Organic carbon and nutrient fluxes to the coastal zone from the Sepik River outflow     

Kathryn A. Burns  Gregg BrunskillDiane Brinkman  Irena Zagorskis 《Continental Shelf Research》2008

The Sepik River is a major contributor of water, sediment and associated organic loads to the coastal waters of northern New Guinea and the Bismarck Sea. We compare dissolved and particulate organic carbon data from September 1997 during an extremely dry El Nino year with those from 1996, 1999 and 2000 during La Nina wet season discharges. Estimated Sepik River flux of DOC is 3.2×10¹⁰ mol yr⁻¹ and POC is 1.1×10¹¹ mol yr⁻¹. The estimates for total river nutrient fluxes to the sea are 1.1×10¹⁰ mol yr⁻¹ for nitrogen and 4.6×10⁸ mol yr⁻¹ for phosphorus. The Sepik DOC flux is about equal to that combined from all four major rivers that enter the Gulf of Papua on the south coast of PNG. The Sepik inorganic PIC flux is low (1.4×10⁸ mol yr⁻¹) as the river does not drain carbonate soils. With a narrow continental shelf, and strong coastal currents, much of this exported material is available for long distance transport into the coastal Bismarck Sea and beyond.  相似文献   

Assessing climate change impacts on European wind energy from ENSEMBLES high-resolution climate projections     

Isabelle Tobin  Robert Vautard  Irena Balog  François-Marie Bréon  Sonia Jerez  Paolo Michele Ruti  Françoise Thais  Mathieu Vrac  Pascal Yiou 《Climatic change》2015,128(1-2):99-112

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Potentials and constraints of different types of soil moisture observations for flood simulations in headwater catchments     

Axel Bronstert  Benjamin Creutzfeldt  Thomas Graeff  Irena Hajnsek  Maik Heistermann  Sibylle Itzerott  Thomas Jagdhuber  David Kneis  Erika Lück  Dominik Reusser  Erwin Zehe 《Natural Hazards》2012,60(3):879-914

Flood generation in mountainous headwater catchments is governed by rainfall intensities, by the spatial distribution of rainfall and by the state of the catchment prior to the rainfall, e.g. by the spatial pattern of the soil moisture, groundwater conditions and possibly snow. The work presented here explores the limits and potentials of measuring soil moisture with different methods and in different scales and their potential use for flood simulation. These measurements were obtained in 2007 and 2008 within a comprehensive multi-scale experiment in the Weisseritz headwater catchment in the Ore-Mountains, Germany. The following technologies have been applied jointly thermogravimetric method, frequency domain reflectometry (FDR) sensors, spatial time domain reflectometry (STDR) cluster, ground-penetrating radar (GPR), airborne polarimetric synthetic aperture radar (polarimetric SAR) and advanced synthetic aperture radar (ASAR) based on the satellite Envisat. We present exemplary soil measurement results, with spatial scales ranging from point scale, via hillslope and field scale, to the catchment scale. Only the spatial TDR cluster was able to record continuous data. The other methods are limited to the date of over-flights (airplane and satellite) or measurement campaigns on the ground. For possible use in flood simulation, the observation of soil moisture at multiple scales has to be combined with suitable hydrological modelling, using the hydrological model WaSiM-ETH. Therefore, several simulation experiments have been conducted in order to test both the usability of the recorded soil moisture data and the suitability of a distributed hydrological model to make use of this information. The measurement results show that airborne-based and satellite-based systems in particular provide information on the near-surface spatial distribution. However, there are still a variety of limitations, such as the need for parallel ground measurements (Envisat ASAR), uncertainties in polarimetric decomposition techniques (polarimetric SAR), very limited information from remote sensing methods about vegetated surfaces and the non-availability of continuous measurements. The model experiments showed the importance of soil moisture as an initial condition for physically based flood modelling. However, the observed moisture data reflect the surface or near-surface soil moisture only. Hence, only saturated overland flow might be related to these data. Other flood generation processes influenced by catchment wetness in the subsurface such as subsurface storm flow or quick groundwater drainage cannot be assessed by these data. One has to acknowledge that, in spite of innovative measuring techniques on all spatial scales, soil moisture data for entire vegetated catchments are still today not operationally available. Therefore, observations of soil moisture should primarily be used to improve the quality of continuous, distributed hydrological catchment models that simulate the spatial distribution of moisture internally. Thus, when and where soil moisture data are available, they should be compared with their simulated equivalents in order to improve the parameter estimates and possibly the structure of the hydrological model.  相似文献   

Magmatic and tectonic history of Jurassic ophiolites and associated granitoids from the South Apuseni Mountains (Romania)     

