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71.
Recent extensive studies have suggested that the occurrence of warm-pool El Niño has increased since the late 1970s and will increase in future climate. Occurrence frequencies of cold-tongue and warm-pool El Niño have been investigated in the observational record (1980–2006) and in the future 50 years (2007–2056) based on 100 synthetic SST datasets with estimates of statistical confidence. In the observational record, 80% of the warm-pool El Niño occurred since 1980 over a period of 27 years; only 20% of the warm-pool El Niño occurred prior to 1980 over a period of 110 years. The 100 synthetic datasets, on average, produce 142 months of cold-tongue El Niño in 2007–2056 as opposed to an average 107 months in the same length of the observational data; this is a 20.7% increase in the occurrence of cold-tongue El Niño compared with the observational period. Warm-pool El Niño occurred for 112 months in 2007–2056 as opposed to an average occurrence of 42 months in the observational record; this is 2.5 times the occurrence frequency in the 1980–2006 period in the synthetic datasets. As a result, occurrence frequencies of cold-tongue and warm-pool El Niño in the period of 2007–2056 become quite comparable to each other in the synthetic datasets. It is expected in the next 50 years that warm-pool El Niño will be nearly as frequent as cold-tongue El Niño.  相似文献   
72.
Equilibrium reactions involving Cu(II) and As(V) have been studied with respect to formation of complexes in aqueous solutions as well as formation of solid phases. Potentiometric titrations performed at 25 °C (I = 0.1 M Na(Cl)) and at different Cu to As ratios gave no evidence for the existence of Cu(II) arsenate complexes in solution below the pH of the precipitation boundaries (pH ≈ 4), irrespective of the Cu to As ratio and pH. Mixing of solutions of Cu(II) and As(V) at different proportions and adjusting pH to values ranging from 4 to 9 resulted in precipitation of five different solid phases. The elemental composition of the solids was determined using X-ray Photoelectron Spectroscopy, and Environmental Scanning Microscopy-Field Emission Gun equipped with an energy dispersive spectroscopy detector. The average Cu/As ratio was determined by dissolving the solids. Total soluble concentrations of the components Cu(II) and As(V), as well as the basicity of the solid phases were determined by analysis of aqueous solutions. Based upon these experimental data the stoichiometric composition of the solid phases and their stability were determined. The resulting equilibrium model includes the solid phases Cu3(AsO4)2, Cu3(AsO4)(OH)3, Cu2(AsO4)(OH), Cu5Na(HAsO4)(AsO4)3 and Cu5Na2AsO4)4, where Cu5Na(HAsO4)(AsO4)3 and Cu5Na2(AsO4)4 have not been reported previously. In 0.1 M Na(Cl), Na+ was found to be a significant component in two of the solid phases. The Cu5Na2(AsO4)4 was formed in weakly alkaline conditions with pNa < 2.5. Stability constants for all solid phases have been determined. Distribution diagrams as well as predominance area (pNa-pH) diagrams are presented to illustrate stability fields of the different solid phases.  相似文献   
73.
Twitter has emerged as a global social network of active users who share conversations with one another in an online setting. Academics are one community that has increasingly taken to Twitter as a means of connecting with other scholars, sharing research, and obtaining meaningful feedback. Tweeting has become especially popular during academic conferences where conference attendees use Twitter hashtags to filter conference conversations into a separate dialogue. For geographers, the Annual Meeting of the American Association of Geographers (AAG) represents one such occasion to use Twitter to discuss contemporary developments in geographic research. In this article, we provide an overview of Twitter as well as the ways in which the academic community uses the platform. Following this, we discuss the tweets sent using the hashtag for the 2018 AAG Annual Meeting, #AAG2018. To analyze these tweets, we collected all tweets with this hashtag for a period of four weeks and examined the content using word clouds and sentiment analysis to explore general feelings and trends associated with geography and the AAG Annual Meeting. We conclude with suggestions for future research avenues that could use Twitter data to gauge the pulse of the geographic discipline. Key Words: academic conferences, American Association of Geographers, geography, sentiment analysis, Twitter.  相似文献   
74.
