Removal of organic matter from reservoir water: mechanisms underpinning surface chemistry of natural adsorbents     

S. Hussain  J. van Leeuwen  R. Aryal  B. Sarkar  C. W. K. Chow  S. Beecham 《International Journal of Environmental Science and Technology》2018,15(4):847-862

One of the key challenges in water treatment industry is the removal of organic compounds by cost-effective methods. This study evaluated the adsorptive removal of dissolved organic carbon (DOC) from reservoir water using fuller’s earth (FE) in comparison with natural (SQ) and modified quartz (MSQ) sands. The removal capacities of FE at different contact times, pH levels, adsorbent dosages and initial DOC concentrations were compared with both the quartz sands. The optimum DOC removals by FE and SQs were achieved at contact time of 60 and 30 min, pH level of 6 and 4, and at adsorbent dose of 1.5 g/150 mL and 10 g/100 mL, respectively. The adsorption capacity of FE (1.05 mg/g) was much higher compared to the MSQ (0.04 mg/g) and SQ (0.01 mg/g). Adsorption equilibrium data better fitted to the Freundlich model than to the Langmuir model, suggesting that adsorption occurred primarily through multilayer formation onto the surfaces of FE and SQ. The pseudo-second-order model described the uptake kinetics more effectively than the pseudo-first-order and intra-particle diffusion models, indicating that the mechanism was primarily governed by chemisorption. These observations were well supported by the physiochemical characteristics and charge behaviour of the adsorbents. In mass-transfer study, the results of liquid film diffusion model showed that the adsorption of DOC on FE was not controlled by film diffusion, but other mechanisms also played an essential role. This study demonstrates that FE is an effective adsorbent for the removal of DOC in surface water treatment.  相似文献   

Geochemical characteristics of mafic and ultramafic rocks from the Naga Hills Ophiolite,India:Implications for petrogenesis     

Ajoy Dey  M.Faruque Hussain  Mrigendra N.Barman 《地学前缘(英文版)》2018,9(2):517-529

The Naga Hills Ophiolite(NHO) represents one of the fragments of Tethyan oceanic crust in the Himalayan Orogenic system which is exposed in the Phek and Kiphire districts of Nagaland, India. The NHO is composed of partially serpentinized dunite, peridotite, gabbro, basalt, minor plagiogranite,diorite dyke and marine sediments. The basalts are mainly composed of fine grained plagioclase feldspar, clinopyroxene and orthopyroxene and show quenching and variolitic textures. The gabbros are characterized by medium to coarse grained plagioclase, orthopyroxene and clinopyroxene with ophitic to sub-ophitic textures. The ultramafic cumulates are represented by olivine, Cpx and Opx.Geochemically, the basalts and gabbros are sub-alkaline to alkaline and show tholeiitic features.The basalts are characterized by 44.1-45.6 wt.% of SiO_2 with 28-38 of Mg#, and the gabbros by38.7-43.7 wt.% of SiO_2, and 26-79 of Mg#. The ultramafic rocks are characterized by 37.4-52.2 wt.% of SiO_2, and 80-88 of Mg#. In multi-element diagrams(spidergrams) both basalts and gabbros show fractionated trends with strong negative anomalies of Zr. Nb. Sr and a gentle negative anomaly of P.However, the rare earth element(REE) plots of the basalts and gabbros show two distinct patterns. The first pattern, represented by light REE(LREE) depletion, suggests N-MORB features and can be interpreted as a signature of Paleo-Tethyan oceanic crust. The second pattern, represented by LREE enrichment with negligible negative Eu anomaly, conforms to E-MORB, and may be related to an arc tectonic setting. In V vs. Ti/1000, Cr vs. Y and AFM diagrams, the basalts and gabbros plot within Island Arc Tholeiite(IAT) and MORB fields suggesting both ridge and arc related settings. The ultramafic rocks exhibit two distinct patterns both in spidergrams and in REE plots. In the spidergram, one group displays highly enriched pattern, whereas the other group shows near flat pattern compared to primordial mantle. In the REE plot, one group displays steeper slopes [(La/Yb)N = 4.340-4.341], whereas the other displays moderate to flat slopes [(La/Yb)N = 0.97-1.67] and negative Eu-anomalies. Our study suggests that the ultramafic rocks represent two possible mantle sources(fertile and refractory).  相似文献   

Rainfall-induced landslide in the active frontal fold–thrust belt of Northwestern Himalaya,Jammu: dynamics inferred by geological evidences and Ground Penetrating Radar     

Yudhbir Singh  Ahsan Ul Haq  G. M. Bhat  S. K. Pandita  Arjun Singh  Rameshwar Sangra  Gulzar Hussain  S. S. Kotwal 《Environmental Earth Sciences》2018,77(16):592

