Contens of Volume 59     

Henry F. Diaz  Jon K. Eischeid  Chris Duncan  Raymond S. Bradley 《Climatic change》2003,59(3):417-418

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Putting Japanese investment in Europe in its place   总被引：1，自引：0，他引：1  

Peter Dicken  Adam Tickell  Henry Yeung 《Area》1997,29(3):200-212

Summary Research on Japanese economic activity in Europe concentrates almost exclusively on investment in manufacturing. However, this paper demonstrates that this emphasis both underestimates the longevity of Japanese direct investment in Europe and also grossly underdefines the importance of services. Not only does Japanese direct investment have a much longer history in Europe than is usually recognized but also—and perhaps more significantly—the bulk of that investment is not in manufacturing production per se but in a variety of circulation services. Using establishment-level data, this paper shows that the spatial manifestation of these circulation services is very different from that of manufacturing production.  相似文献   

Induced stresses and fault potential in eastern Canada due to a realistic load: a preliminary analysis   总被引：1，自引：0，他引：1  

Patrick Wu  Henry S. Hasegawa 《Geophysical Journal International》1996,127(1):215-229

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CURRENT GEOSCIENCE LABORATORIES GEOANALYTICAL PROGRAMS AND THEIR QUALITY ASSURANCE UNDERPINNINGS     

Jean M. RICHARDSON  Peter C. LIGHTFOOT  Hugh de  SOUZA 《Geostandards and Geoanalytical Research》1996,20(1):141-156

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The reaction MgCr2O4 + SiO2 = Cr2O3 + MgSiO3 and the free energy of formation of magnesiochromite (MgCr2O4)     

Stephan Klemme  Hugh S. C. O'Neill 《Contributions to Mineralogy and Petrology》1997,130(1):59-65

Low-temperature heat capacity measurements for MgCr₂O₄ have only been performed down to 52 K, and the commonly quoted third-law entropy at 298 K (106 J K⁻¹ mol⁻¹) was obtained by empirical extrapolation of these measurements to 0 K without considering the magnetic or electronic ordering contributions to the entropy. Subsequent magnetic measurements at low temperature reveal that the Néel temperature, at which magnetic ordering of the Cr³⁺ ions in MgCr₂O₄ occurs, is at ∼15 K. Hence a substantial contribution to the entropy of MgCr₂O₄ has been missed. We have determined the position of the near-univariant reaction MgCr₂O₄+SiO₂=MgSiO₃+Cr₂O₃. The reaction, which has a small positive slope in P-T space, has been bracketed at 100 K intervals between 1273 and 1773 K by reversal experiments. The reaction is extremely sluggish, and lengthy run times with a flux (H₂O, BaO-B₂O₃ or K₂O-B₂O₃) are needed to produce tight reversal brackets. The results, combined with assessed thermodynamic data for Cr₂O₃, MgSiO₃ and SiO₂, give the entropy and enthalpy of formation of MgCr₂O₄ spinel. As expected, our experimental results are not in good agreement with the presently available thermodynamic data. We obtain Δ _f H ^∘ ₂₉₈=−1759.2±1.5 kJ mol⁻¹ and S ^∘ ₂₉₈=122.1±1.0 J K⁻¹ mol⁻¹ for MgCr₂O₄. This entropy is some 16 J K⁻¹ mol⁻¹ more than the calorimetrically determined value, and implies a value for the magnetic entropy of MgCr₂O₄ consistent with an effective spin quantum number (S') for Cr³⁺ of 1/2 rather than the theoretical 3/2, indicating, as in other spinels, spin quenching. Received: 9 May 1997 / Accepted: 28 July 1997  相似文献   

The replacement of anthophyllite by jimthompsonite: a model for hydration reactions in biopyriboles     

Bernard Henry Grobéty 《Contributions to Mineralogy and Petrology》1997,127(3):237-247

Anthophyllite crystals found in ultramafic lenses of the Lepontine Alps (Switzerland) contain coherent, submicroscopic intergrowths of ordered and disordered biopyribole polysomes. The chain width distributions of disordered polysomes were analyzed using high resolution transmission electron microscopy (HRTEM). Chains wider than triple were interpreted as intermediate products in the transformation of anthophyllite to the triple chain silicate jimthompsonite. The concentration of individual chain types is strongly correlated with the reaction progress. Based on observed zipper terminations and the transformation rules given by Veblen and Buseck (1980) a scheme of possible reaction paths leading from anthophyllite to jimthomp sonite is proposed. The reaction scheme and a simple kinetic model for elementary reactions allow modeling of the observed chain width distributions. The model suggests that the complex reaction paths involving steps with increasing and decreasing chain width are more important in the formation of jimthompsonite than the direct transformation from anthophyllite. The wide chains (>triple) occurring as intermediate products of the multi-step paths are structurally closer to talc than jimthompsonite. The back-transformation of these wide chains to triple chains is, therefore, a strong argument that jimthompsonite is a stable phase and not only a metastable intermediate product in the transformation of anthophyllite to talc. Received: 8 July 1996 / Accepted: 13 December 1996  相似文献   

Submarine Ground Water Discharge and Salt Penetration Across the Sea Floor   总被引：1，自引：0，他引：1  