We examine the equilibrium form, properties, stability and nonlinear evolution of steadily-rotating simply-connected vortex patches in the single-layer quasi-geostrophic model of geophysical fluid dynamics. This model, valid for rotating shallow-water flow in the limit of small Rossby and Froude numbers, has an intrinsic length scale L D called the “Rossby deformation length” relating the strength of the stratification to that of the background rotation. Here, we generate steadily-rotating vortex equilibria for a wide range of γ?=?L/L D , where L is the typical horizontal length scale of the vortex. We vary both γ (over the range 0.02?≤?γ?≤?10) and the vortex aspect ratio λ (over the range 0?<?λ?<?1). We find two modes of instability arising at sufficiently small aspect ratio λ?<?λ c (γ): an asymmetric (dominantly wave 3) mode at small γ (or large L D ) and a symmetric (dominantly wave 4) mode at large γ (or small L D ). At marginal stability, the asymmetric mode dominates for γ???3, while the symmetric mode dominates for γ???3. The nonlinear evolution of weakly-perturbed unstable equilibria results in major structural changes, in most cases producing two dominant vortex patches and thin, quasi-passive filaments. Overall, the nonlinear evolution can be classified into three principal types: (1) vacillations for a limited range of aspect ratios λ when 5?≤?γ?≤?6, (2) filamentation and a single-dominant vortex for γ???1, and (3) vortex splitting – asymmetric for 1???γ???4 and symmetric for γ???4.  相似文献   
75.
The highly hydrated, petrologic type 1 CM and CI carbonaceous chondrites likely derived from primitive, water‐rich asteroids, two of which are the targets for JAXA's Hayabusa2 and NASA's OSIRIS‐REx missions. We have collected visible and near‐infrared (VNIR) and mid infrared (MIR) reflectance spectra from well‐characterized CM1/2, CM1, and CI1 chondrites and identified trends related to their mineralogy and degree of secondary processing. The spectral slope between 0.65 and 1.05 μm decreases with increasing total phyllosilicate abundance and increasing magnetite abundance, both of which are associated with more extensive aqueous alteration. Furthermore, features at ~3 μm shift from centers near 2.80 μm in the intermediately altered CM1/2 chondrites to near 2.73 μm in the highly altered CM1 chondrites. The Christiansen features (CF) and the transparency features shift to shorter wavelengths as the phyllosilicate composition of the meteorites becomes more Mg‐rich, which occurs as aqueous alteration proceeds. Spectra also show a feature near 6 μm, which is related to the presence of phyllosilicates, but is not a reliable parameter for estimating the degree of aqueous alteration. The observed trends can be used to estimate the surface mineralogy and the degree of aqueous alteration in remote observations of asteroids. For example, (1) Ceres has a sharp feature near 2.72 μm, which is similar in both position and shape to the same feature in the spectra of the highly altered CM1 MIL 05137, suggesting abundant Mg‐rich phyllosilicates on the surface. Notably, both OSIRIS‐REx and Hayabusa2 have onboard instruments which cover the VNIR and MIR wavelength ranges, so the results presented here will help in corroborating initial results from Bennu and Ryugu.  相似文献   
76.
The LOw-Frequency ARray (LOFAR) is a new radio interferometer that consists of an array of stations. Each of them is a phase array of dipole antennas. LOFAR stations are distributed mostly in the Netherlands, but also throughout Europe. In the article we discuss the possibility of using this instrument for solar and space weather studies, as well as ionosphere investigations. We are expecting that in the near future the LOFAR telescope will bring some interesting observations and discoveries in these fields. It will also help to observe solar active events that have a direct influence on the near-Earth space weather.  相似文献   
77.
Cost reduction in seismic reconnaissance is an issue in geothermal exploration and can principally be achieved by sparse acquisition. To address the adherent decrease in signal/noise ratio, the common‐reflection‐surface method has been proposed. We reduced the data density of an existing 3D dataset and evaluated the results of common‐reflection‐surface processing using seismic attributes. The application of the common‐reflection‐surface method leads in all cases to an improvement of the signal/noise ratio. The most distinct improvement can be seen in the low fold regions. The improvement depends strongly on the midpoint aperture, and there is a tradeoff between reflector continuity and horizontal resolution. If small scale targets are to be imaged, a small aperture size is necessary, which may be far below the Fresnel zone for a specific reflector. The substantial reduction of the data density leads in our case to an irrecoverable information loss.  相似文献   
78.

