replaced by silica (opal-CT, largely in the form of lepispheres). The calcareous fraction of the marl has been replaced by montmorillonite and clinoptilolite. Rounded gravel clasts (largely basaltic) in the base of the overlying glauconitic sands also have been replaced (by montmorillonite), which suggests that all alteration followed deposition of the sands. However, neither the glauconite nor any other mineral in the sands appears highly altered. Similarly, the quartz grains show no evidence of dissolution or silica precipitation. Preservation of most silica sponge spicules, the only siliceous microfossils in the chalk, indicates that the source of the silica was extraneous to the carbonate sediments.Migrating interstitial liquid, largely confined to the sands between the impervious cap of sandy clay plus basalt and the porous but less permeable chalk, is inferred to have been the causal agent for the replacement. Silica, and any other components necessary for the formation of opal-CT, montmorillonite and clinoptilolite, were probably derived by chemical alteration of the capping volcanics in a groundwater regimen. Replacement reactions in the chalk and marl presumably were dependent on the original presence of calcium carbonate, and apart from montmorillonitization of volcanic material, occurred only where this compound was present.  相似文献   

Stable isotopes of carbon dioxide in soil gas over massive sulfide mineralization at Crandon, Wisconsin     

Charles N. Alpers  David L. Dettman  Kyger C. Lohmann  Dragan Brabec 《Journal of Geochemical Exploration》1990,38(1-2)

Stable isotope ratios of oxygen and carbon were determined for CO₂ in soil gas in the vicinity of the massive sulfide deposit at Crandon, Wisconsin with the objective of determining the source of anomalously high CO₂ concentrations detected previously by McCarthy et al. (1986). Values of δ¹³C in soil gas CO₂ from depths between 0.5 and 1.0 m were found to range from −12.68‰ to −20.03‰ (PDB). Organic carbon from the uppermost meter of soil has δ¹³C between −24.1 and −25.8‰ (PDB), indicating derivation from plant species with the C₃ (Calvin) type of photosynthetic pathway. Microbial decomposition of the organic carbon and root respiration from C₃ and C₄ (Hatch-Slack) plants, together with atmospheric CO₂ are the likely sources of carbon in soil gas CO₂. Values of δ¹⁸O in soil-gas CO₂ range from 32 to 38‰ (SMOW). These δ¹⁸O values are intermediate between that calculated for CO₂ gas in isotopic equilibrium with local groundwaters and that for atmospheric CO₂. The δ¹⁸O data indicate that atmospheric CO₂ has been incorporated by mixing or diffusion. Any CO₂ generated by microbial oxidation of organic matter has equilibrated its oxygen isotopes with the local groundwaters.The isotopic composition of soil-gas CO₂ taken from directly above the massive sulfide deposit was not distinguishable from that of background samples taken 1 to 2 km away. No enrichment of the δ¹³C value of soil-gas CO₂ was observed, contrary to what would be expected if the anomalous CO₂ were derived from the dissolution of Proterozoic marine limestone country rock or of Paleozoic limestone clasts in glacial till. Therefore, it is inferred that root respiration and decay of C₃ plant material were responsible for most CO₂ generation both in the vicinity of the massive sulfide and in the “background” area, on the occasion of our sampling. Interpretation of our data is complicated by the effects of rainfall, which significantly reduced the magnitude of the CO₂ anomaly. Therefore, we cannot rule out the possible mechanism of carbonate dissolution driven by pyrite oxidation, as proposed by Lovell et al. (1983) and McCarthy et al. (1986). Further work is needed on seasonal and daily variations of CO₂ concentrations and stable isotope ratios in various hydrogeologic and ecologic settings so that more effective sampling strategies can be developed for mineral exploration using soil gases.  相似文献   

The biodiversity convention and coastal regions     

Gerrit P. Hekstra   《Limnologica》1999,29(3):339

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Analysis of coupled axial and lateral deformation of roots in soil     

Gerrit J. Meijer  David Muir Wood  Jonathan A. Knappett  Glyn A. Bengough  Teng Liang 《国际地质力学数值与分析法杂志》2019,43(3):684-707

Plant roots can help to stabilise slopes. Existing analytical models to predict their mechanical contribution are however limited: they typically focus on the ultimate limit state, employ various empirical factors, and ignore much of the underlying root-soil interaction. A new model was developed based on large deflection Euler-Bernoulli elastic beam theory that can be used to study the mobilisation of root strength under various loading conditions (direct shear and pull-out). Both lateral and axial loading of the root by the soil were incorporated, based on existing methodologies for foundation piles (p-y and t-z curves). The model is able to take the key parameters into account (root biomechanical properties, root architectural properties, and soil properties) while remaining quick to solve using a numerical boundary value problem solver. The model was compared with experimental direct shear test data using various root analogues (rubber, plastic, and wood) in dry sand with various densities and effective stress levels and was able to accurately predict the measured shear force-displacement behaviour. Comparison with experimentally measured pull-out force-displacement curves using rubber and wooden root analogues with various architectures in dry and partially saturated sands was also satisfactory. In the future, this model can aid with addressing long-standing problems in the root-reinforcement community: quantifying the effect of (sequential) mobilisation of root strength in direct shear, the effect of the angle at which the root crosses a shear plane, the effect of root topology on root-reinforcement or the effect of root bending, and root shear shear forces on root-reinforcement.  相似文献   

Stability of the glacial thermohaline circulation and its dependence on the background hydrological cycle     

V.?RomanovaEmail author  M.?Prange  G.?Lohmann 《Climate Dynamics》2004,22(5):527-538

Different reconstructions of glacial sea-surface temperatures (SST) are used to force a hybrid coupled atmosphere–ocean model. The resulting glacial states differ in global salinity and temperature distributions, and consequently in the strength of the thermohaline circulation. Stability analysis of the Atlantic Ocean circulation, by means of freshwater-flux hysteresis maps, reveals mono-stability for each glacial background state, which appears to be a robust feature of the glacial ocean. We show that this behaviour is directly linked to the hydrological cycle. A monotonic relation between the freshwater input necessary for reaching the off-mode and the hydrological budget in the Atlantic catchment area, accounts for the sensitivity of the oceans circulation. The most sensitive part of the hydrological balance appears to be in the tropical and subtropical regions suggesting that the Achilles heel of the global conveyor belt circulation is not restricted to the northern North Atlantic where convection occurs.  相似文献