Monochloramine is interesting both as a selective oxidant of fulvic acid and as a drinking water disinfectant. In this study, the controlled reaction of aquatic fulvic acid with monochloramine did not result in products detectable by ether extraction-gas chromatography-flame ionization detection techniques. Evidence of a reaction was shown by bleaching of the fulvic acid solution (decreased absorbance at 465 nm) and chlorine substitution. Chlorine-containing products were quantified by the total carbon adsorbable organic halide (TOX) parameter. Bleaching and organic chlorine formation were much less extensive than in the reaction of free chlorine with fulvic acid. Monochloramine was shown to produce an organic chlorine fraction more hydrophilic and with higher molecular size than that produced by chlorine and fulvic acid. Results suggest that monochloramine may be useful tool for the investigation of certain humic functionalities because it reacts rather selectively and to a small extent with aquatic fulvic acid. 相似文献
This study shows how wavelet analysis can be used on well log and drill core data to identify cyclicity in sedimentary sequences. Three possible methods for determining wavelength were investigated: the Morlet wavelet, the Fourier transform, and the semivariogram. When applied to several hypothetical signals similar to those observed in petrophysical measurements in hydrocarbon reservoirs, all three methods could identify the presence of cyclicity. Only the wavelet scalogram, however, gave a clear indication of when the cyclic element was present and where frequency changes occurred in the signal. To illustrate the wavelet analysis, we processed well log and core data from a well in the Ormskirk Sandstone and determined the wavelet coefficients for each zone and the wavelengths of the strongest cyclicities. The cyclicities observed corresponded well with sedimentary features of the formation (e.g., channels and channel sets). Also, ratios of the cyclicity wavelengths corresponded with ratios of the Milankovitch precession, obliquity, and eccentricity periods. This result is in agreement with other investigators, who have proposed that Milankovitch-driven climate changes exercised an important control on Ormskirk Sandstone deposition. 相似文献
Life history, habitat utilisation, and biomass of benthic and pelagic opossum shrimp (Mysis relicta) were studied in the oligotrophic Lake Jonsvatn, central Norway. Sampling in the pelagic zone was done by means of a closing zooplankton net; in the benthic zone by means of a benthic beam trawl.
M. relicta had a mixed one or two year life cycle. In the autumn, the proportion of mature females and males were larger in the pelagic than in the benthic habitat. Copulation took place in late autumn, and the first females with eggs occurred in November. In February, the first juvenile M. relicta were released in the benthic habitat. In May and July, however, juveniles were found in large numbers in all parts of the lake. The length distribution of M. relicta indicates that juveniles partly segregate between benthic and pelagic habitats.
Both juvenile and adult M. relicta performed vertical diel migrations in the pelagic habitat. In the benthic habitat, diel vertical migrations along the bottom were not as pronounced as vertical migrations in the pelagic habitat. In the benthic habitat, major migrations were performed only by adults in the autumn. Our results indicate that the light intensity in the green part of the spectrum gives the proximate cue for regulation of vertical distribution of M. relicta.
The mean total biomass varied between 288 and 1576 kg dry weight, corresponding to 23.2–127.1 mg dry weight m−2 surface area. M. relicta had smallest biomass during late spring/early summer and largest biomass during autumn and early winter. Estimated pelagic biomasses were largest in February, August, October and November, while benthic biomasses were largest in May and July. Estimated biomass of pelagic M. relicta during autumn was approximately 1/10 of the estimated biomass of zooplankton in this lake. 相似文献
Characterization of carbonate rocks may involve identifying the important pore types which are present. In the past, this
task has required detailed petrographic analysis of many core samples. Here, we describe a method which uses nuclear magnetic
resonance (NMR) measurements to reduce the amount of petrographic analysis needed for porosity typing of carbonate reservoir
rocks.
For a rock sample which has been measured with NMR, our method decomposes the log(T2) spectrum into at most three Gaussian-shaped components and gives a set of nine parameters. Two characteristic quantities
having geological significance are extracted from the nine parameters. Values of the two quantities are compared with a reference
set, established from samples having both NMR and petrographic evaluations of porosity types. We use a Bayesian approach to
the classification of the dominant porosity type.
Tests of our method on 103 samples show a correct prediction in 60 to 90 percent of the samples. The lower success rate was
obtained for samples with five porosity types from three fields; the higher success rate obtained with samples with three
porosity types from one well. The use of geologically significant quantities extracted from the decomposition gives comparable
success rate to those obtained using a standard, non-geological approach such as canonical variates. 相似文献
Abstract— Shock metamorphosed quartz grains have been discovered in a drill core from the central peak of the Late Jurassic, marine Mjølnir structure; this finding further corroborates the impact origin of Mjølnir. The intersected strata represent the Upper Jurassic Hekkingen Formation and underlying Jurassic and Upper Triassic formations. The appearance, orientation, and origin of shock features in quartz grains and their stratigraphic distribution within the core units have been studied by optical and transmission electron microscopy. The quartz grains contain planar fractures (PFs), planar deformation features (PDFs), and mechanical Brazil twins. The formation of PFs is the predominant shock effect and is attributed to the large impedance differences between the water‐rich pores and constituent minerals in target sediments. This situation may have strengthened tensional/extensional and shear movements during shock compression and decompression. The combination of various shock effects indicates possible shock pressures between 5 and at least 20 GPa for three core units with a total thickness of 86 m (from 74.00 m to 171.09 m core depth). Crater‐fill material from the lower part of the core typically shows the least pressures, whereas the uppermost part of the allochthonous crater deposits displays the highest pressures. The orientations of PFs in studied quartz grains seem to become more diverse as the pressure rises from predominantly (0001) PFs to a combination of (0001), , and orientations. However, the lack of experimental data on porous sedimentary rocks does not allow us to further constrain the shock conditions on the basis of PF orientations. 相似文献