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961.
A magnetic polarity pattern for Boreal and Sub-Boreal ammonite zones of the Upper Oxfordian to Lower Kimmeridgian was established and confirmed in four British sections, including the proposed Global Boundary Stratotype Section and Point (GSSP) on the Isle of Skye (Scotland) to define the base of the international Kimmeridgian Stage. A coeval pattern for Sub-Mediterranean ammonite zones was compiled from seven sections in Poland, one German section and multi-section composites from France and Spain. The mean paleopole for the European Craton (excluding Spain) at the Oxfordian–Kimmeridgian boundary is 74.2°N, 181.3°E (Α95 = 3.8°). The common magnetic polarity scale enables inter-correlation of ammonite subzones among these three faunal provinces and to the marine magnetic-anomaly M-Sequence. The proposed GSSP at the base of the Pictonia baylei Zone is near the base of an extended interval dominated by reversed polarity, which is interpreted to be Chron M26r. This GSSP level projects to the lower to middle part of the Epipeltoceras bimammatum Subzone, which is the middle subzone of this E. bimammatum Zone in the Sub-Mediterranean standard zonation. In contrast, the traditional placement of the Oxfordian–Kimmeridgian boundary in that Sub-Mediterranean standard zonation (base of Sutneria platynota Zone) is at the base of Chron M25r, or nearly 1 million years younger.  相似文献   
962.
Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- 14C-MTBE and U-14C-TBA to 14CO2 and the novel biodegradation of U- 14C-TAME to 14CO2 under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.  相似文献   
963.
Antifouling paint fragments collected from marinas and leisure boat maintenance facilities and in the vicinity of abandoned boats have been chemically characterised. High concentrations of Cu (23-380 mg g−1) and Zn (14-160 mg g−1) in the samples (= 14) are consistent with the use of these metals in the principal biocidal and non-biocidal pigments in contemporary antifouling formulations. Up to about 2% and 7% of the respective metals were solvent-extractable, suggesting that organo-forms of Cu and Zn (e.g. pyrithiones) were also present. Of the organic biocides, dichlofluanid was present in most samples and at concentrations up to about 20 mg g−1. Chlorothalonil and Irgarol 1051® were only detected in one and four cases, respectively, and Sea Nine 211® was not detected in any sample. Results are discussed in terms of UK legislation regarding biocide usage and the likely effects and fate of discarded paint particles in coastal environments where boats are repaired or moored.  相似文献   
964.
We employ a computationally efficient fault system earthquake simulator, RSQSim, to explore effects of earthquake nucleation and fault system geometry on earthquake occurrence. The simulations incorporate rate- and state-dependent friction, high-resolution representations of fault systems, and quasi-dynamic rupture propagation. Faults are represented as continuous planar surfaces, surfaces with a random fractal roughness, and discontinuous fractally segmented faults. Simulated earthquake catalogs have up to 106 earthquakes that span a magnitude range from ~M4.5 to M8. The seismicity has strong temporal and spatial clustering in the form of foreshocks and aftershocks and occasional large-earthquake pairs. Fault system geometry plays the primary role in establishing the characteristics of stress evolution that control earthquake recurrence statistics. Empirical density distributions of earthquake recurrence times at a specific point on a fault depend strongly on magnitude and take a variety of complex forms that change with position within the fault system. Because fault system geometry is an observable that greatly impacts recurrence statistics, we propose using fault system earthquake simulators to define the empirical probability density distributions for use in regional assessments of earthquake probabilities.  相似文献   
965.
In this paper, we present a model for studying aftershock sequences that integrates Coulomb static stress change analysis, seismicity equations based on rate-state friction nucleation of earthquakes, slip of geometrically complex faults, and fractal-like, spatially heterogeneous models of crustal stress. In addition to modeling instantaneous aftershock seismicity rate patterns with initial clustering on the Coulomb stress increase areas and an approximately 1/t diffusion back to the pre-mainshock background seismicity, the simulations capture previously unmodeled effects. These include production of a significant number of aftershocks in the traditional Coulomb stress shadow zones and temporal changes in aftershock focal mechanism statistics. The occurrence of aftershock stress shadow zones arises from two sources. The first source is spatially heterogeneous initial crustal stress, and the second is slip on geometrically rough faults, which produces localized positive Coulomb stress changes within the traditional stress shadow zones. Temporal changes in simulated aftershock focal mechanisms result in inferred stress rotations that greatly exceed the true stress rotations due to the main shock, even for a moderately strong crust (mean stress 50 MPa) when stress is spatially heterogeneous. This arises from biased sampling of the crustal stress by the synthetic aftershocks due to the non-linear dependence of seismicity rates on stress changes. The model indicates that one cannot use focal mechanism inversion rotations to conclusively demonstrate low crustal strength (≤10 MPa); therefore, studies of crustal strength following a stress perturbation may significantly underestimate the mean crustal stress state for regions with spatially heterogeneous stress.  相似文献   
966.