Daniela Gallhofer  Albrecht von Quadt  Stefan M. Schmid  Marcel Guillong  Irena Peytcheva  Ioan Seghedi 《Swiss Journal of Geoscience》2017,110(2):699-719

The Jurassic ophiolites in the South Apuseni Mountains represent remnants of the Neotethys Ocean and belong to the East Vardar ophiolites that contain ophiolite fragments as well as granitoids and volcanics with island-arc affinity. New U–Pb zircon ages, and Sr and Nd isotope ratios give insights into their tectono-magmatic history. The ophiolite lithologies show tholeiitic MOR-type affinities, but are occasionally slightly enriched in Th and U, and depleted in Nb, which indicates that they probably formed in a marginal or back-arc basin. These ophiolites are associated with calc-alkaline granitoids and volcanics, which show trace element signatures characteristic for subduction-enrichment (high LILE, low HFSE). Low ⁸⁷Sr/⁸⁶Sr ratios (0.703836–0.704550) and high ¹⁴³Nd/¹⁴⁴Nd ratios (0.512599–0.512616) of the calc-alkaline series overlap with the ratios measured in the ophiolitic rocks (0.703863–0.704303 and 0.512496–0.512673), and hence show no contamination with continental crust. This excludes a collisional to post-collisional origin of the granitoids and is consistent with the previously proposed intra-oceanic island arc setting. The new U–Pb ages of the ophiolite lithologies (158.9–155.9 Ma, Oxfordian to Early Kimmeridgian) and granitoids (158.6–152.9 Ma, latest Oxfordian to Late Kimmeridgian) indicate that the two distinct magmatic series evolved within a narrow time range. It is proposed that the ophiolites and island arc granitoids formed above a long-lived NE-dipping subduction zone. A sudden flip in subduction polarity led to collision between island arc and continental margin, immediately followed by obduction of the ophiolites and granitoids on top of the continental margin of the Dacia Mega-Unit. Since the granitoids lack crustal input, they must have intruded the Apuseni ophiolites before both magmatic sequences were obducted onto the continental margin. The age of the youngest granitoid (~153 Ma, Late Kimmeridgian) yields an estimate for the maximum age of emplacement of the South Apuseni ophiolites and associated granitoids onto the Dacia Mega-Unit.  相似文献   

Plankton of the Baltic estuarine ecosystems with emphasis on Neva Estuary: a review of present knowledge and research perspectives   总被引：6，自引：0，他引：6  

Telesh IV 《Marine pollution bulletin》2004,49(3):206-219

Different levels of eutrophication and pollution in the Baltic coastal waters in general, and in estuaries particularly define variations in the buffering capacity of ecosystems of these important filter zones between rivers and the adjacent Baltic Proper. Phyto- and zooplankton in the estuaries form important components of the pelagic food webs that participate in producing and structuring the matter, energy, and information fluxes in the ecosystems. Due to salinity gradients, estuaries provide a large variety of aquatic habitats for native populations of marine, brackish and fresh water plankton species. Non-indigenous planktonic species that expand their bio-geographical range and invade the Baltic coastal ecosystems also find favourable environments, establish permanent populations there, and impact aboriginal ecosystems. The dynamics of abundance, species diversity, population structure, productivity of planktonic communities, and peculiarities of trophic interactions in different Baltic estuaries are influenced by a number of common environmental factors. Being measured on the unified basis and monitored, changes (or stability) of structural and functional parameters of plankton communities can serve as indicators of alterations to the ecosystems. Comparative analyses and quantitative estimates of long-term changes in phyto- and zooplankton can contribute to evaluation of functional response of Baltic coastal ecosystems to anthropogenic stress. Both theoretical (modeling) and empirical studies of interactions within plankton communities aimed at the assessment of the role of planktonic organisms in water quality regulation, and applicability of these data for the evaluation of the status of ecosystems and their management can be considered as major goals for the future investigations in Baltic estuaries.  相似文献   

Sn-polymetallic greisen-type deposits associated with late-stage rapakivi granites, Brazil: fluid inclusion and stable isotope characteristics   总被引：3，自引：0，他引：3  

Jorge S. Bettencourt  Washington B. Leite Jr.  Claudio L. Goraieb  Irena Sparrenberger  Rosa M.S. Bello  Bruno L. Payolla 《Lithos》2005,80(1-4):363-386

