运用STOMP数值模拟器进行多空介质中尿素水解以及方解石沉淀数值模拟          下载免费PDF全文

郭娈靖  Hai Huang  Bill X.Hu 《地学前缘》2010,17(6):117-133

遍布于美国能源部所辖野外场地的地下放射性核素和痕量金属污染对美国能源部的长期监管职能提出了最严峻的挑战。目前较有前景的一个原地固化污染物方法是利用尿素酶催化尿素水解,进而推动方解石沉淀及与之共同沉淀。运用STOMP数值模拟器实施一系列反应性溶质数值模拟来研究系统中水流、运移、反应与反应导致的介质性质变化之间的紧密的非线性耦合,并在研究中系统性增加反应系统的复杂度和物理-化学的非均质性以考察模拟效果。通过调整反应速率表达式中尿素酶浓度和沉淀反应常数,对尿素水解和方解石沉淀速率进行了敏感度分析。结果显示:尿素水解速率是矿物沉淀总量的决定性因素,沉淀物的空间分布既取决于水解速率也取决于沉淀速率;在一维水流柱6个空隙体积的时间段模拟中,观察到了5%的最大空隙度减少;当二维模拟中考虑一个低渗透性包裹体时,被改变的流场重新对生成的沉淀组成物进行了分布,形成了扭曲的反应锋面。模拟结果也显示沉淀在低渗透性区域边界上形成,这说明位于这个区域里面的污染物可能被囊裹而从流线中被隔离起来。  相似文献   

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例   总被引：1，自引：0，他引：1       下载免费PDF全文

张斌  黄凌  吴英  王辉  崔洁 《地学前缘》2010,17(4):270

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。  相似文献   

Some Fundamental Issues in Dynamic Compression and Tension Tests of Rocks Using Split Hopkinson Pressure Bar   总被引：12，自引：7，他引：5  

Feng Dai  Sheng Huang  Kaiwen Xia  Zhuoying Tan 《Rock Mechanics and Rock Engineering》2010,43(6):657-666

Accurate characterizations of rock strengths under higher loading rates are crucial in many rock engineering applications. The split Hopkinson pressure bar (SHPB) system has been used to quantify the dynamic compressive strength of rocks using the short cylindrical specimen and the dynamic tensile strength of rocks using the Brazilian disc (BD) specimen. However, SHPB is a standard tool that is suitable for metal testing; there are some fundamental issues that need to be carefully visited in applying SHPB to rock dynamic tests. This paper addresses several such critical issues, including the choice of slenderness ratio of the compressive specimen, the effect of friction between the sample and bars on the measured results of compressive strength, the necessity of dynamic force balance on the dynamic BD test, and the validity of using the standard BD equation in the data reduction. We show that with proper experimental designs that address these issues, the dynamic compressive strength and dynamic tensile strength of rocks measured using SHPB are valid and reliable.  相似文献   

Characteristics and potential environmental consequence of weathered materials in the surface layer of a spontaneously combusting mine spoil stockpile     

W. Lu  C. Lin  Y. Ma  S. Huang  C. Si  Y. Liu  J. Li 《Applied Geochemistry》2010

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Field-observed phenomena of seismic liquefaction and subsidence during the 2008 Wenchuan earthquake in China   总被引：10，自引：8，他引：2  

Yu Huang  Ximiao Jiang 《Natural Hazards》2010,54(3):839-850

In the 2008 Wenchuan earthquake in Sichuan Province, a large number of buildings, water conservancy facilities, and transportation facilities were severely damaged. The damage caused by liquefaction and earthquake-induced soil subsidence was widely distributed, diverse, and extensive. Typical liquefaction and earthquake-induced subsidence damage for this region has been described by investigations of soils and foundations in the earthquake-stricken area. Factors that influenced the liquefaction of soils in Dujiangyan County were analyzed, accounting for regional geological conditions. The results identify several factors that may affect the process of liquefaction and general damage to buildings, roads, levees, and dams. Such factors could serve as the basis for further research into mitigating the damage caused by earthquake-induced liquefaction and subsidence. The importance of detailed ground reconnaissance and the implementation of reasonable and effective measures to improve soft soil are proposed for earthquake hazard reduction in similar areas.  相似文献   

