Characterization of sediments in an abandoned mining area; a case study of Mansfeld region,Germany   总被引：1，自引：0，他引：1  

Rainer?WennrichEmail author  Jürgen?Mattusch  Peter?Morgenstern  Klaus?Freyer  Hanns-Christian?Treutler  Hans-Joachim?St?rk  Lutz?Brüggemann  Albrecht?Paschke  Birgit?Daus  Holger?Weiss 《Environmental Geology》2004,45(6):818-833

The distribution of selected heavy metals, including some radionuclides, metalloids and non-metals was determined in stream sediments in a region influenced by abandoned copper mining and ore processing activities. A considerable amount of the ore processing waste with a very complex composition and highly elevated concentrations of zinc, sulfur, lead, copper, arsenic, and a lot of other elements in the range between 100 and 1,000 mg/kg (Sb, Mn, Ni, Cr, Cd, Hg, and Ag) was piled up on mine dumps. The dispersion of the pollutants originating from this source and their environmental impact were investigated. Both, sediments and original waste material were studied to indicate the pathways and the mobilization behavior of different pollutants. For this purpose, the process of the elution of pollutants by application of different fractionation schemes was studied. The capabilities of different analytical techniques are shown for the analysis of solid samples (X-ray fluorescence spectrometry, Gamma-spectrometry) and liquid ones (ICP-atomic emission spectrometry, ICP-mass spectrometry and different techniques of atomic absorption). Additionally, the coupling of ion chromatography and ICP-MS detection was used to study the distribution of arsenic species in the sediment cores of a lake which acts as a natural sink for the region.  相似文献   

Spatial Variability of Trends in the Rainfall-Runoff Relationship: A Mesoscale Study in the Mosel Basin     

Laurent Pfister  Gilles Drogue  Abdelkhalak El Idrissi  Jean-François Iffly  Christelle Poirier  Lucien Hoffmann 《Climatic change》2004,66(1-2):67-87

The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.  相似文献   

The Mesozoic–Cenozoic structural framework of the Bay of Kiel area, western Baltic Sea     

Martin Bak Hansen  Holger Lykke-Andersen  Ali Dehghani  Dirk Gajewski  Christian Hübscher  Morten Olesen  Klaus Reicherter 《International Journal of Earth Sciences》2005,94(5-6):1070-1082

A dense grid of multichannel high-resolution seismic sections from the Bay of Kiel in the western Baltic Sea has been interpreted in order to reveal the Mesozoic and Cenozoic geological evolution of the northern part of the North German Basin. The overall geological evolution of the study area can be separated into four distinct periods. During the Triassic and the Early Jurassic, E–W extension and the deposition of clastic sediments initiated the movement of the underlying Zechstein evaporites. The deposition ceased during the Middle Jurassic, when the entire area was uplifted as a result of the Mid North Sea Doming. The uplift resulted in a pronounced erosion of Upper Triassic and Lower Jurassic strata. This event is marked by a clear angular unconformity on all the seismic sections. The region remained an area of non-deposition until the end of the Early Cretaceous, when the sedimentation resumed in the area. Throughout the Late Cretaceous the sedimentation took place under tectonic quiescence. Reactivated salt movement is observed at the Cretaceous Cenozoic transition as a result of the change from an extensional to compressional regional stress field. The vertical salt movement influenced the Cenozoic sedimentation and resulted in thin-skinned faulting.  相似文献   

Arsenic fixation on iron-hydroxide-rich and plant litter-containing sediments in natural environments   总被引：2，自引：0，他引：2  

Andreas Fritzsche  Holger Dienemann  Ernst Gert Dudel 《Environmental Geology》2006,51(1):133-142

