Bound and mobile soil water isotope ratios are affected by soil texture and mineralogy,whereas extraction method influences their measurement     

Rachel E. Adams  Ayumi Hyodo  Toby SantaMaria  Cynthia L. Wright  Thomas W. Boutton  Jason B. West 《水文研究》2020,34(4):991-1003

Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ²H and δ¹⁸O of soil water isotope ratios.  相似文献   

A new type of article for Terra Nova          下载免费PDF全文

Max Coleman  Jean Braun  Georges Calas  Carlo Doglioni  Klaus Mezger  Jason Phipps Morgan 《地学学报》2015,27(6):399-399

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Using large-scale diagnostic quantities to investigate change in East Coast Lows     

Fei Ji  Jason P. Evans  Daniel Argueso  Lluis Fita  Alejandro Di Luca 《Climate Dynamics》2015,45(9-10):2443-2453

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Temperature and human thermal comfort effects of street trees across three contrasting street canyon environments     

Andrew M. Coutts  Emma C. White  Nigel J. Tapper  Jason Beringer  Stephen J. Livesley 《Theoretical and Applied Climatology》2016,124(1-2):55-68

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Precipitation over urban areas in the western Maritime Continent using a convection-permitting model     

Daniel Argüeso  Alejandro Di Luca  Jason P. Evans 《Climate Dynamics》2016,47(3-4):1143-1159

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Model-dependent spatial skill in pseudoproxy experiments testing climate field reconstruction methods for the Common Era     

Jason E. Smerdon  Sloan Coats  Toby R. Ault 《Climate Dynamics》2016,46(5-6):1921-1942

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Hydrographic Vertical Separation Surfaces (HyVSEPs) for the Tidal Waters of Canada     

Catherine Robin  Shannon Nudds  Phillip MacAulay  André Godin  Bodo De Lange Boom  Jason Bartlett 《Marine Geodesy》2016,39(2):195-222

Since the advent of Global Navigation Satellite Systems, it has been possible to perform hydrographic survey reductions through the ellipsoid, which has the potential to simplify operations and improve bathymetric products. This technique requires a spatially continuous separation surface connecting chart datum (CD) to a geodetic ellipsoid. The Canadian Hydrographic Service (CHS), with support from the Canadian Geodetic Survey, has developed a new suite of such surfaces, termed Hydrographic Vertical Separations Surfaces, or HyVSEPs, for CD and seven tidal levels. They capture the spatial variability of the tidal datum and levels between tide gauges and offshore using semiempirical models coupling observations at tide stations with relative sea-level rise estimates, dynamic ocean model solutions, satellite altimetry, and a geoid model. HyVSEPs are available for all tidal waters of Canada, covering over seven million square kilometers of ocean and more than 200,000 kilometers of shoreline. This document provides an overview of the CHS's modeling approach, tools, methods, and procedures.

The HyVSEP for CD defines the new hydrographic datum for the tidal waters of Canada. HyVSEPs for other tidal levels are fundamental for coastal studies, climate change adaptation and the definition of the Canadian shoreline and offshore boundaries. HyVSEPs for inland waters are not discussed.  相似文献   

Wetland Loss,Juvenile Salmon Foraging Performance,and Density Dependence in Pacific Northwest Estuaries     

Aaron T. David  Charles A. Simenstad  Jeffery R. Cordell  Jason D. Toft  Christopher S. Ellings  Ayesha Gray  Hans B. Berge 《Estuaries and Coasts》2016,39(3):767-780