Tin-polymetallic greisen-type deposits in the Itu Rapakivi Province and Rondônia Tin Province, Brazil are associated with late-stage rapakivi fluorine-rich peraluminous alkali-feldspar granites. These granites contain topaz and/or muscovite or zinnwaldite and have geochemical characteristics comparable to the low-P sub-type topaz-bearing granites. Stockworks and veins are common in Oriente Novo (Rondônia Tin Province) and Correas (Itu Rapakivi Province) deposits, but in the Santa Bárbara deposit (Rondônia Tin Province) a preserved cupola with associated bed-like greisen is predominant. The contrasting mineralization styles reflect different depths of formation, spatial relationship to tin granites, and different wall rock/fluid proportions. The deposits contain a similar rare-metal suite that includes Sn (±W, ±Ta, ±Nb), and base-metal suite (Zn–Cu–Pb) is present only in Correas deposit. The early fluid inclusions of the Correas and Oriente Novo deposits are (1) low to moderate-salinity (0–19 wt.% NaCl eq.) CO₂-bearing aqueous fluids homogenizing at 245–450 °C, and (2) aqueous solutions with low CO₂, low to moderate salinity (0–14 wt.% NaCl eq.), which homogenize between 100 and 340 °C. In the Santa Bárbara deposit, the early inclusions are represented by (1) low-salinity (5–12 wt.% NaCl eq.) aqueous fluids with variable CO₂ contents, homogenizing at 340 to 390 °C, and (2) low-salinity (0–3 wt.% NaCl eq.) aqueous fluid inclusions, which homogenize at 320–380 °C. Cassiterite, wolframite, columbite–tantalite, scheelite, and sulfide assemblages accompany these fluids. The late fluid in the Oriente Novo and Correas deposit was a low-salinity (0–6 wt.% NaCl eq.) CO₂-free aqueous solution, which homogenizes at (100–260 °C) and characterizes the sulfide–fluorite–sericite association in the Correas deposit. The late fluid in the Santa Bárbara deposit has lower salinity (0–3 wt.% NaCl eq.) and characterizes the late-barren-quartz, muscovite and kaolinite veins. Oxygen isotope thermometry coupled with fluid inclusion data suggest hydrothermal activity at 240–450 °C, and 1.0–2.6 kbar fluid pressure at Correas and Oriente Novo. The hydrogen isotope composition of breccia-greisen, stockwork, and vein fluids (δ¹⁸O_quartz from 9.9‰ to 10.9‰, δD_H2O from 4.13‰ to 6.95‰) is consistent with a fluid that was in equilibrium with granite at temperatures from 450 to 240 °C. In the Santa Bárbara deposit, the inferred temperatures for quartz-pods and bed-like greisens are much higher (570 and 500 °C, respectively), and that for the cassiterite-quartz-veins is 415 °C. The oxygen and hydrogen isotope composition of greisen and quartz-pods fluids (δ¹⁸O_qtz-H2O=5.5–6.1‰) indicate that the fluid equilibrated with the albite granite, consistent with a magmatic origin. The values for mica (δ¹⁸O_mica-H2O=3.3–9.8‰) suggest mixing with meteoric water. Late muscovite veins (δ¹⁸O_qtz-H2O=−6.4‰) and late quartz (δ¹⁸O_mica-H2O=−3.8‰) indicate involvement of a meteoric fluid. Overall, the stable isotope and fluid inclusion data imply three fluid types: (1) an early orthomagmatic fluid, which equilibrated with granite; (2) a mixed orthomagmatic-meteoric fluid; and (3) a late hydrothermal meteoric fluid. The first two were responsible for cassiterite, wolframite, and minor columbite–tantalite precipitation. Change in the redox conditions related to mixing of magmatic and meteoric fluids favored important sulfide mineralization in the Correas deposit.  相似文献   

Geochemistry and mineralogy of bentonites from Ishirini (Libya)     

Irena Kola&#x;íkov  Radek Hanus 《Chemie der Erde / Geochemistry》2008,68(1):61-68

Smectites from the Ishirini bentonite deposit (Libya) were analysed for their oxygen and hydrogen isotopic ratios. Based on published isotopic fractionation data, the results indicate a predominantly meteoric origin of the fluids responsible for the transformation of pyroclastic rocks to bentonite at temperatures ranging from 30 to 90 °C. The thermal effect of the subsequent emplacement of volcanic intrusions was further evaluated by a detailed study of δ¹⁸O isotopic composition of smectites and fluid inclusions in quartz separated from silicified rings produced by the thermal action of a basalt dike. Five different groups of fluids were distinguished based on salinity and homogenization temperatures.

