An invariance in the carbazoles of petroleum     

张春明赵红静  胡伯良 《中国地球化学学报》2005,24(3):253-256

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.  相似文献   

The effects of land use on runoff and soil nutrient losses in a gully catchment of the hilly areas： implications for erosion control   总被引：1，自引：0，他引：1  

WANG Jun FU Bojie QIU Yang CHEN Liding CHEN Chen HU Baodong 《地理学报(英文版)》2005,15(4):396-404

1 Introduction Soiland waterlossisoneofthe worldwide environm entalissuesthreatening sustainable land use in semiarid areas.However,soiland water loss is highly variable in space and time,and its variability resultsfrom m any factorsoperating ata wide ran…  相似文献   

桂林地区古人类演化及环境变迁研分     

王华  杨琰  张会领 《地球学报》2005,26(Z1):205-208

桂林地区曾是古人类活动活跃的地区，据可以断代的古人类洞穴遗址统计，发现桂北地区大部分的洞穴遗址其年代的下限都在距今约7000a 左右，此后古人类离开了洞穴，史前文化也随之发生了重要改变。影响古人类演化的因素鹅很多，究竟是什么原因驱使古人类离开洞穴，改变生活习性，这一问题一直都是困扰考古学界的难题。本文通赤研究桂北地区洞穴遗址的堆积特点，结合洞穴沉积－堆积物的特征及其孢粉记录的古气候信息，探讨了季风气候变化对桂林地区古气候变化的影响作用和气候演变历史，揭示了桂林地区全新世以来的季风气候变化时间序列和突变事件以及对古人类生存环境的影响。距今7000a 左右为中全新世气候适宜期，东亚夏季风强盛，气温升高，桂林地区的降雨增多，一方面由于地下河水位升高，淹没了穴居洞穴，其次是由于降雨增多，导致洞穴湿度增大，从而迫使古人类搬出洞穴。  相似文献   

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway     

Zhenhan Wu  Patrick J. Barosh  Daogong Hu  Zhonghai Wu  Ye Peisheng  Liu Qisheng  Zhou Chunjing 《Engineering Geology》2005,79(3-4):267-287

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.  相似文献   

Adsorbed silica in stalagmite carbonate and its relationship to past rainfall   总被引：4，自引：0，他引：4  

Chaoyong Hu  Junhua Huang  Shucheng Xie  Yanjun Cai 《Geochimica et cosmochimica acta》2005,69(9):2285-2292

Despite considerable work on other trace elements, the incorporation of dissolved silicon from cave waters into speleothems has not been previously investigated. In this study, the controls on dissolved Si in cave waters and on adsorbed Si in resulting speleothems are therefore investigated. Bedrock (dolomite), soil water, dripping water, and cave carbonates were retrieved from Heshang Cave situated in the central Yangtze valley of China and were subjected to analysis of dissolved Si content (plus accompanying Ca and Fe analyses). Soil waters have Si/Ca of 45.5 mmol/mol, compared to only 3.2 mmol/mol in the dolomite bedrock, demonstrating that >80% of the dissolved Si must come from dissolution of silicate minerals in the soil. Drip waters have a dissolved Si concentration of ≈4.2 μg/mL, similar to that in the overlying soil water. Actively growing cave carbonates have a Si/Ca of 0.075 mmol/mol suggesting a partition coefficient for incorporation of dissolved silicon of 0.0014, in good agreement with previous laboratory studies. Extrapolating the results of these laboratory studies to the cave environment suggests that changes in Si/Ca in cave carbonates are likely to be primarily controlled by changes in drip-water Si/Ca. The drip-water Si/Ca will, in turn, be controlled by the rate of wind-blown silicate supply; by soil weathering rates; by rainfall dilution; and by precipitation of calcite. The general expectation is that these effects combine to produce high Si/Ca in speleothems during times of low rainfall. A δ¹⁸O record from a Heshang Cave stalagmite which grew between 20 and 11 thousand years ago allows these controls to be tested. Correlation of high Si/Ca with high δ¹⁸O demonstrates that regional rainfall exerts significant (but not complete) control on speleothem Si/Ca. With further understanding, speleothem Si/Ca may provide a proxy for past rainfall to complement existing proxies such as δ¹⁸O and Mg/Ca.  相似文献   

午后多重极光弧观测研究          下载免费PDF全文

温艳波  杨惠根  韩德胜  T.Araki  艾勇  刘瑞源  刘勇华  胡泽骏  陈卓天  邓忠新  刘嵘  王晶 《极地研究》2005,17(4):255-263

