Magnetic properties and neutron diffraction study of two manganese sulfosalts: monoclinic MnSb<Subscript>2</Subscript>S<Subscript>4</Subscript> and benavidesite (MnPb<Subscript>4</Subscript>Sb<Subscript>6</Subscript>S<Subscript>14</Subscript>)     

Philippe Léone  Charlotte Doussier-Brochard  Gilles André  Yves Moëlo 《Physics and Chemistry of Minerals》2008,35(4):201-206

Mn²⁺Sb₂S₄, a monoclinic dimorph of clerite, and benavidesite (Mn²⁺Pb₄Sb₆S₁₄) show well-individualized single chains of manganese atoms in octahedral coordination. Their magnetic structures are presented and compared with those of iron derivatives, berthierite (Fe²⁺Sb₂S₄) and jamesonite (Fe²⁺Pb₄Sb₆S₁₄). Within chains, interactions are antiferromagnetic. Like berthierite, MnSb₂S₄ shows a spiral magnetic structure with an incommensurate 1D propagation vector [0, 0.369, 0], unchanged with temperature. In berthierite, the interactions between identical chains are antiferromagnetic, whereas in MnSb₂S₄ interactions between chains are ferromagnetic along c-axis. Below 6 K, jamesonite and benavidesite have commensurate magnetic structures with the same propagation vector [0.5, 0, 0]: jamesonite is a canted ferromagnet and iron magnetic moments are mainly oriented along the a-axis, whereas for benavidesite, no angle of canting is detected, and manganese magnetic moments are oriented along b-axis. Below 30 K, for both compounds, one-dimensional magnetic ordering or correlations are visible in the neutron diagrams and persist down to 1.4 K.  相似文献   

The relationship between collision-related calcalkaline, and within-plate alkaline volcanism in the Karacadağ Area (Konya-Türkiye, Central Anatolia)     

Hüseyin Kurt  Kürad Asan  Gilles Ruffet 《Chemie der Erde / Geochemistry》2008,68(2):155-176

The Karacadağ (Kulu-Konya) area is one of the main volcanic provinces in Central Anatolia. The Karacadağ volcanites are composed of large volumes of andesitic-dacitic lavas associated with pyroclastics and small volumes of alkali basalt, trachybasalt and trachyandesite lavas. Two groups of volcanic rocks can be distinguished: (1) calcalkaline rocks including andesites and dacites, and (2) alkaline rocks including basalts, trachybasalts and trachyandesites. ⁴⁰Ar/³⁹Ar ages show that the Karacadağ volcanites were erupted during Early Miocene (ca.18–19 Ma) and suggest that alkaline volcanites succeed shortly afterwards calcalkaline volcanites. Major oxides and trace elements plotted versus SiO₂ suggest fractionation of hornblende, Fe–Ti oxide and apatite for calcalkaline volcanic rocks and olivine, clinopyroxene and Fe–Ti oxide for alkaline volcanic rocks in the magmatic evolution. The incompatible trace element patterns of the calcalkaline volcanites show enrichment of LILEs (Sr, K, Rb, Ba and Th) and negative HFSEs (Nb, Ta) anomalies suggesting an enriched lithospheric source by a subduction-related process. On the other hand, alkaline volcanites show enrichment of both LILEs and HFSEs suggesting an enriched lithospheric source by small volume melts from the asthenosphere. The rocks also have moderately fractionated REE patterns with (La/Lu)_N ratios of 7–24 for calcalkaline and 6–17 for alkaline volcanites. Moreover, the volcanites have relatively low ⁸⁷Sr/⁸⁶Sr(t) ratios for between 0.703782 and 0.705129, and high ε_Nd(t) values between +2.25 and +4.49. Generally, the Sr–Nd isotopic compositions of the rocks range from the mantle array to bulk earth. All of these observations and findings suggest that the calcalkaline volcanites were formed in a subduction modified orogenic setting, and the alkaline volcanites in a within-plate setting.  相似文献   

Preface: Land subsidence processes     

Devin L. Galloway  Gilles Erkens  Eve L. Kuniansky  Joel C. Rowland 《Hydrogeology Journal》2016,24(3):547-550

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Lower and Middle Pleistocene human settlements recorded in fluvial deposits of the middle Loire River Basin,Centre Region,France     

Jackie Despriée  Pierre Voinchet  Hélène Tissoux  Jean-Jacques Bahain  Christophe Falguères  Gilles Courcimault  Jean Dépont  Marie-Hélène Moncel  Sophie Robin  Marta Arzarello  Robert Sala  Laurent Marquer  Erwan Messager  Simon Puaud  Salah Abdessadok 《Quaternary Science Reviews》2011,30(11-12):1474-1485

