PCB-containing paint and plaster caused extreme PCB-concentrations in biota from the Sørfjord (Western Norway)--a case study     

Ruus A  Green NW  Maage A  Skei J 《Marine pollution bulletin》2006,52(1):100-103

The Sørfjord (Western Norway) has a long history of industry and pollution, and has been monitored for several decades. The environmental monitoring has comprised analyses of different contaminants in sea water, mussel, fish, seaweed and sediments. Measurements of polychlorinated biphenyls (PCBs) in blue mussels (Mytilus edulis) some 17 years ago indicated a local source. In 2001 severe concentrations were measured in blue mussels and further investigations disclosed the primary source of PCBs in the Sørfjord. In 2002, extreme PCB-concentrations were found in cod (Gadus morhua) from the same area. However, no induction of EROD activity was detected, indicating the limitations of this assay as marker for PCB contamination. A future scientific challenge will be to understand the specific mechanisms and effects of such PCB accumulation in fish.  相似文献   

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea   总被引：2，自引：0，他引：2  

Vuorinen PJ  Keinänen M  Vuontisjärvi H  Barsiene J  Broeg K  Förlin L  Gercken J  Kopecka J  Köhler A  Parkkonen J  Pempkowiak J  Schiedek D 《Marine pollution bulletin》2006,53(8-9):479-487

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.  相似文献   

A late glacial Antarctic climate teleconnection and variable Holocene seasonality at Lake Pupuke, Auckland, New Zealand     

Thomas Stephens  Daniel Atkin  Paul Augustinus  Philip Shane  Andrew Lorrey  Alayne Street-Perrott  Andreas Nilsson  Ian Snowball 《Journal of Paleolimnology》2012,48(4):785-800

We present the first continuous paleolimnological reconstruction from the North Island of New Zealand (37°S) that spans the last 48.2?cal kyr. A tephra- and radiocarbon-based chronology was developed to infer the timing of marked paleolimnological changes in Lake Pupuke, Auckland, New Zealand, identified using sedimentology, magnetic susceptibility, grain size and geochemistry (carbon, nitrogen and sulphur concentrations and fluxes, carbon and nitrogen stable isotopes). Variable erosional influx, biomass and benthic REDOX conditions are linked to changing effective precipitation and seasonality within three inferred broad intervals of climatic change: (1) the Last Glacial Coldest Phase (LGCP) of reduced effective precipitation and cooler temperatures, from 28.8 to 18.0?cal kyr BP, (2) the Last Glacial Interglacial Transition (LGIT) of increasing effective precipitation and warmer conditions, from 18.0 to 10.2?cal?kyr?BP, and (3) a Holocene interval of high effective precipitation, beginning with a warm period of limited seasonality from 10.2?cal?kyr?BP and followed by increasing seasonality from 7.6?cal?kyr?BP. The LGCP and LGIT also contain millennial-scale climate events, including the coldest inferred glacial conditions during the LGCP from 27.8 to 26.0 and 22.0?C19.0?cal?kyr?BP, and a climate reversal in the LGIT associated with lower lake level, from 14.5 to 13.8?cal?kyr?BP, coeval with the Antarctic Cold Reversal. The onset of seasonal thermal stratification occurred at 5.7?cal?kyr?BP and was linked to natural eutrophication of Lake Pupuke, which produced enhanced organic sedimentation.  相似文献   

Can the uncertainty of full carbon accounting of forest ecosystems be made acceptable to policymakers?     

Anatoly Shvidenko  Dmitry Schepaschenko  Ian McCallum  Sten Nilsson 《Climatic change》2010,103(1-2):137-157

In accordance with the concept that only full accounting of major greenhouse gases corresponds to the goals of the United Nations Framework Convention on Climate Change and its Kyoto Protocol, this paper considers uncertainties of regional (national) terrestrial biota Full Carbon Accounting (FCA), both those already achieved and those expected. We analyze uncertainties of major components of the FCA of forest ecosystems of a large boreal region in Siberia (~300 × 10⁶ ha). Some estimates for forests of other regions and Russia as a whole are used for comparison. The systems integration of available information sources and different types of models within the landscape-ecosystem approach are shown to have enabled an estimation of the major carbon fluxes (Net Primary Production, NPP, and heterotrophic respiration, HR) for the region for a single year at the level of 7–12% (confidential interval, CI, 0.9), Net Ecosystem Production (NEP) of 35–40%, and Net Biome Production (NBP) of 60–80%. The most uncertain aspect is the assessment of change in the soil carbon pool, which limits practical application of a pool-based approach. Regionalization of global process-based models, introduction of climatic data in empirical models, use of an appropriate time period for accounting and reporting, harmonization and multiple constraints of estimates obtained by different independent methods decrease the above uncertainties of NEP and NBP by about half. The results of this study support the idea that FCA of forest ecosystems is relevant in the post-Kyoto international negotiation process.  相似文献   

