Water organisation at the solid–aqueous solution interfaceOrganisation de l'eau à l'interface solide–solution aqueuse     

Laurent J. Michot  Frédéric Villiéras  Michèle François  Isabelle Bihannic  Manuel Pelletier  Jean-Maurice Cases 《Comptes Rendus Geoscience》2002,334(9):611-631

The aim of this review is to examine the present knowledge about water structure close to an interface or confined in porous spaces. First, the structure of liquid water is briefly described. Though its understanding remains incomplete, it appears that it is largely dominated by the hydrogen bond network and its dynamical evolution. The presence of any ‘foreign’ substance in water perturbs such a structure by changing at least locally the hydrogen bond network. For this reason, the presence of a solid interface significantly modifies the structure of the first adsorbed layers. Whatever the support, it is now clearly evidenced that structural perturbations are limited to distances lower than 10–15 Å from the interface. The nature, energetic heterogeneity and hydrophilicility/hydrophobicity of the solid surface influence the arrangement of water molecules. This surface organisation must definitely be considered when studying adsorption phenomena at the solid–aqueous solution interface. The relevance of such problems to geosciences is illustrated by a few situations in which water structure plays a prominent role. To cite this article: L.J. Michot et al., C. R. Geoscience 334 (2002) 611–631.  相似文献   

Controls on the aerodynamic roughness length and the grain‐size dependence of aeolian sediment transport          下载免费PDF全文

J.P. Field  J.D. Pelletier 《地球表面变化过程与地形》2018,43(12):2616-2626

Estimates of the wind shear stress exerted on Earth's surface using the fully rough form of the law‐of‐the‐wall are a function of the aerodynamic roughness length, z₀. Accurate prediction of aeolian sediment transport rates, therefore, often requires accurate estimates of z₀. The value of z₀ is determined by the surface roughness and the saltation intensity, both of which can be highly dynamic. Here we report field measurements of z₀ values derived from velocity profiles measured over an evolving topography (i.e. sand ripples). The topography was measured by terrestrial laser scanning and the saltation intensity was measured using a disdrometer. By measuring the topographic evolution and saltation intensity simultaneously and using available formulae to estimate the topographic contribution to z₀, we isolated the contribution of saltation intensity to z₀ and document that this component dominates over the topographic component for all but the lowest shear velocities. Our measurements indicate that the increase in z₀ during periods of saltation is approximately one to two orders of magnitude greater than the increase attributed to microtopography (i.e. evolving sand ripples). Our results also reveal differences in transport as a function of grain size. Each grain‐size fraction exhibited a different dependence on shear velocity, with the saltation intensity of fine particles (diameters ranging from 0.125 to 0.25 mm) saturating and eventually decreasing at high shear velocities, which we interpret to be the result of a limitation in the supply of fine particles from the bed at high shear velocities due to bed armoring. Our findings improve knowledge of the controls on the aerodynamic roughness length and the grain‐size dependence of aeolian sediment transport. The results should contribute to the development of improved sediment transport and dust emission models. © 2018 John Wiley & Sons, Ltd.  相似文献   

Which way do you lean? Using slope aspect variations to understand Critical Zone processes and feedbacks   总被引：1，自引：0，他引：1       下载免费PDF全文

Jon D. Pelletier  Greg A. Barron‐Gafford  Hugo Gutiérrez‐Jurado  Eve‐Lyn S. Hinckley  Erkan Istanbulluoglu  Luke A. McGuire  Guo‐Yue Niu  Michael J. Poulos  Craig Rasmussen  Paul Richardson  Tyson L. Swetnam  Greg E. Tucker 《地球表面变化过程与地形》2018,43(5):1133-1154