This paper records the findings from c. 80 prehistoric sites that have been discovered in the alluvial deposits of the rivers Creuse, Cher, and Loir, tributaries of the middle Loire River, over the period since 1981. These deposits comprise river terrace aggradations formed during successive glacial–interglacial cycles which have recorded climate and environment during Quaternary time. The systematic dating of these river deposits by Electron Spin Resonance (ESR) applied to optically bleached sedimentary quartz has resulted in the establishment of a chronological framework for the evolution of these rivers during Lower and Middle Pleistocene (between 1.7 Ma and 130 ka). Evidence for Early Palaeolithic (Mode 1) industries with an in situ context (workshops, soils) in the highest aggradations indicates that Hominins were present in the study area, near the geographical centre of France (47°N), around 1.1 Ma. Examination of the sites indicates that Human occupations were located along valley bottom sites during temperate episodes. Subsequently, after a gap of several hundred thousand years industries with handaxes appear in the Middle Loire Basin in the interval between 700 and 600 ka, and then continuously from 400 ka. These two phases of settlement produced industrial assemblages with clear differences in their responses to the supplies of raw materials and in the modes of making flakes.  相似文献   

Petrography and chemistry of SiO2 filling phases in the amethyst geodes from the Serra Geral Formation deposit,Rio Grande do Sul,Brazil     

Adriane Commin-Fischer  Gilles Berger  Mireille Polvé  Michel Dubois  Paul Sardini  Daniel Beaufort  Milton Formoso 《Journal of South American Earth Sciences》2010,29(3):751-760

The filling process of amethyst-bearing geodes from Serra Geral Formation basalts, Brazil, is investigated by different methods performed on the SiO₂ filling phases. Image analysis of quartz–amethyst deposits suggests a single growing mechanism ruled by geometric selection of randomly oriented crystals. Microthermometry of fluid inclusions reveals formation temperature lower than 100 °C, probably lower than 50 °C, and fluid salinity as high as 3 mass% NaCl eq. Composition in REE and trace-elements measured by ICP-MS on acid-digested or laser-ablated samples indicates a common genesis for amethyst, quartz and chalcedony, as well as the absence of significant variations from one geode to another. ⁸⁷Sr/⁸⁶Sr data on chalcedony shows that both the host basalt or the Botucatu sandstone are possible silica sources. These data, combined with thermo-kinetic considerations, permit us to discuss the filling process. We argue in favor of the contribution of a mineralized fluid of hydrothermal origin producing a regional silica source which decreased with time. The observed mineral sequence is related to the depletion of silica in the solution.  相似文献   

Influence of bioturbation by the polychaete Nereis diversicolor on the structure of bacterial communities in oil contaminated coastal sediments   总被引：1，自引：0，他引：1  

Cuny P  Miralles G  Cornet-Barthaux V  Acquaviva M  Stora G  Grossi V  Gilbert F 《Marine pollution bulletin》2007,54(4):452-459

Patterns of change in the structure of bacterial communities monitored by ribosomal intergenic spacer analysis (RISA) in oil contaminated sediments inhabited or not by the marine polychaete Nereis diversicolor were studied during 45 days under laboratory conditions. Results supported by principal component analysis showed a marked response of the bacterial communities to the oil contamination and to the presence of N. diversicolor. Phylogenetic affiliation of specific RISA bands showed that, in the contaminated sediments, the presence of the marine polychaetes favoured the development of bacteria which may play an active role in natural bioremediation processes of oil polluted environments.  相似文献   

Geodynamic and climate controls in the formation of Mio–Pliocene world-class oxidized cobalt and manganese ores in the Katanga province, DR Congo     

Sophie Decrée  Étienne Deloule  Gilles Ruffet  Stijn Dewaele  Florias Mees  Christian Marignac  Johan Yans  Thierry De Putter 《Mineralium Deposita》2010,45(7):621-629

The Katanga province, Democratic Republic of Congo, hosts world-class cobalt deposits accounting for ~50% of the world reserves. They originated from sediment-hosted stratiform copper and cobalt sulfide deposits within Neoproterozoic metasedimentary rocks. Heterogenite, the main oxidized cobalt mineral, is concentrated as “cobalt caps” along the top of silicified dolomite inselbergs. The supergene cobalt enrichment process is part of a regional process of residual ore formation that also forms world-class “manganese cap” deposits in western Katanga, i.e., the “black earths” that are exploited by both industrial and artisanal mining. Here, we provide constraints on the genesis and the timing of these deposits. Ar–Ar analyses of oxidized Mn ore and in situ U–Pb SIMS measurements of heterogenite yield Mio–Pliocene ages. The Ar–Ar ages suggest a multi-phase process, starting in the Late Miocene (10–5 Ma), when the metal-rich substratum was exposed to the action of meteoric fluids, due to major regional uplift. Further oxidation took place in the Pliocene (3.7–2.3 Ma) and formed most of the observed deposits under humid conditions: Co- and Mn-caps on metal-rich substrata, and coeval Fe laterites on barren areas. These deposits formed prior to the regional shift toward more arid conditions in Central Africa. Arid conditions still prevailed during the Quaternary and resulted in erosion and valley incision, which dismantled the metal-bearing caps and led to ore accumulation in valleys and along foot slopes.  相似文献   