赣南地区石雷石英闪长岩的成因:岩石化学、副矿物微量元素、锆石U-Pb年代学与Sr-Nd-Hf同位素制约   总被引：5，自引：2，他引：3  

李光来  华仁民  胡东泉  黄小娥  张文兰  王旭东 《岩石学报》2010,26(3):903-918

石雷石英闪长岩是赣南崇-余-犹地区比较特殊的闪长质侵入体。锆石的原位U-Pb定年表明,该岩体侵位于433.5±3.4Ma。全岩主量元素特征上显示出中偏酸性(SiO2=56.92%～64.70%),富Al(Al2O3=14.10%～14.83%),富碱(Alk=6.41%～7.40%)特别是富钾(K2O=3.86%～4.85%),镁、铁含量较高,MgO:3.47%～5.95%,FeOT:5.23%～8.14%以及低磷(P2O5=0.27%～0.4%)的特点;微量元素上主要富集K、Rb、Cs等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti、P等高场强元素。磷灰石微量元素特征上显示高度富集稀土元素特别是轻稀土元素的特征;具有Eu的负异常(δEu=0.37～0.45)。ISr位于0.7073～0.7132之间,εNd(t)变化于-8.41～-4.97之间,两阶段钕模式年龄介于1.58～1.86Ga之间,Hf同位素组成相对均一,εHf(t)主要集中变化于-8～-2之间,两阶段Hf模式年龄加权平均为1.77±0.09Ga,这些特征都暗示了该石英闪长质岩体的形成是强烈壳幔相互作用的产物,区内加里东晚期可能发生了局部的岩石圈的减薄。  相似文献   

双翼弧平式长螺旋锚杆成孔钻具工艺技术研究     

黄选成  林世文  葛连英 《岩土工程技术》2010,24(4):189-193

通过对以往黏性土层锚杆钻具成孔出现的问题分析,查明了常规取芯钻具与短螺旋钻具在水平方向小角度成孔过程中,土体失去了原始均衡应力造成钻孔缩径,使扰土不能及时输出孔外,是产生堵孔塌孔的直接原因.为此研制了长螺旋锚杆成孔钻具,解决了成孔时扰土输出问题,创新的旋板解决了钻孔内壁土颗粒结构松弛问题,并且彻底解决了在黏性土层中锚杆成孔塌堵现象,保证锚杆成孔设计角度,形成一套较为标准的长螺旋锚杆钻具成孔操作规则.  相似文献   

Quantitative vulnerability estimation for scenario-based landslide hazards   总被引：4，自引：1，他引：3  

Zhihong Li  Farrokh Nadim  Hongwei Huang  Marco Uzielli  Suzanne Lacasse 《Landslides》2010,7(2):125-134

Within the engineering profession and natural sciences, vulnerability is widely accepted to be defined as the degree of loss (or damage) to a given element or set of elements within the area affected by a threat. The value of vulnerability is expressed nondimensionally between 0 and 1. It is a fundamental component in the evaluation of landslide risk, and its accurate estimation is essential in making a reasonable prediction of the landslide consequences. Obviously, vulnerability to landslides depends not only on the characteristics of the element(s) at risk but also on the landslide intensity. This paper summarizes previous research on vulnerability to landslides and proposes a new quantitative model for vulnerability of structures and persons based on landslide intensity and resistance of exposed elements. In addition, an approximate function is suggested for estimating the vulnerability of persons in structures. Different methods for estimating the vulnerability of various elements to slow or rapid landslides are discussed. Finally, the application of the new model is illustrated through an example.  相似文献   

Assessment of the risk of rockfalls in Wu Gorge, Three Gorges, China   总被引：3，自引：0，他引：3  

Huang Bolin  Chen Lide  Peng Xuanming  Liu Guanning  Chen Xiaoting  Dong Haogang  Lei Tianci 《Landslides》2010,7(1):1-11

In 2007 and 2008, six big damaging rockfalls occurred at four sites in Wu Gorge, the second gorge of the Three Gorges, China. Detailed surveys and aerial-photographic interpretation identified 104 potentially dangerous rock masses. This paper reviews previous rock-mass risk ratings, examines dangerous rock-mass structure and presents a new assessment system for rockfall risk (ASRFR) in the Wu Gorge area. The ASRFR considers 15 factors: seven factors for hazard and eight factors for consequence. Relative importance weights for these factors are ascertained using an analytic hierarchy process. Using an equation to calculate the risk, the 104 dangerous rock masses were divided into three risk groups: high risk (33 sites), medium risk (33 sites) and low risk (38 sites). The ASRFR analysis can be used to divide the shipping route through the Wu Gorge into seven courses each of one of three classes: safe-route regions, yellow-alarm regions and red-alarm regions. The system provides geological information and a rockfall-risk management tool for local government and the shipment-route department.  相似文献   

珠江口盆地东沙隆起珠江组层序界面的识别及划分   总被引：5，自引：0，他引：5  

黄诚  傅恒  汪瑞良  周小康  陶碧娥 《海相油气地质》2010,15(3)

在掌握珠江口盆地东沙隆起年代地层、生物地层和岩石地层信息的基础上,通过对测井/录井、地震、古生物、岩心及成岩等相关资料的研究,将珠江组划分出四个三级层序和五个层序界面,归纳出四类界面标志,即沉积标志、成岩标志、测井标志和地震标志。各种界面标志的识别方法都有其特点和局限,实际应用时应综合利用,相互印证,以使层序界面划分更具有可靠性和精确性。  相似文献