Climate change effects on winter chill for tree crops with chilling requirements on the Arabian Peninsula     

Eike Luedeling  Jens Gebauer  Andreas Buerkert 《Climatic change》2009,96(1-2):219-237

Fruit production systems that rely on winter chill for breaking of dormancy might be vulnerable to climatic change. We investigated decreases in the number of winter chilling hours (0–7.2°C) in four mountain oases of Oman, a marginal area for the production of fruit trees with chilling requirements. Winter chill was calculated from long-term hourly temperature records. These were generated based on the correlation of hourly temperature measurements in the oases with daylength and daily minimum and maximum temperatures recorded at a nearby weather station. Winter chill was estimated for historic temperature records between 1983 and 2008, as well as for three sets of synthetic 100-year weather records, generated to represent historic conditions, and climatic changes likely to occur within the next 30 years (temperatures elevated by 1°C and 2°C). Our analysis detected a decrease in the numbers of chilling hours in high-elevation oases by an average of 1.2–9.5 h/year between 1983 and 2008, a period during which, according to the scenario analysis, winter chill was sufficient for most important species in most years in the highest oasis. In the two climate change scenarios, pomegranates, the most important tree crop, received insufficient chilling in 13% and 75% of years, respectively. While production of most traditional fruit trees is marginal today, with trees barely fulfilling their chilling requirements, such production might become impossible in the near future. Similar developments are likely to affect other fruit production regions around the world.  相似文献   

Radiative lifetimes and transition probabilities in Hf I and Hf III     

G. Malcheva  S. Enzonga Yoca  R. Mayo  M. Ortiz  L. Engström  H. Lundberg  H. Nilsson  É. Biémont  K. Blagoev 《Monthly notices of the Royal Astronomical Society》2009,396(4):2289-2294

Radiative lifetimes of nine odd levels in Hf III (5d6p z³P_0,1, z¹D₂, z³D_1,2,3, z³F_2,3,4) and of two odd levels in Hf I (5d6s²6p z³D_2,3) have been determined using Time-Resolved Laser-Induced Fluorescence. The investigated levels in Hf I were excited in a single-step process from the ground term (5d²6s² a³F), whereas in Hf III we started from either the ground term 5d² a³F or the low-lying 5d6s a³D term. For all of the investigated levels, the lifetimes have been measured for the first time. A multiconfiguration relativistic Hartree–Fock method, including core-polarization effects, has been used to compute radiative lifetimes of 15 Hf III levels, including those measured in this work. Transition probabilities for 55 transitions in Hf III are also given.  相似文献   

Lander radioscience for obtaining the rotation and orientation of Mars     

Veronique Dehant  William Folkner  Etienne Renotte  Daniel Orban  Sami Asmar  Georges Balmino  Jean-Pierre Barriot  Jeremy Benoist  Richard Biancale  Jens Biele  Frank Budnik  Stefaan Burger  Olivier de Viron  Bernd Häusler  Özgur Karatekin  Sébastien Le Maistre  Philippe Lognonné  Michel Menvielle  Michel Mitrovic  Martin Pätzold  Marie Yseboodt 《Planetary and Space Science》2009,57(8-9):1050-1067

The paper presents the concept, the objectives, the approach used, and the expected performances and accuracies of a radioscience experiment based on a radio link between the Earth and the surface of Mars. This experiment involves radioscience equipment installed on a lander at the surface of Mars. The experiment with the generic name lander radioscience (LaRa) consists of an X-band transponder that has been designed to obtain, over at least one Martian year, two-way Doppler measurements from the radio link between the ExoMars lander and the Earth (ExoMars is an ESA mission to Mars due to launch in 2013). These Doppler measurements will be used to obtain Mars’ orientation in space and rotation (precession and nutations, and length-of-day variations). More specifically, the relative position of the lander on the surface of Mars with respect to the Earth ground stations allows reconstructing Mars’ time varying orientation and rotation in space.Precession will be determined with an accuracy better by a factor of 4 (better than the 0.1% level) with respect to the present-day accuracy after only a few months at the Martian surface. This precession determination will, in turn, improve the determination of the moment of inertia of the whole planet (mantle plus core) and the radius of the core: for a specific interior composition or even for a range of possible compositions, the core radius is expected to be determined with a precision decreasing to a few tens of kilometers.A fairly precise measurement of variations in the orientation of Mars’ spin axis will enable, in addition to the determination of the moment of inertia of the core, an even better determination of the size of the core via the core resonance in the nutation amplitudes. When the core is liquid, the free core nutation (FCN) resonance induces a change in the nutation amplitudes, with respect to their values for a solid planet, at the percent level in the large semi-annual prograde nutation amplitude and even more (a few percent, a few tens of percent or more, depending on the FCN period) for the retrograde ter-annual nutation amplitude. The resonance amplification depends on the size, moment of inertia, and flattening of the core. For a large core, the amplification can be very large, ensuring the detection of the FCN, and determination of the core moment of inertia.The measurement of variations in Mars’ rotation also determines variations of the angular momentum due to seasonal mass transfer between the atmosphere and ice caps. Observations even for a short period of 180 days at the surface of Mars will decrease the uncertainty by a factor of two with respect to the present knowledge of these quantities (at the 10% level).The ultimate objectives of the proposed experiment are to obtain information on Mars’ interior and on the sublimation/condensation of CO₂ in Mars’ atmosphere. Improved knowledge of the interior will help us to better understand the formation and evolution of Mars. Improved knowledge of the CO₂ sublimation/condensation cycle will enable better understanding of the circulation and dynamics of Mars’ atmosphere.  相似文献   