Soil‐mantled pole‐facing hillslopes on Earth tend to be steeper, wetter, and have more vegetation cover compared with adjacent equator‐facing hillslopes. These and other slope aspect controls are often the consequence of feedbacks among hydrologic, ecologic, pedogenic, and geomorphic processes triggered by spatial variations in mean annual insolation. In this paper we review the state of knowledge on slope aspect controls of Critical Zone (CZ) processes using the latitudinal and elevational dependence of topographic asymmetry as a motivating observation. At relatively low latitudes and elevations, pole‐facing hillslopes tend to be steeper. At higher latitudes and elevations this pattern reverses. We reproduce this pattern using an empirical model based on parsimonious functions of latitude, an aridity index, mean‐annual temperature, and slope gradient. Using this empirical model and the literature as guides, we present a conceptual model for the slope‐aspect‐driven CZ feedbacks that generate asymmetry in water‐limited and temperature‐limited end‐member cases. In this conceptual model the dominant factor driving slope aspect differences at relatively low latitudes and elevations is the difference in mean‐annual soil moisture. The dominant factor at higher latitudes and elevations is temperature limitation on vegetation growth. In water‐limited cases, we propose that higher mean‐annual soil moisture on pole‐facing hillslopes drives higher soil production rates, higher water storage potential, more vegetation cover, faster dust deposition, and lower erosional efficiency in a positive feedback. At higher latitudes and elevations, pole‐facing hillslopes tend to have less vegetation cover, greater erosional efficiency, and gentler slopes, thus reversing the pattern of asymmetry found at lower latitudes and elevations. Our conceptual model emphasizes the linkages among short‐ and long‐timescale processes and across CZ sub‐disciplines; it also points to opportunities to further understand how CZ processes interact. We also demonstrate the importance of paleoclimatic conditions and non‐climatic factors in influencing slope aspect variations. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Asymmetry of weathering‐limited hillslopes: the importance of diurnal covariation in solar insolation and temperature          下载免费PDF全文

Jon D. Pelletier  Tyson L. Swetnam 《地球表面变化过程与地形》2017,42(9):1408-1418

Hillslope asymmetry, i.e. variation in hillslope form as a function of slope aspect and/or mean solar insolation, has been documented in many climates and geologic contexts. Such patterns have the potential to help us better understand the hydrologic, ecologic, and geomorphologic processes and feedbacks operating on hillslopes. Here we document asymmetry in the fraction of hillslope relief accommodated by cliffs in weathering‐limited hillslopes of drainage basins incised into the East Kaibab Monocline (northern Arizona) and Raplee Ridge Monocline (southern Utah) of the southern Colorado Plateau. We document that south‐ and west‐facing hillslopes have a larger proportion of hillslope relief accommodated by cliffs compared with north‐ and east‐facing hillslopes. Cliff abundance correlates positively with mean solar insolation and, by inference, negatively with soil/rock moisture. Solar insolation control of hillslope asymmetry is an incomplete explanation, however, because it cannot account for the fact that the greatest asymmetry occurs between southwest‐ and northeast‐facing hillslopes rather than between south‐ and north‐facing hillslopes in the study sites. Modeling results suggest that southwest‐facing hillslopes are more cliff‐dominated than southeast‐facing hillslopes of the same mean solar insolation in part because potential evapotranspiration rates, which control the soil/rock moisture that drives weathering, are controlled by the product of solar insolation and a nonlinear function of surface temperature, together with the fact that southwest‐facing hillslopes receive peak solar insolation during warmer times of day compared with southeast‐facing hillslopes. The dependence of water availability on both solar insolation and surface temperature highlights the importance of the diurnal cycle in controlling water availability, and it provides a general explanation for the fact that vegetation cover tends to exhibit the greatest difference between northeast‐ and southwest‐facing hillslopes in the Northern Hemisphere and between southeast‐ and northwest‐facing hillslopes in the Southern Hemisphere. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

A model-based evaluation of Marine Protected Areas: the example of eastern Baltic cod (Gadus morhua callarias L.)     