Iron-hydroxide-rich and plant litter-containing sediments from natural sites contaminated with uranium mine tailing leachates were examined for their ability to adsorb arsenic. The samples with high contents of iron hydroxides (Fe_total concentration, >300 g kg⁻¹) exhibited remarkable fixation of arsenic (up to 40 g As kg⁻¹). This value corresponded approximately to the supersaturation point for natural iron hydroxides under the present conditions, and it was significantly lower than the value found for synthetic iron hydroxides. There was a strong correlation (R=0.8999) between the concentration of iron and that of arsenic at low arsenic contents, indicating adsorption on strong binding sites. Although all the samples had noticeable contents of organic carbon (plant litter), calcium, and manganese, no obvious effect of these elements on arsenic fixation could be detected. The amount of iron hydroxides was found the only fixation-controlling parameter immediately below a leaching water source.  相似文献   

Biogenic hydrocarbons in fluid inclusions from the aberfoyle tin-tungsten deposit, Tasmania, Australia   总被引：3，自引：0，他引：3  

C. F. Hoffmann  R. W. Henley  N. C. Higgins  M. Solomon  R. E. Summons 《Chemical Geology》1988,70(4):287-299

Trace components in fluid inclusions from the Aberfoyle tin-tungsten deposit in Tasmania, Australia, were examined by thermal decrepitation-mass spectrometry. The technique involves the decrepitation of fluid inclusions by stepwise heating in the source of a mass spectrometer. In addition to water, other species identified were carbon dioxide and hydrocarbons. Detailed analysis of these hydrocarbons showed that they ranged in carbon number from C₁ up to at least C₃₃ and probably comprised, in part, biological marker compounds, previously unreported in such high-temperature environments. Their presence suggests that the fluid responsible for mineralisation was not entirely magmatic but contained a non-magmatic component evolved through fluid-rock interaction in the sedimentary country rocks.  相似文献   

Development of Emission Models and Improvement of Emission Data for Germany     

R. Friedrich  B. Wickert  P. Blank  S. Emeis  W. Engewald  D. Hassel  H. Hoffmann  H. Michael  A. Obermeier  K. Schäfer  T. Schmitz  A. Sedlmaier  M. Stockhause  J. Theloke  F.-J. Weber 《Journal of Atmospheric Chemistry》2002,42(1):179-206

Measurements and model developments with the objective to improve the quality and resolution of estimations of anthropogenic emissions are described. Measurement results on a chassis dynamometer were used to determine VOC profiles for exhaust gas emissions of passenger cars for different vehicle and fuel types and different driving modes. Further measurements resulted in emission factors and VOC profiles for lignite burning in residential stoves. Using remote sensing techniques benzene emission factors of gas stations and the efficiency of gasoline vapour recovery systems were measured.To improve the quality and the spatial and temporal resolution of emission data, emission models were improved or modified. This was done by elaborating and applying new methods for important emission source categories (e.g., solvent use, road traffic, small combustion) as well as including new data sources in the calculation routines (e.g. emission statements, land use data, import/export indices of solvents). Simultaneously considerable progress was made improving temporal and spatial allocation functions and VOC profiles. With these improvements a large number of anthropogenic emission data sets for 14 different grid projections in Germany and Europe have been generated. An emission scenario for Germany for 2010 suggests that considering air quality directives from the EU and Germany which are in force or in pipeline, German emissions of VOC and NO_x will decrease, but still exceed the national emission ceilings of the EU-NEC directive.  相似文献   

An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials   总被引：2，自引：0，他引：2  

Kenneth W.W. Sims  James B. Gill  Anthony Dosseto  Dirk L. Hoffmann  Craig C. Lundstrom  Ross W. Williams  Lary Ball  Darren Tollstrup  Simon Turner  Julie Prytulak  Justin J.G. Glessner  J.J. Standish  Tim Elliott 《Geostandards and Geoanalytical Research》2008,32(1):65-91

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).  相似文献   

Significance of boulder shape,shoreline configuration and pre-transport setting for the transport of boulders by tsunamis     

Jan Oetjen  Max Engel  Shiva P. Pudasaini  Holger Schuettrumpf 《地球表面变化过程与地形》2020,45(9):2118-2133