The occurrence of disasters such as extreme flooding in urban environments has severe consequences, not only on the human population but also on critical infrastructures such as the road networks, which are of vital importance for everyday living and particularly for emergency response. In this article, our main goal is to present-conceptually and in praxis-a model that could be used from the emergency responders for timely and efficient emergency management and response in an urban complex environment. For the city of Cologne in Germany, we aim to indicate possible ways to decrease the emergency response time during an extreme flood scenario through the development of an accessibility indicator, which consists of different components. Therefore, we will investigate the opportunities that occur, in a flood risk scenario, from the use of geographic information in different forms such as Volunteered Geographic Information (VGI) and open-source data in an ArcGIS environment, to increase urban resilience through the decreasing emergency response time. We will focus on network analysis for the fire brigades (first acting emergency responders) during a flood scenario to calculate their emergency response ranges and emergency response routes through flooded road networks, for the assistance of the possibly affected hospitals, refugee homes and fire brigades, which can be flooded. At the end of the paper, we suggest that the vulnerable community of the refugees could be taken into consideration as a new source of VGI, as an additional component that would lead to the decrease in the emergency response time. The geo-located information that could be provided by the refugee community can be very useful in emergency situations, such as those examined in this article where timely information can be forwarded to the proper authorities for a more focused and timely emergency response, increasing the resilience of the urban population and their community.

  相似文献   
79.
The authors suggested acceptance criteria for rural dispersion models’ performance measures in this journal in 2004. The current paper suggests modified values of acceptance criteria for urban applications and tests them with tracer data from four urban field experiments. For the arc-maximum concentrations, the fractional bias should have a magnitude <0.67 (i.e., the relative mean bias is less than a factor of 2); the normalized mean-square error should be <6 (i.e., the random scatter is less than about 2.4 times the mean); and the fraction of predictions that are within a factor of two of the observations (FAC2) should be >0.3. For all data paired in space, for which a threshold concentration must always be defined, the normalized absolute difference should be <0.50, when the threshold is three times the instrument’s limit of quantification (LOQ). An overall criterion is then applied that the total set of acceptance criteria should be satisfied in at least half of the field experiments. These acceptance criteria are applied to evaluations of the US Department of Defense’s Joint Effects Model (JEM) with tracer data from US urban field experiments in Salt Lake City (U2000), Oklahoma City (JU2003), and Manhattan (MSG05 and MID05). JEM includes the SCIPUFF dispersion model with the urban canopy option and the urban dispersion model (UDM) option. In each set of evaluations, three or four likely options are tested for meteorological inputs (e.g., a local building top wind speed, the closest National Weather Service airport observations, or outputs from numerical weather prediction models). It is found that, due to large natural variability in the urban data, there is not a large difference between the performance measures for the two model options and the three or four meteorological input options. The more detailed UDM and the state-of-the-art numerical weather models do provide a slight improvement over the other options. The proposed urban dispersion model acceptance criteria are satisfied at over half of the field experiments.  相似文献   
80.
The effects of inorganic nutrient (N and P) and glucose C treatments on bacterial growth were followed for 3 days in natural surface and deep water bacterial samples during the main post-spring bloom stages of phytoplankton growth in the northern Baltic Sea. In addition, the importance of photochemical degradation of dissolved organic matter on bacterial growth was investigated vertically (0.1–2.0 m) and spatially, in a salinity gradient from river mouth to open sea. Bacterial production was consistently C limited in the surface layer, with N or both N and P as the secondary limiting nutrients from spring to early summer and in late summer, respectively. In deep water, bacterial growth showed combined temperature and C limitation, and in spring, this also appeared to be true with surface samples. The effect of 1-day sunlight pre-treatment varied from no effect up to a 44% production increase, with clear bacterial production responses only being seen at the surface (10 cm depth). The implications of bacterial C limitation for the structure and function of the surface plankton ecosystem, including its CO2 exchange with the atmosphere are discussed.  相似文献   
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