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561.
The neighboring coastal plain estuaries of the Elbe and Weser Rivers in Northern Germany exhibit pronounced estuarine turbidity maxima (ETM). Common features and differences between the longitudinal distributions of salinity and suspended particulate matter (SPM) in both estuaries are compared as well as the mechanisms effecting them. Monthly transects of the near surface SPM indicate that the long-term variability of salinity and the ETM is mainly influenced by the freshwater runoff. The variability is reduced to certain characteristic patterns by application of Empirical Orthogonal Functions analysis. The coefficients of these patterns are then correlated to runoff and the resulting functional regressions are used for the construction of a statistical model for the distribution of salinity and SPM along the estuaries; for SPM this has not been successful.  相似文献   
562.
A numerical experiment has been conducted on the OH-initiated tropospheric oxidation of DMS. This involved the selection of a set of reactions describing the OH-initiated oxidation kinetics and the conversion of the present level of uncertainty of the system into uncertainty ranges and distributions for the relevant system parameters (kinetic constants and initial concentrations). Uncertainties have been propagated through the model onto the output variables of interest. This has allowed (a) the uncertainty in model prediction to be quantified and compared with observations (uncertainty analysis) and (b) the relative importance of each input parameter in determining the output uncertainty to be quantified (sensitivity analysis). Output considered were the ratio of MSA/(SO2 + H2SO4) concentration at a given time, the ratio SO2/H2SO4, the total peroxynitrate species concentrations and the relative fraction of SO2 and H2SO4 formed through the various pathways. Conditional upon the model and data assumptions underlying the experiment, the following main conclusions were drawn:
  1. The possibility of direct formation of SO3 without SO2 as intermediate as suggested by Bandyet al. (1992) and Yinet al. (1990), involving direct thermal decomposition of CH3SO3 · does not seem to play a major role in the overall generation of sulphate. This is relevant to the issue of gas to particle conversion over remote areas.
  2. Reaction of CH3SOO · intermediate may be the most important pathway to the formation of SO2.
  3. The dominating peroxynitrate is CH3S(O)2O2NO2.
Through sensitivity analysis the kinetic constants have been identified which — because of their uncertainty and of their impact on the output — mostly contribute to the output uncertainty.  相似文献   
563.
Brief overviews of the Arctic’s atmosphere, ice cover, circulation, primary production and sediment regime are given to provide a conceptual framework for considering panarctic shelves under scenarios of climate variability. We draw on past ‘regional’ studies to scale-up to the panarctic perspective. Within each discipline a synthesis of salient distributions and processes is given, and then functions are noted that are critically poised and/or near transition and thereby sensitive to climate variability and change. The various shelf regions are described and distinguished among three types: inflow shelves, interior shelves and outflow shelves. Emphasis is on projected climate changes that will likely have the greatest impact on shelf-basin exchange, productivity and sediment processes including (a) changes in wind fields (e.g. currents, ice drift, upwelling and downwelling); (b) changes in sea ice distribution (e.g. radiation and wind regimes, enhanced upwelling and mixing, ice transport and scour resuspension, primary production); and (c) changes in hydrology (e.g. sediment and organic carbon delivery, nutrient supplies). A discussion is given of the key rate-controlling processes, which differ for different properties and shelf types, as do the likely responses; that is, the distributions of nutrients, organic carbon, freshwater, sediments, and trace minerals will all respond differently to climate forcing.A fundamental conclusion is that the changes associated with light, nutrients, productivity and ice cover likely will be greatest at the shelf-break and margins, and that this forms a natural focus for a coordinated international effort. Recognizing that the real value of climate research is to prepare society for possible futures, and that such research must be based both on an understanding of the past (e.g. the palaeo-record) as well as an ability to reliably predict future scenarios (e.g. validated models), two recommendations emerge: firstly, a comprehensive survey of circumpolar shelf-break and slope sediments would provide long-term synchronous records of shelf-interior ocean exchange and primary production at the shelf edge; secondly, a synoptic panarctic ice and ocean survey using heavy icebreakers, aircraft, moorings and satellites would provide the validation data and knowledge required to properly model key forcing processes at the margins.  相似文献   
564.
565.
