Correlations and sequence stratigraphic model for Messinian carbonate platforms of the western and central Mediterranean   总被引：1，自引：0，他引：1  

Jean-Jacques?CornéeEmail author  Jean-Paul?Saint Martin  Gilles?Conesa  Philippe?Münch  Jean-Pierre?André  Simona?Saint Martin  Stefan?Roger 《International Journal of Earth Sciences》2004,93(4):621-633

Distance correlations of Late Tortonian–Messinian littoral carbonate complexes are proposed from the study of eight platforms in the western and central Mediterranean. Correlations are based on the identification of two major biological sedimentary cycles and of two index surfaces. Surface A is a maximum flooding surface during cycle 1 at around 6.7 Ma. Surface B is a regional marine planation surface at around 5.95 Ma, at the base of cycle 2 (Terminal Carbonate Complex). A general sedimentary model is proposed for the 7–5.6-Ma time-span. The boundary between cycles 1 and 2 is coincident with the onset of the Messinian Salinity Crisis, and appears to be related to major environmental–paleo-oceanographic changes in the Mediterranean, rather than to a major sea-level drop or to climatic change.  相似文献   

The crystalline complexes of Hamadan (Sanandaj–Sirjan zone, western Iran): metasedimentary Mesozoic sequences affected by Late Cretaceous tectono-metamorphic and plutonic events     

Aliakbar Baharifar  Hossein Moinevaziri  Herv Bellon  Alain Piqu 《Comptes Rendus Geoscience》2004,336(16):1443-1452

The Hamadan area is characterised by various metamorphic rocks where the slates yielded Jurassic fossils. The entire column, representing the Mesozoic from at least the Jurassic to the Mid-Cretaceous, has been affected by tectono-metamorphic events and the emplacement of Late Cretaceous granitic rocks. A timing of these events is based on the ⁴⁰K–⁴⁰Ar ages carried mainly on separated amphiboles, biotites and muscovites, and interpreted as the ages of their isotopic closure. Results are ranging between 91 and 70 Ma. To cite this article: A. Baharifar et al., C. R. Geoscience 336 (2004).

Résumé

La région de Hamadan expose des roches métamorphiques dont les termes les moins transformés contiennent des fossiles jurassiques. Au cours du Crétacé supérieur, elle a été affectée par un événement tectono-métamorphique régional et elle a été le siège d'une activité plutonique. Les résultats des datations ⁴⁰K–⁴⁰Ar des amphiboles et des micas séparés des roches métamorphiques et plutoniques qui s'étagent entre 91 et 70 Ma montrent l'importance de ces événements et leur étalement au cours du Crétacé supérieur. Pour citer cet article : A. Baharifar et al., C. R. Geoscience 336 (2004).  相似文献   

Architecture interne d'une vallée incisée sur une côte à forte énergie de houle et de marée (vallée de la Leyre,côte aquitaine,France)     

Hugues Féniès  Gilles Lericolais 《Comptes Rendus Geoscience》2005,337(14):1257-1266

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Spatial Variability of Trends in the Rainfall-Runoff Relationship: A Mesoscale Study in the Mosel Basin     

Laurent Pfister  Gilles Drogue  Abdelkhalak El Idrissi  Jean-François Iffly  Christelle Poirier  Lucien Hoffmann 《Climatic change》2004,66(1-2):67-87

The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.  相似文献   

The Upper Rhône Delta Sedimentary Record in the Arles-Piton Core: Analysis of Delta-Plain Subenvironments, Avulsion Frequency, Aggradation Rate and Origin of Sediment Yield     

Gilles Arnaud-Fassetta 《Geografiska Annaler: Series A, Physical Geography》2004,86(4):367-383

Results from analyses of the Arles‐Piton sediment core, retrieved from the apex of the Rhône Delta, highlight processes of Holocene deltaic construction controlled mainly by hydrosedimentary variability and channel avulsions. The alluvial suite was investigated for grain size, sedimentary structures, CaCO₃, organic matter, heavy minerals and chrono‐stratigraphy (¹⁴C and archaeological/historical dates). The study shows the succession of six facies associations: a distributary channel (before 6157‐5843 BC), a swamp (5719‐5530/4796‐4463 BC), a distal flood plain (5719‐5530/4796‐4463 BC), a distributary channel (4796‐4463/2900‐2503 BC), a proximal flood plain (2900‐2503 BC/AD 270‐290), and a crevasse splay (after AD 270‐290). Substantial changes in hydrodynamics are strongly linked to three channel avulsions (before 6157‐5843 BC, after 4796‐4463 BC and after 2900‐2503 BC). A correlation with the whole channel avulsion history of the Rhône Delta allowed us to propose an average rhythm of channel avulsion of c. 1450 years. From 5719‐5530 BC to AD 270‐290, the flood plain aggraded at the average rate of 2.5 mm/a. The aggradation rates were higher both in the proximal and distal flood plains, where sedimentation process is continuous. They were lower both in the active distributary channels, because of frequent truncation of the alluvial suite, and the abandoned channels where detritic inputs are minimum. The sediment supply arriving to the upper Rhône Delta was derived mainly from proximal source areas (Massif Central, Southern Alps) during the last 8000 years, except during the hydrological changes of Roman antiquity during which detritic inputs were derived firstly from the Northern Alps and Southern Alps, and secondly from the Massif Central.  相似文献   

