The kinetics of iodide oxidation by the manganese oxide mineral birnessite     

Patricia M. Fox  James A. Davis 《Geochimica et cosmochimica acta》2009,73(10):2850-11620

The kinetics of iodide (I⁻) and molecular iodine (I₂) oxidation by the manganese oxide mineral birnessite (δ-MnO₂) was investigated over the pH range 4.5-6.25. I⁻ oxidation to iodate proceeded as a two-step reaction through an I₂ intermediate. The rate of the reaction varied with both pH and birnessite concentration, with faster oxidation occurring at lower pH and higher birnessite concentration. The disappearance of I⁻ from solution was first order with respect to I⁻ concentration, pH, and birnessite concentration, such that −d[I⁻]/dt = k[I⁻][H⁺][MnO₂], where k, the third order rate constant, is equal to 1.08 ± 0.06 × 10⁷ M⁻² h⁻¹. The data are consistent with the formation of an inner sphere I⁻ surface complex as the first step of the reaction, and the adsorption of I⁻ exhibited significant pH dependence. Both I₂, and to a lesser extent, sorbed to birnessite. The results indicate that iodine transport in mildly acidic groundwater systems may not be conservative. Because of the higher adsorption of the oxidized I species I₂ and , as well as the biophilic nature of I₂, redox transformations of iodine must be taken into account when predicting I transport in aquifers and watersheds.  相似文献   

Assessing the hydrological and geomorphic behaviour of a landscape evolution model within a limits-of-acceptability uncertainty analysis framework     

Jefferson S. Wong  Jim E. Freer  Paul D. Bates  Jeff Warburton  Tom J. Coulthard 《地球表面变化过程与地形》2021,46(10):1981-2003

Landscape evolution models (LEMs) have the capability to characterize key aspects of geomorphological and hydrological processes. However, their usefulness is hindered by model equifinality and paucity of available calibration data. Estimating uncertainty in the parameter space and resultant model predictions is rarely achieved as this is computationally intensive and the uncertainties inherent in the observed data are large. Therefore, a limits-of-acceptability (LoA) uncertainty analysis approach was adopted in this study to assess the value of uncertain hydrological and geomorphic data. These were used to constrain simulations of catchment responses and to explore the parameter uncertainty in model predictions. We applied this approach to the River Derwent and Cocker catchments in the UK using a LEM CAESAR-Lisflood. Results show that the model was generally able to produce behavioural simulations within the uncertainty limits of the streamflow. Reliability metrics ranged from 24.4% to 41.2% and captured the high-magnitude low-frequency sediment events. Since different sets of behavioural simulations were found across different parts of the catchment, evaluating LEM performance, in quantifying and assessing both at-a-point behaviour and spatial catchment response, remains a challenge. Our results show that evaluating LEMs within uncertainty analyses framework while taking into account the varying quality of different observations constrains behavioural simulations and parameter distributions and is a step towards a full-ensemble uncertainty evaluation of such models. We believe that this approach will have benefits for reflecting uncertainties in flooding events where channel morphological changes are occurring and various diverse (and yet often sparse) data have been collected over such events.  相似文献   

Women advancing research on hydrological processes: Preface     

Doerthe Tetzlaff  Elizabeth Boyer  Tanya Doody  Anne Jefferson  Annalisa Molini 《水文研究》2021,35(7):e14267

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Burial and exhumation of the Hoh Xil Basin,northern Tibetan Plateau: Constraints from detrital (U-Th)/He ages     

Jin-Gen Dai  Matthew Fox  David L. Shuster  Jeremy Hourigan  Xu Han  Ya-Lin Li  Cheng-Shan Wang 《Basin Research》2020,32(5):894-915

