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71.
We present the first spectra of Neptune taken with the Spitzer Space Telescope, highlighting the high-sensitivity, moderate-resolution 10-20 μm (500-1000 cm−1) spectra. We report the discovery of methylacetylene (CH3C2H) and diacetylene (C4H2) with derived 0.1-mbar volume mixing ratios of (1.2±0.1)×10−10 and (3±1)×10−12 respectively. 相似文献
72.
73.
A number of archeological features, including in‐filled irrigation canals of uncertain prehistoric age, occur within the Holocene floodplain of the Salt River at Phoenix, Arizona. In the first attempt to date irrigation‐canal sediments using luminescence methods, we obtained age estimates of 1640 ± 190 yr B.P. (1σ) (multi‐aliquot or MA) and 1621 ± 95 yr B.P. (post‐IR single‐aliquot‐regenerative‐dose or SAR) for a single sample from the base of the oldest canal‐infilling deposits (all IR‐PSL ages reported in this article are in calendar years before A.D. 2001). For the remaining canal samples, weighted mean luminescence ages of 819 ± 45 yr (MA) and 826 ± 32 yr (post‐IR SAR) were obtained. Thus from photonic dating we can resolve the first and last phases of canal use at this Phoenix site: initiation at ca. 1600 years ago and final use at ca. 800 years ago. These results demonstrate the power of SAR luminescence sediment dating to enhance our understanding of prehistoric irrigation‐canal development and usage here and elsewhere in the world. © 2004 Wiley Periodicals, Inc. 相似文献
74.
Owen M. Weller Simon Jackson William G. R. Miller Marc R. St-Onge Nicole Rayner 《Journal of Metamorphic Geology》2020,38(8):853-880
Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes. 相似文献
75.
Christopher K. Shuler Aly I. El-Kadi Henrietta Dulai Craig R. Glenn Joseph Fackrell 《Hydrogeology Journal》2017,25(8):2419-2434
This study presents a modeling framework for quantifying human impacts and for partitioning the sources of contamination related to water quality in the mixed-use landscape of a small tropical volcanic island. On Tutuila, the main island of American Samoa, production wells in the most populated region (the Tafuna-Leone Plain) produce most of the island’s drinking water. However, much of this water has been deemed unsafe to drink since 2009. Tutuila has three predominant anthropogenic non-point-groundwater-pollution sources of concern: on-site disposal systems (OSDS), agricultural chemicals, and pig manure. These sources are broadly distributed throughout the landscape and are located near many drinking-water wells. Water quality analyses show a link between elevated levels of total dissolved groundwater nitrogen (TN) and areas with high non-point-source pollution density, suggesting that TN can be used as a tracer of groundwater contamination from these sources. The modeling framework used in this study integrates land-use information, hydrological data, and water quality analyses with nitrogen loading and transport models. The approach utilizes a numerical groundwater flow model, a nitrogen-loading model, and a multi-species contaminant transport model. Nitrogen from each source is modeled as an independent component in order to trace the impact from individual land-use activities. Model results are calibrated and validated with dissolved groundwater TN concentrations and inorganic δ15N values, respectively. Results indicate that OSDS contribute significantly more TN to Tutuila’s aquifers than other sources, and thus should be prioritized in future water-quality management efforts. 相似文献
76.
The hydraulic gradient between aquifers and rivers is one of the most variable properties in a river/aquifer system. Detailed process understanding of bank storage under hydraulic gradients is obtained from a two‐dimensional numerical model of a variably saturated aquifer slice perpendicular to a river. Exchange between the river and the aquifer occurs first at the interface with the unsaturated zone. The proportion of total water exchanged through the river bank compared to the river bed is a function of aquifer hydraulic conductivity, partial penetration, and hydraulic gradient. Total exchange may be estimated to within 50% using existing analytical solutions provided that unsaturated zone processes do not strongly influence exchange. Model‐calculated bank storage is at a maximum when no hydraulic gradient is present and increases as the hydraulic conductivity increases. However, in the presence of a hydraulic gradient, the largest exchange flux or distance of penetration does not necessarily correspond to the highest hydraulic conductivity, as high hydraulic conductivity increases the components of exchange both into and out of an aquifer. Flood wave characteristics do not influence ambient groundwater discharge, and so in large floods, hydraulic gradients must be high to reduce the volume of bank storage. Practical measurement of bank storage metrics is problematic due to the limitations of available measurement technologies and the nested processes of exchange that occur at the river‐aquifer interface. Proxies, such as time series concentration data in rivers and groundwater, require further development to be representative and quantitative. 相似文献
77.
Leigh N. Fletcher Kevin H. Baines Adam P. Showman Glenn S. Orton C. Merlet 《Icarus》2011,214(2):510-533
The latitudinal variation of Saturn’s tropospheric composition (NH3, PH3 and AsH3) and aerosol properties (cloud altitudes and opacities) are derived from Cassini/VIMS 4.6-5.1 μm thermal emission spectroscopy on the planet’s nightside (April 22, 2006). The gaseous and aerosol distributions are used to trace atmospheric circulation and chemistry within and below Saturn’s cloud decks (in the 1- to 4-bar region). Extensive testing of VIMS spectral models is used to assess and minimise the effects of degeneracies between retrieved variables and sensitivity to the choice of aerosol properties. Best fits indicate cloud opacity in two regimes: (a) a compact cloud deck centred in the 2.5-2.8 bar region, symmetric between the northern and southern hemispheres, with small-scale opacity variations responsible for numerous narrow light/dark axisymmetric lanes; and (b) a hemispherically asymmetric population of aerosols at pressures less than 1.4 bar (whose exact altitude and vertical structure is not constrained by nightside spectra) which is 1.5-2.0× more opaque in the summer hemisphere than in the north and shows an equatorial maximum between ±10° (planetocentric).Saturn’s NH3 spatial variability shows significant enhancement by vertical advection within ±5° of the equator and in axisymmetric bands at 23-25°S and 42-47°N. The latter is consistent with extratropical upwelling in a dark band on the poleward side of the prograde jet at 41°N (planetocentric). PH3 dominates the morphology of the VIMS spectrum, and high-altitude PH3 at p < 1.3 bar has an equatorial maximum and a mid-latitude asymmetry (elevated in the summer hemisphere), whereas deep PH3 is latitudinally-uniform with off-equatorial maxima near ±10°. The spatial distribution of AsH3 shows similar off-equatorial maxima at ±7° with a global abundance of 2-3 ppb. VIMS appears to be sensitive to both (i) an upper tropospheric circulation (sensed by NH3 and upper-tropospheric PH3 and hazes) and (ii) a lower tropospheric circulation (sensed by deep PH3, AsH3 and the lower cloud deck). 相似文献
78.
Although artificial reefs are commonly used throughout the world as tools to mitigate for habitat alteration, their development is rarely subjected to a rigorous site selection process. We developed a simple site selection model using the following seven systematic steps: exclusion mapping, depth and slope verification, surficial substrate assessment, data weighting and the subsequent ranking analysis, visual transect surveys, benthic air‐lift sampling, and larval settlement collector deployment. American lobster (Homarus americanas) was selected as the target species for these investigations owing to the local commercial importance of the species. Results from each step in this process ultimately allowed us to select a site for an artificial reef at a target depth that received little wave action, had no slope, and possessed a surficial substrate type that could support the weight of a reef. The site also had the presence of a natural larval supply and low species diversity before reef installation. Each step in this site selection model was designed for easy adaptation to suit the needs of various artificial reef projects. 相似文献
79.
Helen Glenn Diana TingleySonia Sánchez Maroño Dennis HolmGurpreet Padda Ingi Runar EdvardssonAlexis Conides Kostas KapirisMintewab Bezabih Premachandra WattageSakari Kuikka 《Marine Policy》2012,36(1):54-72
This paper explores the issue of “trust” in the fisheries science community, a key corollary of effective risk communication. It presents the findings of a survey undertaken in Iceland, Greece, Spain, United Kingdom and Faroe Islands during 2008. The findings reveal differing levels of trust and mistrust in the fisheries science community between countries and between stakeholder groups, demonstrating areas for future attention in the interests of improving fisheries science and management. As this paper explores, unfortunately the “trust” necessary for effective stakeholder cooperation and participation within current fisheries science is currently somewhat lacking. The cited reasons behind this lack of trust include: a lack of soundness, credibility, responsiveness, flexibility and stakeholder involvement, flawed data and weak science, poor communications and political and lobby group interference. Notable from the results is a lack of consensus on the existence of a common language and vision. It is evident, however, that certain aspects of fisheries science are strong contributors to trust and that there are opportunities for improvement. 相似文献
80.
We present the closed form of a general steady-state shape factor for a partially penetrating well in a uniform anisotropic aquifer. Our simple analytical expression for the shape factor has a uniform representation for full range of parameters and meets or exceeds the accuracy of previous results obtained through semiempirical methods (e.g., Bouwer and Rice [1976] equations). This general shape factor pertains to the flow of fluids (water or air) in subsurface formations when the upper formation boundary has constant potential and the lower boundary is impermeable. The results of our investigation are directly applicable to analyses of (1) slug tests with falling or rising head and (2) injection/extraction tests with constant head, essential techniques for the characterization of hydraulic conductivity of aquifers, streambeds, or lakebeds as well as the design of aquifer and soil remediation systems. 相似文献