Speciation and characterization of arsenic in gold ores and cyanidation tailings using X-ray absorption spectroscopy     

Dogan Paktunc  Andrea Foster  Gilles Laflamme 《Geochimica et cosmochimica acta》2004,68(5):969-983

The knowledge of mineralogy and molecular structure of As is needed to better understand the stability of As in wastes resulting from processing of gold ores. In this study, optical microscopy, scanning electron microscopy, electron microprobe, X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy (including both XANES and EXAFS regimes) were employed to determine the mineralogical composition and local coordination environment of As in gold ores and process tailings from bench-scale tests designed to mimic a common plant practice. Arsenic-bearing minerals identified in the ores and tailings include iron (III) oxyhydroxides, scorodite (FeAsO₄·2H₂O), ferric arsenates, arseniosiderite (Ca₂Fe₃(AsO₄)₃O₂·3H₂O), Ca-Fe arsenates, pharmacosiderite (KFe₄(AsO₄)₃(OH)₄·6-7H₂O), jarosite (K₂Fe₆(SO₄)₄(OH)₁₂) and arsenopyrite (FeAsS). Iron (III) oxyhydroxides contain variable levels of As from trace to about 22 wt% and Ca up to approximately 9 wt%.Finely ground ore and tailings samples were examined by bulk XAFS and selected mineral grains were analyzed by microfocused XAFS (micro-EXAFS) spectroscopy to reconcile the ambiguities of multiple As sources in the complex bulk EXAFS spectra. XANES spectra indicated that As occurs as As⁵⁺in all the samples. Micro-EXAFS spectra of individual iron (III) oxyhydroxide grains with varying As concentrations point to inner-sphere bidentate-binuclear arsenate complexes as the predominant form of As. There are indications for the presence of a second Fe shell corresponding to bidentate-mononuclear arrangement. Iron (III) oxyhydroxides with high As concentrations corresponding to maximum adsorption densities probably occur as nanoparticles. The discovery of Ca atoms around As in iron (III) oxyhydroxides at interatomic distances of 4.14-4.17 Å and the coordination numbers suggest the formation of arseniosiderite-like nanoclusters by coprecipitation rather than simple adsorption of Ca onto iron (III) oxyhydroxides. Correlation of Ca with As in iron (III) oxyhydroxides as determined by electron microprobe analysis supports the coprecipitate origin for the presence of Ca in iron (III) oxyhydroxides.The samples containing higher abundances of ferric arsenates released higher As concentrations during the cyanidation tests. The presence of highly soluble ferric arsenates and Ca-Fe arsenates, and relatively unstable iron (III) oxyhydroxides with Fe/As molar ratios of less than 4 in the ore and process tailings suggests that not only the tailings in the impoundment will continue to release As, but also there is the potential for mobilization of As from the natural sources such as the unmined ore.  相似文献   

Geology and Hydrothermal Alteration of the Low Sulfidation     

Betchaida D. Payot    Victor B. Maglambayan    Carla B. Dimalanta    Graciano P. Yumul  Jr.  Rodolfo A. Tamayo  Jr  Toshihiko Matsuda    Shigeyuki Suzuki  Herve Bellon 《Resource Geology》2005,55(3):155-162

Abstract. The Pantingan Gold System (PGS) is a vein-type epithermal prospect exposed within the summit caldera of Mount Mariveles, Bagac, Bataan (Luzon), Philippines. It consists of nine major veins, eight of which trend NW-WNW and distributed in an en echelon array. The eastern tips of these veins appear to terminate near the NE-NNE trending Vein 1, which is located in the easternmost portion of the prospect. Metal assay results on vein and wall rock samples indicate concentrations of 0.01 to 1.1 g/ton Au, trace to 34 g/ton Ag and 0.003 to 0.02 % Cu. Andesite lava flow deposits host the PGS. Potassium-Argon isotopic dating of these andesites yields anarrow age range of 0.88± 0.13 to 1.13 ± 0.17 Ma. The surface exposures of the veins (up to 5 m wide) are encountered at different levels between 590–740 masl. These commonly display a massive texture although banding prominently occurs in Vein 1. The veins consist of gray to cream-colored crystalline and chalcedonic quartz and amorphous silica. Pyrite is the most ubiquitous sulfide mineral. It occurs either as fine-grained disseminations and aggregates in quartz or as infillings in vugs. Calcite, marcasite and bornite are also occasionally noted in the deposit. The prospect shows silicic, argillic, propylitic and advanced argillic alteration zones. Silicic and argillic alterations are confined in the immediate wall rocks of the quartz veins. Argillic alteration grades to a propylitic zone farther away from the veins. The advanced argillic alteration zone, indicated by a suite of acidic clay minerals that include kaolin-ite, dickite, pyrophyllite and alunite, might have been imprinted during the late stages of gold deposition. As a whole, the PGS displays geological and mineralogical features typical of gold mineralization in a low sulfidation, epithermal environment. It is also representative of a young, tectonically undisturbed gold deposit.  相似文献   