The uplift and associated exhumation of the Tibetan Plateau has been widely considered a key control of Cenozoic global cooling. The south-central parts of this plateau experienced rapid exhumation during the Cretaceous–Palaeocene periods. When and how the northern part was exhumed, however, remains controversial. The Hoh Xil Basin (HXB) is the largest late Cretaceous–Cenozoic sedimentary basin in the northern part, and it preserves the archives of the exhumation history. We present detrital apatite and zircon (U-Th)/He data from late Cretaceous–Cenozoic sedimentary rocks of the western and eastern HXB. These data, combined with regional geological constraints and interpreted with inverse and forward model of sediment deposition and burial reheating, suggest that the occurrence of ca. 4–2.7 km and ca. 4–2.3 km of vertical exhumation initiated at ca. 30–25 Ma and 40–35 Ma in the eastern and western HXB respectively. The initial differential exhumation of the eastern HXB and the western HXB might be controlled by the oblique subduction of the Qaidam block beneath the HXB. The initial exhumation timing in the northern Tibetan Plateau is younger than that in the south-central parts. This reveals an episodic exhumation of the Tibetan Plateau compared to models of synchronous Miocene exhumation of the entire plateau and the early Eocene exhumation of the northern Tibetan Plateau shortly after the India–Asia collision. One possible mechanism to account for outward growth is crustal shortening. A simple model of uplift and exhumation would predict a maximum of 0.8 km of surface uplift after upper crustal shortening during 30–27 Ma, which is insufficient to explain the high elevations currently observed. One way to increase elevation without changing exhumation rates and to decouple uplift from upper crustal shortening is through the combined effects of continental subduction, mantle lithosphere removal and magmatic inflation.  相似文献   

Stormwater control impacts on runoff volume and peak flow: A meta-analysis of watershed modelling studies     

Colin D. Bell  Jordyn M. Wolfand  Chelsea L. Panos  Aditi S. Bhaskar  Ryan L. Gilliom  Terri S. Hogue  Kristina G. Hopkins  Anne J. Jefferson 《水文研究》2020,34(14):3134-3152

Decades of research has concluded that the percent of impervious surface cover in a watershed is strongly linked to negative impacts on urban stream health. Recently, there has been a push by municipalities to offset these effects by installing structural stormwater control measures (SCMs), which are landscape features designed to retain and reduce runoff to mitigate the effects of urbanisation on event hydrology. The goal of this study is to build generalisable relationships between the level of SCM implementation in urban watersheds and resulting changes to hydrology. A literature review of 185 peer-reviewed studies of watershed-scale SCM implementation across the globe was used to identify 52 modelling studies suitable for a meta-analysis to build statistical relationships between SCM implementation and hydrologic change. Hydrologic change is quantified as the percent reduction in storm event runoff volume and peak flow between a watershed with SCMs relative to a (near) identical control watershed without SCMs. Results show that for each additional 1% of SCM-mitigated impervious area in a watershed, there is an additional 0.43% reduction in runoff and a 0.60% reduction in peak flow. Values of SCM implementation required to produce a change in water quantity metrics were identified at varying levels of probability. For example, there is a 90% probability (high confidence) of at least a 1% reduction in peak flow with mitigation of 33% of impervious surfaces. However, as the reduction target increases or mitigated impervious surface decreases, the probability of reaching the reduction target also decreases. These relationships can be used by managers to plan SCM implementation at the watershed scale.  相似文献   

The geology of the Caribbean crust, I: Beata Ridge     

Paul J. Fox  William F. Ruddiman  William B. F. Ryan  Bruce C. Heezen 《Tectonophysics》1970,10(5-6):495-513

Igneous and sedimentary rocks recently dredged and cored from the steep western slope of the Beata Ridge provide important data on the composition, age and details of crustal evolution of the rock-types responsible for recorded compressional wave velocities. The sedimentary rock samples also provide new data concerning the age and depositional environment of overlying sedimentary reflectors.

The deepest (4,100 m) dredge haul contains deeply weathered coarsegrained igneous rocks. Nine other hauls, distributed between 4,000–2,300 m, contain holocrystalline basalts and diabases. The compressional wave velocity of air-dried samples of two holocrystalline basalts and a diabase at atmospheric pressure ranges from 5.0–5.6 km/sec. Sampling in depths less than 2,300 m shows that the crest of the Beata Ridge is capped by Quaternary deposits underlain by consolidated carbonate sediment of at least Middle Eocene age. The faunal assemblages of the Mid-Eocene samples are the product of normal accumulation in a shallow shelf environment.