Current estimates of freshwater flux through Arctic and subarctic seas   总被引:2,自引:0,他引:2  
As the world warms, the expectation is that the freshwater outflows from the Arctic Ocean to the North Atlantic will strengthen and may act to suppress the rate of the climatically-important Atlantic meridional overturning circulation. Hitherto, however, we have lacked the system of measurements required to estimate the totality of the freshwater flux through subarctic seas. Though observations remain patchy and rudimentary in places, we piece-together the results from recent large-scale observational programmes together with associated modelling, to establish preliminary maps of the rates and pathways of freshwater flux through subarctic seas. These fluxes are calculated according to two reference salinities, S = 34.8 to conform with the majority of estimates reported in the literature, and S = 35.2, the salinity of the inflowing Atlantic water, to calculate the freshwater balance of the ‘Arctic Mediterranean’. We find that 148 mSv of freshwater enters the Nordic Seas across its northern boundary. There it is supplemented by around 54 mSv of freshwater from Baltic runoff, Norwegian runoff, P − E and Greenland ice melt, so that the total freshwater contribution to the Nordic Seas from all sources is 202 mSv. Of this, around 51 mSv of freshwater is estimated to pass south to the deep Atlantic in the dense water overflows leaving an assumed balance of 151 mSv to leave the Nordic Seas in the upper water export through Denmark Strait. The corresponding estimate for the freshwater outflow west of Greenland is 103 mSv relative to 35.2 so that the total freshwater flux reaching the North Atlantic through subarctic seas is around 300 mSv.  相似文献   
566.
567.
568.
Natural evidence for rapid abiogenic hydrothermal generation of CH4   总被引:1,自引:0,他引:1  
Although recent hydrothermal experiments imply that abiogenic methane (CH4) generation from hydrothermal reduction of CO2 can occur, evidence from natural systems was still lacking. Based on the chemical and isotopic equilibrium signatures of low-temperature fumarolic gas discharges, we are able to provide hard evidence for its natural occurrence, namely in three subduction-related bi-phase hydrothermal systems of the Mediterranean, whose temperatures range from 260 to 470 °C. The attainment of equilibrium and the time spans of recent volcanic dormancy allowed us to calculate minimum rates for chemical and isotopic equilibration. These are significantly higher than those previously reported and might be due to the presence of a saturated water vapor phase in the investigated systems. The fact that nature provides conditions enabling relatively fast production of hydrocarbons from CO2 strongly supports the concerns that were recently raised from laboratory experiments. These address the use of the carbon isotope composition of reduced carbon in Archean sediments as a tracer of early life and the occurrence of CH4 on extraterrestrial planets as a bioindicator. In view of the potential role of abiogenic CH4 as a precursor of life, we also present an estimate of abiogenic hydrothermal CH4 fluxes throughout the Archean. It is not expected that these fluxes exceeded 80 Mt/yr during the past 4.0 Ga. This, however, would have been enough to facilitate HCN production on the prebiotic Earth.  相似文献   
569.
We present a unique, versatile piston corer for recovering continuous lake and bog sediment sequences with superior accuracy and quality. The main components of the system and their function are described, with special focus on measures for obtaining long, continuous lake sediment sections up to a current maximum length of 95 m. Examples of lake sediment profiles obtained with this system from different climatic zones are presented.  相似文献   
570.
Geophysical and hydrogeological investigations have been carried out around Sawmills in Zimbabwe, Africa. The investigations are components of a larger investigation to assess the groundwater potential of the Karoo sedimentary basin with regards to supplying water to Bulawayo City. The Sawmills area was selected due to the availability of borehole logs indicating favourable stratigraphy for groundwater availability and due to the high yields from the aquifers measured from these boreholes. Data collected using two geophysical methods are presented here: transient electromagnetic (TEM) and continuous vertical electrical sounding (CVES) data. The data have also been processed using laterally constrained inversion (LCI). Because the CVES provides greater detail in the shallow subsurface, whereas TEM is more effective at depth, a more accurate image of the entire subsurface profile is provided based on using both methods. The results suggest that LCI of CVES and TEM data, in the subsurface at the required depths at Sawmills, is able to provide a substantially more accurate image of the subsurface than either method alone. The hydrogeological interpretation of the geophysical data is valuable for determining the depth to and thickness of the potential aquifer horizon(s) and for identifying the position of potential recharge zones.  相似文献   
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