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91.
92.
The influence of meteorological variation, i.e., typhoon and precipitation events, on the coastal upwelling off the eastern Hainan Island was studied based on observations taken during two upwelling seasons. The observations were made in August 2007 and July 2008, respectively. We found that, in principle, similar structure of sea surface temperature and bottom temperature prevailed in both observational periods, providing evidence that upwelling events occur frequently during the summer monsoon along the eastern Hainan shelf. Based on a simple momentum balance theory, we studied the balances between momentum fluxes, wind stress, and bottom stress. The results showed that the Burger number is S ≈ 1, indicating that the cross-shelf momentum flux divergence was balanced by the wind stress and the onshore return flow occurred in the interior of the water column. Hence, a conceptual model of the upwelling structure was built for further understanding of upwelling events. In addition, it was also observed that variations in the strength of upwelling are controlled by storm events, i.e., strong northerly winds change the structure of the thermocline on the shelf significantly. The strong mixing caused by wind reduces the strength of the thermocline, in particular in coastal seas. Based on our conceptual model, a frontal zone between mixed coastal water and offshore water develops which destabilizing the water column and hence decreases the upwelling strength. Freshwaters from the two main rivers in the Wenchang Bay are confined to the coastal area less than 20–30 m deep, as confirmed by our water mass analysis. Freshwater discharge stabilized the water column, inhibiting the upwelling as shown by the potential energy calculation. Consequently, estuarine water only inhibits the upwelling in the near coastal area. Therefore, it can be concluded that estuarine water does not have a significant impact on upwelling strength on the shelf.  相似文献   
93.
Model calibration and history matching are important techniques to adapt simulation tools to real-world systems. When prediction uncertainty needs to be quantified, one has to use the respective statistical counterparts, e.g., Bayesian updating of model parameters and data assimilation. For complex and large-scale systems, however, even single forward deterministic simulations may require parallel high-performance computing. This often makes accurate brute-force and nonlinear statistical approaches infeasible. We propose an advanced framework for parameter inference or history matching based on the arbitrary polynomial chaos expansion (aPC) and strict Bayesian principles. Our framework consists of two main steps. In step 1, the original model is projected onto a mathematically optimal response surface via the aPC technique. The resulting response surface can be viewed as a reduced (surrogate) model. It captures the model’s dependence on all parameters relevant for history matching at high-order accuracy. Step 2 consists of matching the reduced model from step 1 to observation data via bootstrap filtering. Bootstrap filtering is a fully nonlinear and Bayesian statistical approach to the inverse problem in history matching. It allows to quantify post-calibration parameter and prediction uncertainty and is more accurate than ensemble Kalman filtering or linearized methods. Through this combination, we obtain a statistical method for history matching that is accurate, yet has a computational speed that is more than sufficient to be developed towards real-time application. We motivate and demonstrate our method on the problem of CO2 storage in geological formations, using a low-parametric homogeneous 3D benchmark problem. In a synthetic case study, we update the parameters of a CO2/brine multiphase model on monitored pressure data during CO2 injection.  相似文献   
94.
During the last decades, increasing exports of both dissolved organic carbon (DOC) and iron were observed from peat catchments in North America and Europe with potential consequences for water quality of streamwater and carbon storages of soils. As mobilisation and transport processes of DOC and iron in peat catchments are only partly understood, the purpose of this study was to elucidate these processes in an intensively monitored and studied system. Specifically, it was hypothesised that dissimilatory iron reduction in riparian peatland soils mobilises DOC initially adsorbed to iron minerals. During stormflow conditions, both DOC and iron will be transported into the stream network. Ferrous iron may be reoxidised at redox interfaces on its way to the stream, and subsequently, ferric iron could be transported together with DOC as complexes. To test these hypotheses, generalised additive models (GAMs) were applied to 14 years of weekly time series of discharge and concentrations of selected solutes measured in a German headwater stream called Lehstenbach. This stream drains a 4.19‐km2 forested mountain catchment; one third of which is covered by riparian peatland soils. We interpreted results of different types of GAM in the way that (a) iron reduction drove the mobilisation of DOC from peatland soils and that (b) both iron and DOC were transported as complexes after their joint mobilisation to and within the steam. It was speculated that low nitrate availability in the uppermost wetland soil layer, particularly during the growing season, promoted iron reduction and thus the mobilisation of DOC. However, the influence of nitrate on the DOC mobilisation remains relatively uncertain. This influence could be further investigated using methods similar to the GAM analysis conducted here for other catchments with long‐term data as well as detailed measurements of the relevant species in riparian wetland soils and the adjacent stream network.  相似文献   
95.
Lacustrine groundwater discharge (LGD) and the related water residence time are crucial parameters for quantifying lake matter budgets and assessing its vulnerability to contaminant input. Our approach utilizes the stable isotopes of water (δ18O, δ2H) and the radioisotope radon (222Rn) for determining long‐term average and short‐term snapshots in LGD. We conducted isotope balances for the 0.5‐km2 Lake Ammelshainer See (Germany) based on measurements of lake isotope inventories and groundwater composition accompanied by good quality and comprehensive long‐term meteorological and isotopic data (precipitation) from nearby monitoring stations. The results from the steady‐state annual isotope balances that rely on only two sampling campaigns are consistent for both δ18O and δ2H and suggested an overall long‐term average LGD rate that was used to infer the water residence time of the lake. These findings were supported by the good agreement of the simulated LGD‐driven annual cycles of δ18O and δ2H lake inventories with the observed lake isotope inventories. However, radon mass balances revealed lower values that might be the result of seasonal LGD variability. For obtaining further insights into possible seasonal variability of groundwater–lake interaction, stable water isotope and radon mass balances could be conducted more frequently (e.g., monthly) in order to use the derived groundwater discharge rates as input for time‐variant isotope balances.  相似文献   
96.