The dredging results coupled with previously published seismic reflection and refraction data, suggest that the 5.4–5.7 km/sec crust is composed of a layer of basalt and diabase which outcrops below 2,300 m, on a fault-generated escarpment that was produced in the Late Cretaceous-Early Tertiary. The shallow shelf samples of Eocene age indicate that the Beata Ridge was higher in the Early Tertiary and has subsided subsequently to its present depth.  相似文献   

Advantages to Geoscience and Disaster Response from QuakeSim Implementation of Interferometric Radar Maps in a GIS Database System     

Jay Parker  Andrea Donnellan  Margaret Glasscoe  Geoffrey Fox  Jun Wang  Marlon Pierce  Yu Ma 《Pure and Applied Geophysics》2015,172(8):2295-2304

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Mineral Potential Modelling for the Greater Nahanni Ecosystem Using GIS Based Analytical Methods     

J. R. Harris  D. Lemkow  C. Jefferson  D. Wright  H. Falck 《Natural Resources Research》2008,17(2):51-78

Mineral potential within the Greater Nahanni Ecosystem (GNE) was modelled in a Geographic Information System (GIS) for four different deposit types: (1) SEDEX (stratiform shale-hosted sedimentary exhalative Zn–Pb–Ag), (2) ‘Carbonate-Fault’ (carbonate-hosted zinc–lead–silver associated with major faults), (3) ‘Intrusion-Related’ (includes skarn, rare metals and gemstones) and (4) Carlin-Type gold as lode and/or derived placer deposits. This mineral potential modelling study integrates data collected during the Nahanni Mineral and Energy Resource Assessment (MERA) undertaken from 2003 to 2007. The results have contributed to the process of determining the geographic boundaries of the proposed expansion of the Nahanni National Park Reserve. Four mineral potential maps were produced (one for each deposit type) using a knowledge-driven approach. A weighting scheme based on integrated mineral deposit and regional geological knowledge was derived for the various evidence maps for each deposit model using expert opinion. The four potential maps were then combined into a final potential map using a maximum operator. Plots showing the efficiency of the models (mineral potential maps) for predicting the known occurrences of the four deposit types show that partial data sets provide reasonable predictions of the remaining known mineral prospects, occurrences and deposits. Hydrocarbon potential from Nahanni MERA 1 was added to the final potential map to ensure that both mineral and energy potential data were incorporated into the park configuration modelling.  相似文献   

Seismic hazard disaggregation in performance‐based earthquake engineering: occurrence or exceedance?          下载免费PDF全文

Matthew J. Fox  Peter J. Stafford  Timothy J. Sullivan 《地震工程与结构动力学》2016,45(5):835-842

Seismic hazard disaggregation is commonly used as an aid in ground‐motion selection for the seismic response analysis of structures. This short communication investigates two different approaches to disaggregation related to the exceedance and occurrence of a particular intensity. The impact the different approaches might have on a subsequent structural analysis at a given intensity is explored through the calculation of conditional spectra. It is found that the exceedance approach results in conditional spectra that will be conservative when used as targets for ground‐motion selection. It is however argued that the use of the occurrence disaggregation is more consistent with the objectives of seismic response analyses in the context of performance‐based earthquake engineering. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Developing service-oriented applications in a grid environment     

Jose Garcia  Peter Fox  Patrick West  Stephan Zednik 《Earth Science Informatics》2009,2(1-2):133-139

The Open-source Project for a Network Data Access Protocol (OPeNDAP) software framework has evolved over the last 10 years to become a robust, high performance, service oriented architecture for the access and transport of scientific data from a broad variety of disciplines, over the Internet. Starting with version 4.0 of the server release, Hyrax, has at its core, the Back-End Server (BES). The BES offers ease of programming, extensibility and reliability allowing added functionality especially related to high-performance data Grids, that goes beyond its original goal of distributed data access. We present the fundamentals of the BES server as a component based architecture, as well as our experiences using the BES to distribute data processing in Grid-oriented intensive parallel computational tasks.  相似文献