Henry Bokuniewicz  Meagen Pollock  John Blum  Robert Wilson 《Ground water》2004,42(7):983-989

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Variographic analysis of tropical forest cover from multi-scale remotely sensed imagery     

Sergio Colombo  Mario Chica-Olmo  Francisco Abarca  Hugh Eva 《ISPRS Journal of Photogrammetry and Remote Sensing》2004,58(5-6):330-341

Tropical forest mapping is one of the major environmental concerns at global and regional scales in which remote sensing techniques are firmly involved. This study examines the use of the variogram function to analyse forest cover fragmentation at different image scales. Two main aspects are considered here: (1) analysis of the spatial variability structure of the forest cover observed at three different scales using fine, medium and coarse spatial resolution images; and (2) the study of the relationship between rescaled images from the finest spatial resolution and those of the medium and coarse spatial resolutions. Both aspects are analysed using the variogram function as a basic tool to calculate and interpret the spatial variability of the forest cover. An example is presented for a Brazilian tropical forest zone using satellite images of different spatial resolutions acquired by Landsat TM (30 m), Resurs MSU (160 m) and ERS ATSR (1000 m). The results of this study contribute to establishing a suitable spatial resolution of remotely sensed data for tropical forest cover monitoring.  相似文献   

Controls on iron-isotope fractionation in organic-rich sediments (Kimmeridge Clay, Upper Jurassic, Southern England)     

Alan Matthews  Helen S. Morgans-Bell  Hugh C. Jenkyns  Ludwik Halicz 《Geochimica et cosmochimica acta》2004,68(14):3107-3123

This study explores the fractionation of iron isotopes (⁵⁷Fe/⁵⁴Fe) in an organic-rich mudstone succession, focusing on core and outcrop material sampled from the Upper Jurassic Kimmeridge Clay Formation type locality in south Dorset, UK. The organic-rich environments recorded by the succession provide an excellent setting for an investigation of the mechanisms by which iron isotopes are partitioned among mineral phases during biogeochemical sedimentary processes.Two main types of iron-bearing assemblage are defined in the core material: mudstones with calcite ± pyrite ± siderite mineralogy, and ferroan dolomite (dolostone) bands. A cyclic data distribution is apparent, which reflects variations in isotopic composition from a lower range of δ⁵⁷Fe values associated with the pyrite/siderite mudstone samples to the generally higher values of the adjacent dolostone samples. Most pyrite/siderite mudstones vary between −0.4 and 0.1‰ while dolostones range between −0.1 and 0.5‰, although in very organic-rich shale samples below 360 m core depth higher δ⁵⁷Fe values are noted. Pyrite nodules and pyritized ammonites from the type exposure yield δ⁵⁷Fe values of −0.3 to −0.45‰. A fractionation model consistent with the δ⁵⁷Fe variations relates the lower δ⁵⁷Fe pyrite and siderite ± pyrite mudstones values to the production of isotopically depleted Fe(II) during biogenic reduction of the isotopically heavier lithogenic Fe(III) oxides. A consequence of this reductive dissolution is that a ⁵⁷Fe-enriched iron species must be produced that potentially becomes available for the formation of the higher δ⁵⁷Fe dolostones. An isotopic profile across a dolostone band reveals distinct zonal variations in δ⁵⁷Fe, characterized by two peaks, respectively located above and below the central part of the band, and decoupling of the isotopic composition from the iron content. This form of isotopic zoning is shown to be consistent with a one-dimensional model of diffusional-chromatographic Fe-isotope exchange between dolomite and isotopically enriched pore water. An alternative mechanism envisages the infiltration of dissolved ferrous iron from variable (high and low) δ⁵⁷Fe sources during coprecipitation of Fe(II) ion with dolomite. The study provides clear evidence that iron isotopes are cycled during the formation and diagenesis of organic carbon-rich sediments.  相似文献   

‘Committing to Place’ at the Local Scale: the potential of youth education programs for promoting community participation in regional natural resource management     

Ruth Lane  Damian Lucas  Frank Vanclay  Sophie Henry  Ian Coates 《The Australian geographer》2005,36(3):351-367

Emerging approaches to environmental governance require a greater level of community participation than did previous approaches in which these responsibilities largely rested with government agencies. There is consequently a need for increased engagement with NRM among a broad community sector. This paper examines initiatives by two prominent government agencies, the Murray–Darling Basin Commission (MDBC) and the National Museum of Australia (NMA), to engage school children from regional communities using education programs that focus on place and environmental health. We focus on the MDBC's International Riverhealth Conference held in Mildura in 2003 and the associated Murray–Darling Basin TalkBack Classroom sponsored by the NMA and the Parliamentary Education Office (PEO). We explore how key themes of local scale, place-based identities, youth voice and critical engagement are developed in these programs and consider how they relate to the environmental agency of children. We then reflect on the potential for the kinds of environmental agency promoted through these programs to help build the capacity of local communities to progress larger goals of environmental restoration and sustainability in the Murray–Darling Basin. The evaluation research reported here forms part of the Committing to Place research project, an Australian Research Council Linkage grant involving the University of Tasmania, the National Museum of Australia and the Murray–Darling Basin Commission.  相似文献