Landslides are the most established geological hazards in the frontal fold–thrust belt of Northwestern Himalaya comprising of Siwaliks and Murree strata. The continuous rainfall from 2 to 6 September, 2014 caused a massive landslide at village Sadal in Udhampur district of Jammu and Kashmir state. The landslide occurred in the early morning of September 6, 2014, destroying entire Sadal habitation comprising 45 houses, and killing 41 people and more than 500 domestic animals. Google earth images of pre and post-landslide events along with the field measurements show the kinematics of upper and lower parts of the slide. Horizontal and vertical components of displacement and mode of failure suggest the landslide as of complex nature. The shallow subsurface geophysical imaging through Ground Penetrating Radar (GPR) survey shows the failure plane composed of friable mudstone bed underlain by massive mudstone and overlain by cross-bedded sandstone. The depth of debris material above the failure plane ranges from 6 m at Site S1a-b to 10 m at Site-S2b and 20 m at Site S3a. The velocity analysis of Site-3 shows four thick layers represented from bottom to surface by L1—sandstone (V?=?0.16 m/ns, travel time?=?356.36 ns), L2—mudstone (V?=?0.17 m/ns, travel time?=?288.48 ns), L3—massive mudstone (V?=?0.19 m/ns, travel time 220.68 ns), and L4—cross-laminated sandstone (V?=?0.20 m/ns, travel time?=?77.58 ns) overlaying the failure plane. The study shows the landslide occur along the western limb of a fold identified during the present work. We mapped an old landslide on the same limb which shows 5–6 m-thick subsurface debris material with thick rock fragments involved in the landslide process. The detailed geological and geophysical investigations suggest that both the landslides were triggered by extreme rain fall events.  相似文献   

Cadmium (Cd) concentration in wheat (<Emphasis Type="Italic">Triticum aestivum</Emphasis>) grown in Cd-spiked soil varies with the doses and biochar feedstock     

Muhammad Zia ur Rehman  Muhammad Rizwan  Shafaqat Ali  Muhammad Irfan Sohail  Amjad Hussain  Muhammad Farooq Qayyum  Hinnan Khalid  Muhammad Zeeshan  Naveeda Majid 《Arabian Journal of Geosciences》2018,11(21):685

Biochar is considered a promising amendment for the reduction of metal concentration in plants; however, the effects of biochar in terms of dose and feedstock on metal uptake by plants remain widely unclear. In the current study, three individual biochars were prepared at 450 °C from different feedstocks (wheat straw, sukh chain (Pongamia pinnata), and cotton sticks). The main aim was to evaluate their ability to remediate cadmium (Cd)-spiked soil in terms of growth response and Cd uptake by wheat (Triticum aestivum) tissues. Biochars were separately applied at 0, 1, and 2% (w/w) in Cd-spiked soil and wheat was grown until maturity in pots and then morphological and physiological parameters and Cd concentrations in grains, roots, and shoots were determined. The post-harvest soil was analyzed for extractable Cd concentrations. Plants grown in Cd-spiked soil treated with biochars had higher seed germination, lengths of roots, shoots, and spikes, grains per spike and leaf relative water contents, chlorophyll contents, and dry weight of roots, shoots, and grains as compared to the untreated control. Biochar treatments significantly decreased the Cd concentrations in shoots, roots, and grains as well as total Cd uptake by grains. Soil extractable Cd concentrations were significantly decreased with biochar treatments. The application of 2.0% wheat straw biochar was the most efficient treatment in increasing grain yield and decreasing Cd in grains as well as soil extractable Cd than the other two biochars and doses applied.  相似文献   

Lithologic characteristics and diagenesis of the Devonian Jauf sandstone at Ghawar Field, Eastern Saudi Arabia     

Khalid A. Al-Ramadan  Mahbub Hussain  Badrul Imam  Salih Saner 《Marine and Petroleum Geology》2004,21(10):1221-1234

The Lower Devonian Jauf Formation in Saudi Arabia is an important hydrocarbon reservoir. However, in spite of its importance as a reservoir, published studies on the Jauf Formation more specifically on the reservoir quality (including diagenesis), are very few. This study, which is based on core samples from two wells in the Ghawar Field, northeastern Saudi Arabia, reports the lithologic and diagenetic characteristics of this reservoir. The Jauf reservoir is a fine to medium-grained, moderate to well-sorted quartz arenite. The diagenetic processes recognized include compaction, cementation (calcite, clay minerals, quartz overgrowths, and a minor amount of pyrite), and dissolution of the calcite cements and of feldspar grains. The widespread occurrences of early calcite cement suggest that the Jauf reservoir lost a significant amount of primary porosity at a very early stage of its diagenetic history. Early calcite cement, however, prevented the later compaction of the sandstone, thus preserving an unfilled part of the primary porosity. Based on the framework grain–cement relationships, precipitation of the early calcite cement was either accompanied or followed by the development of part of the pore-lining and pore-bridging clay cement. Secondary porosity development occurred due to partial to complete dissolution of early calcite cements and feldspar. Late calcite cement occurs as isolated patches, and has little impact on reservoir quality of the sandstones.In addition to calcite, several different clay minerals including illite and chlorite occur as pore-filling and pore-lining cements. While the pore-filling illite and chlorite resulted in a considerable loss of porosity, the pore-lining chlorite may have helped in retaining the porosity by preventing the precipitation of syntaxial quartz overgrowths. Illite, which largely occurs as hair-like rims around the grains and bridges on the pore throats, caused a substantial deterioration to permeability of the reservoir. Diagenetic history of the Jauf Formation as established here is expected to help better understanding and exploitation of this reservoir.  相似文献   