本文利用2001-2003年南极中山站175天全天空摄像机观测,对午后多重极光弧的出现率及其与Kp指数的关系进行了统计分析,结果表明午后多重极光弧出现率呈一单峰分布,最大发生率出现在1445UT(1645MLT),其位置在1500MLT极光热点(1300-1700MLT)近夜侧的部分。与地磁活动指数Kp的相关统计分析表明,Kp值为2-3之间时多重极光弧有较大的出现率,这说明中等地磁活动情形下午后多重极光弧有较高的出现率。事件分析表明多重极光弧的强度变化与地磁Pc5脉动具有较高的相关性,并且有类似的频谱特征,这说明午后多重极光弧可能与同时出现的Pc5地磁脉动有关。  相似文献   

松花江上游地区汞污染的化学生态效应   总被引：5，自引：0，他引：5  

王宁  朱颜明  朴明玉  孟丹 《地理科学》2005,25(6):737-741

采样分析了吉林省东部松花江上游金矿开采区及其附近水、土壤、动植物及河流沉积物样品中汞的含量，发现河流沉积物中汞的污染相当严重；受其影响当地的植物和两栖类动物——中国林蛙体内总汞和甲基汞含量也明显高于对照组。实验表明，林蛙内脏对汞的富集能力大于肌肉；秋季对汞的富集大于春季；河流沉积物中甲基汞的含量与林蛙体内甲基汞的含量有较好的正相关。汞污染的来源与区域内个体金矿的滥采滥排有直接关系，表明人类活动所产生的有毒重金属在地表过程中出现了化学生态效应。  相似文献   

黄土区人类活动影响下的 产汇流模拟研究   总被引：4，自引：0，他引：4  

池宸星  郝振纯  王玲  胡健伟 《地理科学进展》2005,24(3):101-108

日益频繁的人类活动改变了流域下垫面条件,对流域产汇流产生很大的影响。本文以黄河中游典型支流岔巴沟为研究区域,提出利用基于DEM的分布式水文模拟技术,探讨流域人类活动过程中的产汇流模拟,避免了经验公式的概化和由此引起的局限。模拟的结果证实了该方法的可行性。采用网格滞蓄的方法可以在子网格上体现人类活动引起的下垫面的变化及其对产汇流的影响,反映各个时期的产汇流条件,对降雨做出合理响应。  相似文献   

Validating the ability of the discontinuous deformation analysis method to model normal P‐wave propagation across rock fractures          下载免费PDF全文

Wenjun Gong  Yunsheng Wang  Youjun Ning  Yonghong Luo  Yujie Wang 《国际地质力学数值与分析法杂志》2017,41(10):1267-1282

The effects of fractures on wave propagation problems are increasingly abstracting the attention of scholars and engineers in rock engineering field. This study aims to fully validate the ability of discontinuous deformation analysis (DDA) to model normal P‐wave propagation across rock fractures. The effects of a single fracture and multiple parallel fractures are all tested. The results indicate that DDA can accurately reflect the fracture effects, including the fractures stiffness, the fracture spacing and the fracture number, and the effects of incident wave frequency on one‐dimensional P‐wave propagation problems. Thus, DDA is able to deal well with normal incident P‐wave propagation problems. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Effects of temporal scales and space mismatches on the TRMM 3B42 v7 precipitation product in a remote mountainous area          下载免费PDF全文

Shiva Ebrahimi  Cheng Chen  Qiuwen Chen  Yinsheng Zhang  Ning Ma  Qammerul Zaman 《水文研究》2017,31(24):4315-4327

The accurate measurement of precipitation is essential to understanding regional hydrological processes and hydrological cycling. Quantification of precipitation over remote regions such as the Tibetan Plateau is highly unreliable because of the scarcity of rain gauges. The objective of this study is to evaluate the performance of the satellite precipitation product of tropical rainfall measuring mission (TRMM) 3B42 v7 at daily, weekly, monthly, and seasonal scales. Comparison between TRMM grid precipitation and point‐based rain gauge precipitation was conducted using nearest neighbour and bilinear weighted interpolation methods. The results showed that the TRMM product could not capture daily precipitation well due to some rainfall events being missed at short time scales but provided reasonably good precipitation data at weekly, monthly, and seasonal scales. TRMM tended to underestimate the precipitation of small rainfall events (less than 1 mm/day), while it overestimated the precipitation of large rainfall events (greater than 20 mm/day). Consequently, TRMM showed better performance in the summer monsoon season than in the winter season. Through comparison, it was also found that the bilinear weighted interpolation method performs better than the nearest neighbour method in TRMM precipitation extraction.  相似文献