During the transition of juveniles from fresh water to estuarine and coastal environments, the survival of Pacific salmon (Oncorhynchus spp.) can be strongly size selective and cohort abundance is partly determined at this stage. Because quantity and quality of food influence juvenile salmon growth, high rates of prey and energy acquisition during estuarine residence are important for survival. Human activities may have affected the foraging performance of juvenile salmon in estuaries by reducing the area of wetlands and by altering the abundance of salmon. To improve our understanding of the effects of wetland loss and salmon density on juvenile salmon foraging performance and diet composition in estuaries, we assembled Chinook salmon (Oncorhynchus tshawytscha) diet and density data from nine US Pacific Northwest estuaries across a gradient of wetland loss. We evaluated the influence of wetland loss and density on juvenile Chinook salmon instantaneous ration and energy ration, two measures of foraging performance, and whether the effect of density varied among estuaries with different levels of wetland loss. We also assessed the influence of wetland loss and other explanatory variables on salmon diet composition. There was no evidence of a direct effect of wetland loss on juvenile salmon foraging performance, but wetland loss appeared to mediate the effect of density on salmon foraging performance and alter salmon diet composition. Specifically, density had no effect on foraging performance in the estuaries with less than 50 % wetland loss but had a negative effect on foraging performance in the estuaries with greater than 50 % wetland loss. These results suggest that habitat loss may interact with density to constrain the foraging performance of juvenile Chinook salmon, and ultimately their growth, during a life history stage when survival can be positively correlated with growth and size.  相似文献   

High Precision Sr‐Nd‐Hf‐Pb Isotopic Compositions of USGS Reference Material BCR‐2          下载免费PDF全文

Jason Jweda  Louise Bolge  Cornelia Class  Steven L. Goldstein 《Geostandards and Geoanalytical Research》2016,40(1):101-115

The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were ⁸⁷Sr/⁸⁶Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), ¹⁴³Nd/¹⁴⁴Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and ¹⁷⁶Hf/¹⁷⁷Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were ²⁰⁶Pb/²⁰⁴Pb = 18.8029 ± 10 (2s, 55 ppm), ²⁰⁷Pb/²⁰⁴Pb = 15.6239 ± 8 (2s, 52 ppm), ²⁰⁸Pb/²⁰⁴Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions.  相似文献   

Impacts of hydrous manganese oxide on the retention and lability of dissolved organic matter     

Jason W. Stuckey  Christopher Goodwin  Jian Wang  Louis A. Kaplan  Prian Vidal-Esquivel  Thomas P. BeebeJr.  Donald L. Sparks 《Geochemical transactions》2018,19(1):6

Minerals constitute a primary ecosystem control on organic C decomposition in soils, and therefore on greenhouse gas fluxes to the atmosphere. Secondary minerals, in particular, Fe and Al (oxyhydr)oxides—collectively referred to as “oxides” hereafter—are prominent protectors of organic C against microbial decomposition through sorption and complexation reactions. However, the impacts of Mn oxides on organic C retention and lability in soils are poorly understood. Here we show that hydrous Mn oxide (HMO), a poorly crystalline δ-MnO₂, has a greater maximum sorption capacity for dissolved organic matter (DOM) derived from a deciduous forest composite O_i, O_e, and O_a horizon leachate (“O horizon leachate” hereafter) than does goethite under acidic (pH 5) conditions. Nonetheless, goethite has a stronger sorption capacity for DOM at low initial C:(Mn or Fe) molar ratios compared to HMO, probably due to ligand exchange with carboxylate groups as revealed by attenuated total reflectance-Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy and scanning transmission X-ray microscopy–near-edge X-ray absorption fine structure spectroscopy coupled with Mn mass balance calculations reveal that DOM sorption onto HMO induces partial Mn reductive dissolution and Mn reduction of the residual HMO. X-ray photoelectron spectroscopy further shows increasing Mn(II) concentrations are correlated with increasing oxidized C (C=O) content (r = 0.78, P < 0.0006) on the DOM–HMO complexes. We posit that DOM is the more probable reductant of HMO, as Mn(II)-induced HMO dissolution does not alter the Mn speciation of the residual HMO at pH 5. At a lower C loading (2 × 10² μg C m^?2), DOM desorption—assessed by 0.1 M NaH₂PO₄ extraction—is lower for HMO than for goethite, whereas the extent of desorption is the same at a higher C loading (4 × 10² μg C m^?2). No significant differences are observed in the impacts of HMO and goethite on the biodegradability of the DOM remaining in solution after DOM sorption reaches steady state. Overall, HMO shows a relatively strong capacity to sorb DOM and resist phosphate-induced desorption, but DOM–HMO complexes may be more vulnerable to reductive dissolution than DOM–goethite complexes.  相似文献