Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction     

Megan FULLER  Yongsong HUANG 《Meteoritics & planetary science》2003,38(3):357-363

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.  相似文献   

贵州织金煤矿区龙潭组岩石特征及其意义     

陶述平  谭西德  黄昔容 《国土资源导刊(湖南)》2001,20(4):247-249

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.  相似文献   

The influence of a non‐associated flow rule on the calculation of the factor of safety of soil slopes     

Yu‐Jie Wang  Jian‐Hua Yin  C. F. Lee 《国际地质力学数值与分析法杂志》2001,25(13):1351-1359

This paper presents a method that incorporates a non‐associated flow rule into the limit analysis to investigate the influence of the dilatancy angle on the factor of safety for the slope stability analysis. The proposed method retain's the advantage of the upper bound method, which is simple and has no stress involvement in the calculation of the energy dissipation and the factor of safety. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

广西森林旅游资源的特色及其开发意义     

傅中平  黄载环 《南方国土资源》2001,14(3):27-29

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。  相似文献   

Early warning research on salt-alkalization desertification in western Songnen Plain     

BIAN Jian-min  LIN Nian-feng  TANG Jie College of Environment  Resources  Jilin  University  Changchun  Jilin  China 《东北亚地学研究》2005,(Z1)

Desertification is an environmental issue in the world. The salt-alkalization desertification land area formed by both primary and secondary salt-alkalization has extended in a large scale, which has become a significant eco-environmental problem. Based on the characteristics of eco-environment and the situation of desertification in western Songnen plain, this paper reports the analyzes of its formation in background and cause. An early warning system on the salt-alkalization desertification is established and the GIS technology is used to abstract the information of desertification evaluation index. Supported by the integrated technology of the GIS and ANN, the orientation and quantitative result of desertification are gained, which is helpful to the eco-environment protection and resource development in western Songnen Plain.  相似文献   

VPN技术在浙江省气象网络中的应用   总被引：2，自引：0，他引：2  

吴孟春  马奇蔚  周必高  周捷  周翔 《成都信息工程学院学报》2006,21(4):551-554

随着浙江省气象业务的不断发展，网络数据交换日益增多，同时更多基于网络的气象业务的增加，如网络视频会商、自动站数据传输等，使目前浙江省气象系统专线网络运行已达到极限，所以需要建立VPN网以对现有的网络作链路上的备份，而VPN的建立同时还可以实现移动办公，领导能在远程调用内网的资料进行远程决策服务和汇报工作。主要介绍VPN技术并叙述VPN技术在浙江省气象系统网络中的具体应用。  相似文献   

广西难处理金矿固化焙烧氰化提金试验   总被引：1，自引：0，他引：1  

邱美珍  韦丛中  蒋奇亮  杜杰 《南方国土资源》2002,15(4):43-46

通过对广西六梅金矿、明山金矿、金牙金矿含高砷高硫难浸金矿石进行固化焙烧—氰化提金的试验研究 ,获得了砷、硫固定率分别为 99.0 3%、97.0 4 % ,金浸出率 92 .35 %的较好指标 ,为这类难浸金矿的开发 ,展示了一种经济有效的途径  相似文献   

基于STC单片机的实验开发平台的设计     

杨明欣  张杰  郑郁正 《成都信息工程学院学报》2006,21(3):410-413

介绍了基于STC89C516RD＋单片机的实验开发平台的硬件电路设计、ISP编程、软件开发实例及系统的抗干扰措施.为帮助学生学习单片机技术,同时也为有经验者开发和调试产品打下基础.  相似文献   

Using an adjoint model to improve an optimum interpolation-based data-assimilation system     

X.-Y. HUANG  N. GUSTAFSSON  E. R. KÄLLÉN 《地球，A辑:动力气象学与海洋学》1997,49(2):161-176

  相似文献   

CORRESPONDENCE ANALYSIS ON IMAGES OF JIANGXI PROVINCE AS A TOURIST DESTINATION   总被引：4，自引：0，他引：4  

MAO Duan-qian ZHANG Jie BAO Hao-sheng 《中国地理科学(英文版)》2005,15(3):275-280

1IN T R O D U C T IO NAn image isa setofbelief,s ideasand impressionsthatapersonholdsaboutan object(KOTLER,1991).Similar-lydefinitionistheimage of a destinationas thesum ofbelief,sideasand impressionsthatpeoplehave ofa placeor destination(CROMPTON,1979;KO…  相似文献