On the relationship between Indian Ocean Dipole events and the precipitation of Pakistan     

Hussain  Mian Sabir  Kim  Sunyoung  Lee  Seungho 《Theoretical and Applied Climatology》2017,130(1-2):673-685

This study investigated the relationship between the Indian Ocean Dipole (IOD) and the precipitation of Pakistan using data for the period of 1958–2010. The long-term evolution of the IOD index did not show interannual patterns similar to those of the annual precipitation of Pakistan. No linkage between the co-occurring trends of the IOD and the precipitation was traced during the period of investigation. The correlation between the IOD and the precipitation of Pakistan indicated a noteworthy impact over the monsoonal regions, especially the coastal area and the western region of Pakistan, which showed a significant positive correlation between the IOD index and annual and summer precipitation. A significant positive relationship was also revealed between the precipitation of the Balochistan Plateau and the IOD index for the summer monsoon season. No connection was observed between the IOD and the precipitation of the northern regions and the upper Indus Plain of Pakistan. Positive phases of the IOD have been noted to occur along with surplus precipitation during active monsoon conditions. The southeasterly wind moves from the Arabian Sea and transports additional moisture from the Arabian Sea to the coastal and southwestern parts of Pakistan during positive phases of the IOD.

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A statistical downscaling model for summer rainfall over Pakistan     

Dildar Hussain Kazmi  Jianping Li  Chengqing Ruan  Sen Zhao  Yanjie Li 《Climate Dynamics》2016,47(7-8):2653-2666

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Object-based urban land cover classification using rule inheritance over very high-resolution multisensor and multitemporal data     

Ejaz Hussain  Jie Shan 《地理信息系统科学与遥感》2016,53(2):164-182

Very high spatial and temporal resolution remote sensing data facilitate mapping highly complex and diverse urban environments. This study analyzed and demonstrated the usefulness of combined high-resolution aerial digital images and elevation data, and its processing using object-based image analysis for mapping urban land covers and quantifying buildings. It is observed that mapping heterogeneous features across large urban areas is time consuming and challenging. This study presents and demonstrates an approach for formulating an optimal land cover classification rule set over small representative training urban area image, and its subsequent transfer to the multisensor, multitemporal images. The classification results over the training area showed an overall accuracy of 96%, and the application of rule set to different sensor images of other test areas resulted in reduced accuracies of 91% for the same sensor, 90% and 86% for the different sensors temporal data. The comparison of reference and classified buildings showed ±4% detection errors. Classification through a transferred rule set reduced the classification accuracy by about 5%–10%. However, the trade-off for this accuracy drop was about a 75% reduction in processing time for performing classification in the training area. The factors influencing the classification accuracies were mainly the shadow and temporal changes in the class characteristics.  相似文献   

The effects of land-based activities on the near-shore environment of the Red Sea,Egypt     

Mahmoud A. Dar  Fatma A. Fouda  Atif M. El-Nagar  Hussain M. Nasr 《Environmental Earth Sciences》2016,75(3):188

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Spatial analysis of anthropogenic disturbances in mangrove forests of Bhitarkanika Conservation Area,India     

K. R. Ambastha  S. A. Hussain  R. Badola  P. S. Roy 《Journal of the Indian Society of Remote Sensing》2010,38(1):67-83

The dependence of coastal communities on mangrove forests for direct consumptive use due to the scarcity of alternate resources makes them one of the highly disturbed landscapes. This paper examines the spatial characteristics and extent of anthropogenic disturbances affecting the mangrove forests of Bhitarkanika Conservation Area situated along the east coast of India by using remotely sensed data and GIS, supplemented with socioeconomic surveys. The study reveals that resource extractions from these forests were considerable despite the protected status. Around 14% of the total fuel wood consumed annually in each of the household came from the mangrove forests of the Park. The patterns of consumption were spatially heterogeneous, controlled by the availability of alternatives, ease of accessibility, presence of markets, human density, and forest composition. The disturbance surface showed 30% of the major forest classes to be under high to very high levels of disturbance especially at easy access points. Besides, the distribution of economically useful species also determined the degree of disturbance. Resource use surfaces clearly identified the biotic pressure zones with respect to specific mangrove use and could be combined with the disturbance regime map to prioritize areas for mangrove restoration.  相似文献