The contact zone of bentonite affected by high concentrated saline solution exhibit mineralogical changes. High salinity and high temperature also remarkably influence the technical parameters of bentonites and reduce, for example, the cation exchange capacity (CEC) or microporosity.  相似文献   

Searching for similarity in topographic controls on carbon,nitrogen and phosphorus export from forested headwater catchments   总被引：1，自引：0，他引：1       下载免费PDF全文

Samson G. Mengistu  Irena F. Creed  Kara L. Webster  Eric Enanga  Frederick D. Beall 《水文研究》2014,28(8):3201-3216

Topography influences hydrological processes that in turn affect biogeochemical export to surface water on forested landscapes. The differences in long‐term average annual dissolved organic carbon (DOC), organic and inorganic nitrogen [NO₃^?‐N, dissolved organic nitrogen (DON)], and phosphorus (total dissolved phosphorus, TDP) export from catchments in the Algoma Highlands of Ontario, Canada, with similar climate, geology, forest and soil were established. Topographic indicators were designed to represent topographically regulated hydrological processes that influence nutrient export, including (1) hydrological storage potential (i.e. effects of topographic flats/depressions on water storage) and (2) hydrological flushing potential (i.e. effects of topographic slopes on potential for variable source area to expand and tap into previously untapped areas). Variations in NO₃^?‐N export among catchments could be explained by indicators representing both hydrological flushing potential (91%, p < 0.001) and hydrological storage potential (65%, p < 0.001), suggesting the importance of hydrological flushing in regulating NO₃^?‐N export as well as surface saturated areas in intercepting NO₃^?‐N‐loaded runoff. In contrast, hydrological storage potential explained the majority of variations among catchments in DON (69%, p < 0.001), DOC (94%, p < 0.001) and TDP (82%, p < 0.001) export. The lower explanatory power of DON (about 15% less) compared with that of DOC and TDP suggests another mechanism influencing N export, such as controls related to alternative fates of nitrogen (e.g. as gas). This study shows that simple topographic indicators can be used to track nutrient sources, sinks and their transport and export to surface water from catchments on forest landscapes. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Biodegradation and migrational fractionation of oils from the Eastern Carpathians, Poland   总被引：1，自引：0，他引：1  

Irena Matyasik  Anna Steczko  R. Paul Philp 《Organic Geochemistry》2000,31(12)

Nineteen oil samples from Silesian Unit of the eastern Carpathian Overthrust have been characterised geochemically in order to determine the causes of compositional differences among them and elucidating the processes responsible for their differences. Some of analysed crude oils have undergone post-emplacement alteration in the reservoir such as biodegradation and evaporative fractionation. This explains much of the chemical and physical properties variability across individual fields from one tectonic unit. Geochemical correlation based on biomarker distributions showed a close relationship between all oils (included biodegraded oils). However, data based on the whole oil GC analysis of selected oils suggest that the process of evaporative fractionation may change the composition of lower molecular weight hydrocarbons of the oils in this region. This paper outlines the probable mechanisms for oil mixing in the region and describes how this can lead to observable lateral differences in the composition of oils.  相似文献   

Constant denudation rates in a high alpine catchment for the last 6 kyrs          下载免费PDF全文

R. Grischott  F. Kober  M. Lupker  K. Hippe  S. Ivy‐Ochs  I. Hajdas  B. Salcher  M. Christl 《地球表面变化过程与地形》2017,42(7):1065-1077

Terrestrial cosmogenic nuclides (TCN) have widely been used as proxies in determining denudation rates in catchments. Most studies were limited to samples from modern active streams, thus little is known about the magnitude and causes of TCN variability on millennial time scales. In this work we present a 6 kyrs long, high resolution record of ¹⁰Be concentrations (n = 18), which were measured in sediment cores from an alluvial fan delta at the outlet of the Fedoz Valley in the Swiss Alps. This record is paired with a 3‐year time series (n = 4) of ¹⁰Be measured in sediment from the active stream currently feeding this fan delta. The temporal trend in the ¹⁰Be concentrations after correction for postdepositional production of ¹⁰Be was found to be overall constant and in good agreement with the modern river ¹⁰Be concentration. The calculated mean catchment‐wide denudation rate amounts to 0.73 ± 0.18 mm yr^?1. This fairly constant level of ¹⁰Be concentrations can be caused by a constant denudation rate over time within the catchment or alternatively by a buffered signal. In this contribution we suggest that the large alluvial floodplain in the Fedoz Valley may act as an efficient buffer on Holocene time scales in which sediments with different ¹⁰Be signatures are mixed. Therefore, presumable variations in the ¹⁰Be signals derived from changes in denudation under a fluctuating Holocene climate are only poorly transferred to the catchment outlet and not recorded in the ¹⁰Be record. However, despite the absence of high frequency signals, we propose that the buffered and averaged ¹⁰Be signal could be meaningfully and faithfully interpreted in terms of long‐term catchment‐averaged denudation rate. Our study suggests that alluvial buffers play an important role in regulating the ¹⁰Be signal exported by some alpine settings that needs to be taken into account and further investigated. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献