We present validation studies of MLS V2.2 and V3.3 water vapor(WV) and ozone profiles over the Tibetan Plateau(Naqu and Lhasa) and its adjacent region(Tengchong) respectively by using the balloon-borne Cryogenic Frost point Hygrometer and Electrochemical Concentration Cell ozonesonde. Coincident in situ measurements were selected to compare the MLS V2.2 and V3.3 WV and ozone profiles for understanding the applicability of the two version MLS products over the region. MLS V2.2 and V3.3 WV profiles respectively show their differences within ?2.2±15.7%(n=74) and 0.3±14.9%(n=75) in the stratosphere at and above 82.5 h Pa. Accordingly, at 100 h Pa, the altitude approaching the tropopuase height, differences are within 9.8± 46.0%(n=18) and 23.0±45.8%(n=17), and they are within 21.5±90.6%(n=104) and 6.0±83.4%(n=99) in upper troposphere. The differences of MLS ozone are within ?11.7±16.3%(n=135, V2.2) and 15.6±24.2%(n=305, V3.3) at and above 82.5 h Pa. At 100 h Pa, they are within ?3.5±54.4%(n=27) and ?8.7±41.6%(n=38), and within 18.0±79.1%(n=47) and 34.2±76.6%(n=160) in the upper troposphere. The relative difference of MLS WV and ozone profile has significant oscillation and scatter at upper troposphere and lower stratosphere partly due to the stronger gradients of WV and ozone concentrations here as well the linear interpolation of sonde data for the intercomparison. At and below 70 h Pa, the relative differences of MLS ozone are significantly larger over Lhasa during the Tibetan Plateau "ozone valley" season, which is also the Asian Summer Monsoon period. The MLS ozone differences over the three sites are similar in their vertical distributions during that period. A simple linear correlation analysis between MLS and sonde profiles indicates that the sensitivity of MLS profile products is related to concentrations at each pressure level. The MLS V3.3 product sensitivity is slightly improved for WV at and above 82.5 h Pa, whereas it is not obvious for ozone. The possible factors contributing to the differences of the MLS profile products of WV and ozone are discussed.  相似文献   
97.
Surface currents measured by high frequency (HF) radar arrays are assimilated into a regional ocean model over Qingdao coastal waters based on Kalman filter method. A series of numerical experiments are per- formed to evaluate the performance of the data assimilation schemes. In order to optimize the analysis pro- cedure in the traditional ensemble Kalman filter (ENKF), a different analysis scheme called quasiensemble Kaman filter (QENKF) is proposed. The comparisons between the ENKF and the QENKF suggest that both them can improve the simulated error and the spatial structure. The estimations of the background error covariance (BEC) are also assessed by comparing three different methods: Monte Carlo method; Canadian quick covariance (CQC) method and data uncertainty engine (DUE) method. A significant reduction of the root-mean-square (RMS) errors between model results and the observations shows that the CQC method is able to better reproduce the error statistics for this coastal ocean model and the corresponding external forcing. In addition, the sensibility of the data assimilation system to the ensemble size is also analyzed by means of different scales of the ensemble size used in the experiments. It is found that given the balance of the computational cost and the forecasting accuracy, the ensemble size of 50 will be an appropriate choice in the Qingdao coastal waters.  相似文献   
98.
Photoreduction of Hg in natural water plays a crucial role in the production of elemental Hg and its biogeochemical cycle. Solar irradiation and dissolved organic carbon (DOC) in water are considered to be the major factors inducing Hg photoreduction. We investigated Hg isotope fractionation during photoreduction and its relationship with Hg/DOC ratios. Both mass dependent (MDF) and mass independent fractionation (MIF) was observed. MIF enriched 199Hg and 201Hg in the reactant Hg(II) and thus, significantly enhanced the fractionation between odd and even isotopes. This direction of MIF is consistent with magnetic isotope effect as the underlying cause for the odd isotope enrichment in reactants. MIF also occurred in dark controls. But in the absence of light, 199Hg and 201Hg were enriched in the product Hg(0), which is not explained by magnetic isotope effects. We propose that nuclear volume effect dominated Hg isotope fractionation under these conditions. The reduction kinetics and isotope fractionation during photoreduction strongly correlated to Hg/DOC concentration ratios. Although different reduction kinetics and fractionation factors were measured at different Hg/DOC ratios, the same Hg/DOC ratios led to almost identical results. The degree of MIF for the two odd isotopes was also affected by Hg/DOC ratios. For this reason, it is critical to study Hg photoreduction at a near-natural Hg/DOC ratio in order to better simulate natural conditions. We suggest that differences in Hg-DOC binding, which varies with Hg/DOC ratios, may be responsible for the relationship between Hg/DOC ratios and Hg photoreduction.  相似文献   
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