967.
This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
968.
We present thermal measurements made by high spatial resolution ground-based (a hand-held thermal camera) and low spatial resolution space-based (MODIS) instruments for a lava flow field active during the last phase of the May–July 2003 eruption at Piton de la Fournaise (La Réunion). Multiple oblique ground-based thermal images were merged to provide full coverage of the flow-field. These were then corrected for path length attenuation and orthorectified, allowing the at-surface radiance emitted by the flow-field to be estimated. Comparison with the radiance recorded by the MODIS sensors during the eruption reveals that, for clear-sky conditions and moderate-to-low viewing angles (satellite zenith <40°), the satellite measurements represent ∼90% of the at-surface radiance, and thus represent valuable data for quantifying volcanic thermal anomalies. Nevertheless, extreme viewing geometries and the presence of clouds strongly affect the radiance reaching the sensor and affected data from 94% of the overpasses. Ground-based thermal data were used to investigate an empirical relationship between the radiant heat flux and lava discharge rate during the emplacement of pahoehoe flows. While the average radiation temperature for flow surface that were 6–24 h old ranged between 500 K and 625 K, the ratio between radiative heat flux and Time-Averaged lava Discharge Rate (TADR) ranged between 1.5 × 108 J m−3 and 3.5 × 108 J m−3. This relationship was used to estimate TADR values from optimal MODIS data and produced results in line with those obtained from GPS surveys (Coppola et al. 2005). Our results underscore the importance of ground-based thermal analysis for the interpretation of satellite measurements, particularly in terms of calculating discharge rate trends.  相似文献   
969.
The Pajarito fault forms the western margin of the Rio Grande rift in north-central New Mexico, and lies adjacent to Los Alamos National Laboratory, a major Federal research facility. Vertical displacement on this normal fault over the past 1.2 Ma has created a 50- to 120-m-high fault scarp on Bandelier Tuff (1.2 Ma), yielding a long-term average slip rate of ca. 0.1 mm/yr. In support of a Laboratory-wide seismic hazards assessment, we excavated 14 trenches in the Pajarito fault zone to determine the age of the most recent displacement event, the recurrence interval between events, the displacement per event, and the variability in slip rate and recurrence through time. The large number of trenches was required by the large height of the fault scarp and the complexity of the fault zone. Only about half the trenches contained significant thicknesses of Holocene deposits, but in those trenches there was clear evidence for an early-to-mid-Holocene displacement event. The previous event was at least 20–40 ka, and the average recurrence interval over the past ca. 300 ka was about 20–40 kyr. We infer that much of the structural relief across this fault developed soon after eruption of the Bandelier Tuff between 1.0 and 1.2 Ma, and that slip rate slowed considerably after that time.  相似文献   
970.
Satellite gravity measurements from the Gravity Recovery and Climate Experiment (GRACE) provide quantitative measurement of terrestrial water storage (TWS) changes with unprecedented accuracy. Combining GRACE-observed TWS changes and independent estimates of water change in soil and snow and surface reservoirs offers a means for estimating groundwater storage change. Since its launch in March 2002, GRACE time-variable gravity data have been successfully used to quantify long-term groundwater storage changes in different regions over the world, including northwest India, the High Plains Aquifer and the Central Valley in the USA, the North China Plain, Middle East, and southern Murray–Darling Basin in Australia, where groundwater storage has been significantly depleted in recent years (or decades). It is difficult to rely on in situ groundwater measurements for accurate quantification of large, regional-scale groundwater storage changes, especially at long timescales due to inadequate spatial and temporal coverage of in situ data and uncertainties in storage coefficients. The now nearly 13 years of GRACE gravity data provide a successful and unique complementary tool for monitoring and measuring groundwater changes on a global and regional basis. Despite the successful applications of GRACE in studying global groundwater storage change, there are still some major challenges limiting the application and interpretation of GRACE data. In this paper, we present an overview of GRACE applications in groundwater studies and discuss if and how the main challenges to using GRACE data can be addressed.  相似文献   
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