Research on tsunami-induced coarse-clast transport is a field of rising interest since such deposits have been identified as useful proxies for extreme-wave events (tsunamis, storm waves) that provide crucial information for coastal hazard assessment. Physical experiments are, beside in-situ observations, the foundation of our understanding of how boulders are transported by tsunamis and provide clues to the development of empirical equations and numerical models describing the processes and fundamental mechanics. Nevertheless, investigating tsunami-induced boulder transport is a comparatively young discipline and only a few experimental studies focusing on this topic have been published so far. To improve the knowledge on nearshore tsunami hydrodynamics, physical experiments utilizing real-world boulder shapes have been carried out simulating three different shore types in a wave flume. Crucial insights were gained into boulder transport hydrodynamics and data resulting from the experiments were analysed in an empirical, statistical, quantitative and qualitative manner. The regular cuboid boulder – one of the specific shapes used in the experiments – showed the longest transport distances compared to a complex, natural boulder and a flat cuboid boulder, but also significant fluctuations regarding the total transport distance. The experiments indicate a strong influence of the shore shape on boulder transport behaviour. Experimental setups of increased mean transport distances also led to a higher spreading of results. This spreading was further amplified between the idealized-shaped cuboid and the complex-shaped boulder, which is associated with a lower drag coefficient. Due to the highly sensitive boulder reaction to divergent experimental setups, the need to recognize boundary conditions overcoming commonly considered parameters (e.g. roughness or Flatness Index) in field studies and numerical models is underlined. Beside the strong influence of initial boulder submergence and alignment, both the boulder shape and shore type influence the boulder transport pattern, increasing the total transport distance by more than 350% in some cases. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Latitudinal and longitudinal variability of mesospheric winds and temperatures during stratospheric warming events   总被引：1，自引：0，他引：1  

P. Hoffmann  W. Singer  D. Keuer  W.K. Hocking  M. Kunze  Y. Murayama 《Journal of Atmospheric and Solar》2007,69(17-18):2355

Continuous MF and meteor radar observations allow detailed studies of winds in the mesosphere and lower thermosphere (MLT) as well as temperatures around the mesopause. This height region is characterized by a strong variability in winter due to enhanced planetary wave activity and related stratospheric warming events, which are distinct coupling processes between lower, middle and upper atmosphere. Here the variability of mesospheric winds and temperatures is discussed in relation with major and minor stratospheric warmings as observed during winter 2005/06 in comparison with results during winter 1998/99.Our studies are based on MF radar wind measurements at Andenes (69°N, 16°E), Poker Flat (65°N, 147°W) and Juliusruh (55°N, 13°E) as well as on meteor radar observations of winds and temperatures at Resolute Bay (75°N, 95°W), Andenes (69°N, 16°E) and Kühlungsborn (54°N, 12°E). Additionally, energy dissipation rates have been estimated from spectral width measurements using a 3 MHz Doppler radar near Andenes. Particular attention is directed to the changes of winds, turbulence and the gravity wave activity in the mesosphere in relation to the planetary wave activity in the stratosphere.Observations indicate an enhancement of planetary wave 1 activity in the mesosphere at high latitudes during major stratospheric warmings. Daily mean temperatures derived from meteor decay times indicate that strong warming events are connected with a cooling of the 90 km region by about 10–20 K. The onset of these cooling processes and the reversals of the mesospheric circulation to easterly winds occur some days before the changes of the zonal circulation in the stratosphere start indicating a downward propagation of the circulation disturbances from the MLT region to the stratosphere and troposphere during the stratospheric warming events. The short-term reversal of the mesospheric winds is followed by a period of strong westerly winds connected with enhanced turbulence rates and an increase of gravity wave activity in the altitude range 70–85 km.  相似文献   

On the constancy of the light curve of CC comae     

R. A. Breinhorst  M. Hoffmann 《Astrophysics and Space Science》1982,86(1):107-115

New photoelectric measurements were obtained in 1980. Variability of the light curve was found, which affects mostly the minima. No period change could be detected. An estimation of the uncertainty of the parameters of the system showed an effect on the ratio of the radii of about 10%.  相似文献