Melting and Sublimation of Planetary Ices Under Low Pressure Conditions: Laboratory Experiments with a Melting Probe Prototype     

Erika?Kaufmann  Günter?Kargl  Norbert?I.?K?mleEmail author  Manfred?Steller  Johann?Hasiba  Florian?Tatschl  Stefan?Ulamec  Jens?Biele  Marc?Engelhardt  Jens?Romstedt 《Earth, Moon, and Planets》2009,105(1):11-29

One possibility to explore the subsurface layers of icy bodies is to use a probe with a “hot tip", which is able to penetrate ice layers by melting. Such probes have been built and used in the past for the exploration of terrestrial polar ice sheets and may also become useful tools to explore other icy layers in the Solar System. Examples for such layers are the polar areas of Mars or the icy crust of Jupiter’s moon Europa. However, while on Earth a heated probe launched into an ice sheet always causes melting with subsequent refreezing, the behaviour of such a probe in a low pressure environment is quite different. We report on the results of some experiments with a simple “melting probe" prototype with two different kinds of hot tips in a vacuum environment. For one of the tips the probe moved into two types of ice samples: (i) compact water ice and (ii) porous water ice with a snow (firn) like texture. It was also found that the penetration behaviour was basically different for the two sample types even when the same kind of tip was used. While in the porous sample the ice was only subliming, the phase changes occurring during the interaction of the tip with the compact ice are much more complex. Here alternating phases of melting and sublimation occur. The absence of the liquid phase has severe consequences on the performance of a “melting probe" under vacuum conditions: In this environment we find a high thermal resistance between the probe surface and the underlying ice. Therefore, only a low percentage of the heat that is generated in the tip is used to melt or sublime the ice, the bulk of the power is transferred towards the rear end of the probe. This is particularly a problem in the initial phases of an ice penetration experiment, when the probe has not yet penetrated the ice over its whole length. In the compact ice sample, phases could be observed, where a high enough gas pressure had built up locally underneath the probe, so that melting becomes possible. Only during these melting periods the thermal contact between the probe and the ice is good and in consequence the melting probe works effectively.  相似文献   

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics     

Jürgen Oberst  Valéry Lainey  Christophe Le Poncin-Lafitte  Veronique Dehant  Pascal Rosenblatt  Stephan Ulamec  Jens Biele  J?rn Spurmann  Ralph Kahle  Volker Klein  Ulrich Schreiber  Anja Schlicht  Nicolas Rambaux  Philippe Laurent  Beno?t Noyelles  Bernard Foulon  Alexander Zakharov  Leonid Gurvits  Denis Uchaev  Scott Murchie  Cheryl Reed  Slava G. Turyshev  Jesus Gil  Mariella Graziano  Konrad Willner  Kai Wickhusen  Andreas Pasewaldt  Marita W?hlisch  Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   

Numerical Modeling of Nitrate Removal in Anoxic Groundwater during River Flooding of Riparian Zones     

Jannick Kolbjørn Jensen  Bertel Nilsson  Peter Engesgaard 《Ground water》2021,59(6):866-877

A numerical study demonstrates the effects of flooding on subsurface hydrological flowpaths and nitrate removal in anoxic groundwater in riparian zones with a top peat layer. A series of two-dimensional numerical simulations with changing conditions for flow (steady state or transient with flooding), hydrogeology, denitrification, and duration of flooding demonstrate how flowpaths, residence times, and nitrate removal are affected. In periods with no flooding groundwater flows horizontally and discharges to the river through the riverbed. During periods with flooding, shallow groundwater is forced upwards as discharge through peat layers that often have more optimal conditions for denitrification caused by the presence of highly reactive organic matter. The contrast in hydraulic conductivity between the sand aquifer and the overlying peat layer, as well as the flooding duration, have a significant role in determining the degree of nitrate removal.  相似文献