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows     

Felipe Espinoza  Diego Morata  Ewan Pelleter  Ren  C. Maury  Manuel Su  rez  Yves Lagabrielle  Mireille Polv    Herv  Bellon  Joseph Cotten  Rita De la Cruz  Christelle Guivel 《Lithos》2005,82(3-4):315-343

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.  相似文献   

Hydrous ferric oxide precipitation in the presence of nonmetabolizing bacteria: Constraints on the mechanism of a biotic effect     

Denis G. Rancourt  Pierre-Jean Thibault  Denis Mavrocordatos  Gilles Lamarche 《Geochimica et cosmochimica acta》2005,69(3):553-577

We have used room temperature and cryogenic ⁵⁷Fe Mössbauer spectroscopy, powder X-ray diffraction (pXRD), mineral magnetometry, and transmission electron microscopy (TEM), to study the synthetic precipitation of hydrous ferric oxides (HFOs) prepared either in the absence (abiotic, a-HFO) or presence (biotic, b-HFO) of nonmetabolizing bacterial cells (Bacillus subtilis or Bacillus licheniformis, ∼10⁸ cells/mL) and under otherwise identical chemical conditions, starting from Fe(II) (10⁻², 10⁻³, or 10⁻⁴ mol/L) under open oxic conditions and at different pH (6-9). We have also performed the first Mössbauer spectroscopy measurements of bacterial cell wall (Bacillus subtilis) surface complexed Fe, where Fe(III) (10^−3.5-10^−4.5 mol/L) was added to a fixed concentration of cells (∼10⁸ cells/mL) under open oxic conditions and at various pH (2.5-4.3). We find that non-metabolic bacterial cell wall surface complexation of Fe is not passive in that it affects Fe speciation in at least two ways: (1) it can reduce Fe(III) to sorbed-Fe²⁺ by a proposed steric and charge transfer effect and (2) it stabilizes Fe(II) as sorbed-Fe²⁺ against ambient oxidation. The cell wall sorption of Fe occurs in a manner that is not compatible with incorporation into the HFO structure (different coordination environment and stabilization of the ferrous state) and the cell wall-sorbed Fe is not chemically bonded to the HFO particle when they coexist (the sorbed Fe is not magnetically polarized by the HFO particle in its magnetically ordered state). This invalidates the concept that sorption is the first step in a heterogeneous nucleation of HFO onto bacterial cell walls. Both the a-HFOs and the b-HFOs are predominantly varieties of ferrihydrite (Fh), often containing admixtures of nanophase lepidocrocite (nLp), yet they show significant abiotic/biotic differences: Biotic Fh has less intraparticle (including surface region) atomic order (Mössbauer quadrupole splitting), smaller primary particle size (magnetometry blocking temperature), weaker Fe to particle bond strength (Mössbauer center shift), and no six-line Fh (6L-Fh) admixture (pXRD, magnetometry). Contrary to current belief, we find that 6L-Fh appears to be precipitated directly, under a-HFO conditions, from either Fe(II) or Fe(III), and depending on Fe concentration and pH, whereas the presence of bacteria disables all such 6L-Fh precipitation and produces two-line Fh (2L-Fh)-like biotic coprecipitates. Given the nature of the differences between a-HFO and b-HFO and their synthesis condition dependences, several biotic precipitation mechanisms (template effect, near-cell environment effect, catalyzed nucleation and/or growth effect, and substrate-based coprecipitation) are ruled out. The prevailing present view of a template or heterogeneous nucleation barrier reduction effect, in particular, is shown not to be the cause of the large observed biotic effects on the resulting HFOs. The only proposed mechanism (relevant to Fh) that is consistent with all our observations is coprecipitation with and possible surface poisoning by ancillary bacteriagenic compounds. That bacterial cell wall functional groups are redox active and the characteristics of biotic (i.e., natural) HFOs compared to those of abiotic (i.e., synthetic) HFOs have several possible biogeochemical implications regarding Fe cycling, in the photic zones of water columns in particular.  相似文献   

Comments on “(U–Th)/He dating of fluorite: application to the La Azul fluorspar deposit in the Taxco mining district, Mexico” by Pi et al. (Mineralium Deposita 39: 976–982)     

Jordi Tritlla  Gilles Levresse 《Mineralium Deposita》2006,41(3):296-299

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