Quantifying the spatial distribution of sediment transport in an experimental gully system using the morphological method     

Wen Dai  Liyang Xiong  Gilles Antoniazza  Guoan Tang  Stuart N. Lane 《地球表面变化过程与地形》2021,46(6):1188-1208

Whilst time-series of sediment transport in gullies in both laboratory experimental and field settings can be determined through instrumentation, quantifying the spatial distribution of transport rates remains challenging. The morphological method, which was proposed for estimating bed-material transport in both one- and two-dimensions in rivers, provides an alternative. Here, we developed this method for gully systems. A laboratory catchment was used to simulate gully erosion. High-resolution topographical data were acquired by close-range digital photogrammetry. Morphological changes were determined using high-resolution topographic data and an associated level of detection. Based on measured morphological changes, one-dimensional (1D) and two-dimensional (2D) sediment transport rates were calculated via cross-section by cross-section routing (1D) and cell by cell routing (2D). The 1D application provided a general trend of longitudinal variation of sediment transport for the whole gully system, increased gradually from zones of headward extension to a zone downstream where erosion and deposition were in balance, and sediment transport rates less variable in space. For the 2D application, hydrological and blended hydrological-hydraulic routing solutions were compared. We found that the level of negative transport was insensitive to whether or not a blended hydrological-hydraulic routing was used and that results from applying the hydrological routing throughout were not significantly degraded. We also found that consideration should be given to spatial and temporal resolution of the topographic data. The 2D application provided spatial patterns of sediment transport that vary with gully evolution. The main gully remained a high transport corridor but branch transport became more important through time. The framework we report provides an additional tool for both experimental and field quantification of the spatial patterns of sediment transport in gullies; and quantification of how these patterns change under different forcing factors.  相似文献   

Modelling the Concentration Distributions of Aerosol Puffs Using Artificial Neural Networks   总被引：1，自引：1，他引：0  

Xiaoying Cao  Gilles Roy  William S. Andrews 《Boundary-Layer Meteorology》2010,136(1):83-103

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Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses   总被引：1，自引：0，他引：1  

Maxime Mercier  Andrea Di Muro  Daniele Giordano  Priscille Lesne  Bruno Scaillet  Gilles Montagnac 《Geochimica et cosmochimica acta》2009,73(1):197-217

The development of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via micro-Raman analysis requires the assessment of the spectra topology dependence on glass composition. We report here a detailed study of the respective influence of bulk composition, iron oxidation state and total water content on the absolute and relative intensities of the main Raman bands related to glass network vibrations (LF: ∼490 cm⁻¹; HF: ∼960 cm⁻¹) and total water stretching (H₂O_T: ∼3550 cm⁻¹) in natural glasses. The evolution of spectra topology was examined in (i) 33 anhydrous glasses produced by the re-melting of natural rock samples, which span a very large range of polymerisation degree (NBO/T from 0.00 to 1.16), (ii) 2 sets of synthetic anhydrous basaltic glasses with variable iron oxidation state (Fe³⁺/Fe_T from 0.05 to 0.87), and (iii) 6 sets of natural hydrous glasses (C_H2OT from 0.4 to 7.0 wt%) with NBO/T varying from 0.01 to 0.76.In the explored domain of water concentration, external calibration procedure based on the H₂O_T band height is matrix-independent but its accuracy relies on precise control of the focusing depth and beam energy on the sample. Matrix-dependence strongly affects the internal calibrations based on H₂O_T height scaled to that of LF or HF bands but its effect decreases from acid (low NBO/T, SM) to basic (high NBO/T, SM) glasses. Structural parameters such as NBO/T (non-bridging oxygen per tetrahedron) and SM (sum of structural modifiers) describe the matrix-dependence better than simple compositional parameters (e.g. SiO₂, Na₂O + K₂O). Iron oxidation state has only a minor influence on band topology in basalts and is thus not expected to significantly affect the Raman determinations of water in mafic (e.g. low SiO₂, iron-rich) glasses. Modelling the evolution of the relative band height with polymerisation degree allows us to propose a general equation to predict the dissolved water content in natural glasses: