Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy          下载免费PDF全文

Jesse D. Ward  Mark Bowden  C. Tom Resch  Steven Smith  Bruce K. McNamara  Edgar C. Buck  Gregory C. Eiden  Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   

The Economic Contributions of Agricultural Tourism in Michigan          下载免费PDF全文

Gregory Veeck  Lucius Hallett IV  Deborah Che  Ann Veeck 《Geographical review》2016,106(3):421-440

Family farms have long generated income from agricultural tourism including U‐picks, wagon rides, corn mazes and petting zoos, but contemporary agricultural tourism reflects much greater sophistication in terms of product variety, services, activities, and marketing. In Michigan, farm operators have moved beyond classic products and activities and the traditional consumer base. New sources of revenue derive from classes on beer, cider, mead and wine making, yarn spinning, perfume/soap‐making, farm markets, fishing, educational classes, school tours and hospitality including weddings and on‐farm restaurants. This case study of Michigan agricultural tourism reports results from a systematic survey of 154 agritourism operations conducted throughout the state during summer and fall of 2013 with a focus on the economic benefits of the fast‐changing sector. This study summarizes tax revenues, sales and employment trends for the farm operations participating in the survey but also quantitatively assesses the contribution of agricultural tourism to Michigan's economy through an extrapolation of the sample to estimate state‐wide totals. Results from OLS multivariate regression analysis intended to identify relationships between employment, advertising and scale to gross sales per day are also reported. These analyses show the importance of agricultural tourism to rural and peri‐urban places in Michigan and throughout the nation, while raising concerns about a growing division between large and small operators and what this growing gap may mean for the future of the sector.  相似文献   

Uncertainty in dam safety risk analysis     

Gregory B. Baecher 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2016,10(2):92-108

The character and importance of uncertainty in dam safety risk analysis drives how risk assessments are used in practice. The current interpretation of uncertainty is that, in addition to the aleatory risk which arises from presumed uncertainty in the world, it comprises the epistemic aspects of irresolution in a model or forecast, specifically model and parameter uncertainty. This is true in part but it is not all there is to uncertainty in risk analysis. The physics of hazards and of failure may be poorly understood, which goes beyond uncertainty in its conventional sense. There may be alternative scenarios of future conditions, for example non-stationarity in the environment, which cannot easily be forecast. There may also be deep uncertainties of the type associated with climate change. These are situations in which analysts do not know or do not agree on the system characterisation relating actions to consequences or on the probability distributions for key parameters. All of these facets are part of the uncertainty in risk analysis with which we must deal.  相似文献   

Erratum to: The oceanic cycles of the transition metals and their isotopes     

Derek Vance  Corey Archer  Susan H. Little  Michael Köbberich  Gregory F. de Souza 《中国地球化学学报》2018,37(1):151-151

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Perspectives on lithospheric evolution through tectonomagmatic processes: a volume in honour of Jaroslav Dostal—an introduction     

Shellnutt  J. Gregory  Murphy  J. Brendan  Greenough  John D.  Keppie  J. Duncan 《International Journal of Earth Sciences》2018,107(3):781-785

International Journal of Earth Sciences -  相似文献   

An autochthonous Avalonian basement source for the latest Ordovician Brenton Pluton in the Meguma terrane of Nova Scotia: U–Pb–Hf isotopic constraints and paleogeographic implications     

Duncan Keppie  J.  Gregory Shellnutt  J.  Dostal  Jaroslav  Fraser Keppie  D. 《International Journal of Earth Sciences》2018,107(3):955-969

International Journal of Earth Sciences - The Ediacaran–Ordovician Meguma Supergroup was thrust over Avalonia basement prior to the intrusion of post-Acadian, ca. 370 Ma, S-type...  相似文献   

Hybrid Gaussian-cubic radial basis functions for scattered data interpolation     

Pankaj K. Mishra  Sankar K. Nath  Mrinal K. Sen  Gregory E. Fasshauer 《Computational Geosciences》2018,22(5):1203-1218

Scattered data interpolation schemes using kriging and radial basis functions (RBFs) have the advantage of being meshless and dimensional independent; however, for the datasets having insufficient observations, RBFs have the advantage over geostatistical methods as the latter requires variogram study and statistical expertise. Moreover, RBFs can be used for scattered data interpolation with very good convergence, which makes them desirable for shape function interpolation in meshless methods for numerical solution of partial differential equations. For interpolation of large datasets, however, RBFs in their usual form, lead to solving an ill-conditioned system of equations, for which, a small error in the data can cause a significantly large error in the interpolated solution. In order to reduce this limitation, we propose a hybrid kernel by using the conventional Gaussian and a shape parameter independent cubic kernel. Global particle swarm optimization method has been used to analyze the optimal values of the shape parameter as well as the weight coefficients controlling the Gaussian and the cubic part in the hybridization. Through a series of numerical tests, we demonstrate that such hybridization stabilizes the interpolation scheme by yielding a far superior implementation compared to those obtained by using only the Gaussian or cubic kernels. The proposed kernel maintains the accuracy and stability at small shape parameter as well as relatively large degrees of freedom, which exhibit its potential for scattered data interpolation and intrigues its application in global as well as local meshless methods for numerical solution of PDEs.  相似文献   

Fish Predation on Juvenile Penaeid Shrimp: Examining Relative Predator Impact and Size-Selective Predation     

Marvin M. MaceIII  Lawrence P. Rozas 《Estuaries and Coasts》2018,41(7):2128-2134

Predation is likely the primary source of mortality for juvenile penaeid shrimp and, therefore, a key factor driving their population dynamics. We sampled juvenile penaeids and their potential predators in a salt marsh from July to August 2012 to examine the impact of these predators and possible size-selective predation on the shrimp population. We quantified predator impact using the frequency of occurrence (FO) index and a relative predation index (RPI) that accounts for predator abundance and the number of shrimp consumed per individual predator. Size selectivity was assessed by comparing the size distribution of shrimp in the study area to the size distribution of shrimp removed from predator stomachs. Two penaeid species, white shrimp Litopenaeus setiferus and brown shrimp Farfantepenaeus aztecus, were collected, and most (86%) were juvenile white shrimp ≤?12 mm carapace length. Spotted seatrout Cynoscion nebulosus, which consumed relatively large shrimp, was the most important predator based on the FO index. Bay whiff Citharichthys spilopterus, which ate the smallest shrimp, was the most important predator based on the RPI. The size distribution of shrimp removed from predator stomachs differed from those collected in the study area; the smallest shrimp were disproportionally more abundant in predator stomachs. Using the RPI, we identified some potentially important predators (e.g., bay whiff) that may impact shrimp populations by consuming the smallest shrimp in estuarine nurseries. Our approach could be useful for examining predator impacts on other populations of juvenile penaeids and more generally for any prey consumed by fish predators.  相似文献   

Kampelite,Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O,a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula,Russia)     

Yakovenchuk  Victor N.  Ivanyuk  Gregory Yu.  Pakhomovsky  Yakov A.  Panikorovskii  Taras L.  Britvin  Sergei N.  Krivovichev  Sergey V.  Shilovskikh  Vladimir V.  Bocharov  Vladimir N. 《Mineralogy and Petrology》2018,112(1):111-121

Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,...  相似文献   

Social media information sharing for natural disaster response     

Dong  Zhijie Sasha  Meng  Lingyu  Christenson  Lauren  Fulton  Lawrence 《Natural Hazards》2021,106(3):2077-2109

Natural Hazards - Prediction in ungauged basins (PUB) is as crucial as it is challenging. Thus far, there have been abundant regionalization studies on PUB, whereas "regionalization" is...  相似文献