Kraus  Gerd; Pelletier  Dominique; Dubreuil  Julien; Mollmann  Christian; Hinrichsen  Hans-Harald; Bastardie  Francois; Vermard  Youen; Mahevas  Stephanie 《ICES Journal of Marine Science》2009,66(1):109-121

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Improving resolution and accuracy of mean sea surface from kinematic GPS,Vanuatu subduction zone     

Marie-Noëlle Bouin  Valérie Ballu  Stéphane Calmant  Bernard Pelletier 《Journal of Geodesy》2009,83(11):1017-1030

Satellite altimetry provides an ocean mean sea surface (MSS) map with global coverage and overall excellent precision. However, in some areas, like the Vanuatu archipelago, the coverage and resolution of this tool are not sufficient to correctly map the short scale undulations of the sea surface, due to numerous islands and to strong lithospheric and mantle heterogeneities. New applications such as seafloor geodesy may require local mean surface representation with improved resolution in specific areas. We used sea surface height collected with kinematic GPS during three different cruises in 2004, 2006 and 2007 to reconstruct a homogeneous sea surface map around Santo Island, Vanuatu. We assess the accuracy of this GPS-derived local sea surface to 6–19 cm and evaluate the quality of existing altimetry and gravity-derived MSSs on the Vanuatu archipelago. Observed short scale undulations are interpreted as due to local geodynamics.  相似文献   

Absolute seafloor vertical positioning using combined pressure gauge and kinematic GPS data   总被引：1，自引：0，他引：1  

Valérie Ballu  Marie-Noelle Bouin  Stéphane Calmant  Eric Folcher  Jean-Michel Bore  Jérome Ammann  Olivier Pot  Michel Diament  Bernard Pelletier 《Journal of Geodesy》2010,84(1):65-77

Knowledge of the position and motion of points on the seafloor can be critically important in both fundamental research (for example, global geodesy and plate tectonics) and for more practical applications such as seismic risk evaluation, off-shore construction and pipeline monitoring. In the Vanuatu subduction zone, for example, measuring deformation underwater could provide valuable information for modeling deformation and understanding the seismic cycle. We report a shallow water experiment in Vanuatu to measure the relative and absolute depth of seafloor points. The experiment differs from previous efforts mainly in that it uses the height of the sea surface determined by kinematic GPS, allowing us to locate the points in a global reference frame. The ITRF2005 ellipsoidal height of a seafloor benchmark was determined with a 1-sigma uncertainty of 0.7–2.1 cm. The estimated ellipsoidal height differs only by a few tenths of a centimeter between measurements made in 2004 and another set made in 2006. These results are encouraging and open new perspectives for vertical underwater deformation monitoring in shallow water areas. Sea-surface GPS measurements can also help to reduce the uncertainty in depth difference determination for relative measurements.  相似文献   

Hydrologic evaluation of spatially disaggregated global ensemble rainfall forecasts          下载免费PDF全文

E. Gaborit  F. Anctil  V. Fortin  G. Pelletier 《水文研究》2014,28(17):4682-4693

A statistic–stochastic multi‐fractal downscaling technique was evaluated from a hydrologic point of view. Ensemble hydrologic forecasts with a time step of 3 h were performed for original and disaggregated ensemble rainfall forecasts issued by the Canadian Global Ensemble Prediction System in its 2009 operational version. This hydro‐meteorological operational forecasting chain was conducted using the hydrological model SWMM5. The model was implemented on a small 6‐km² urban catchment located in the Québec City region. The hydrological evaluation was based on the comparison of forecasted flows to the observed ones, calculating several deterministic and probabilistic scores, and drawing rank histograms and reliability diagrams. Disaggregated products led to a better representation of the ensemble members' dispersion. This disaggregation technique represents an interesting way of bridging the gap between the meteorological models' resolution and the high degree of spatial precision sometimes required by hydrological models in their precipitation representation. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Controls on valley spacing in landscapes subject to rapid base‐level fall          下载免费PDF全文

Luke A. McGuire  Jon D. Pelletier 《地球表面变化过程与地形》2016,41(4):460-472

What controls the architecture of drainage networks is a fundamental question in geomorphology. Recent work has elucidated the mechanisms of drainage network development in steadily uplifting landscapes, but the controls on drainage‐network morphology in transient landscapes are relatively unknown. In this paper we exploit natural experiments in drainage network development in incised Plio‐Quaternary alluvial fan surfaces in order to understand and quantify drainage network development in highly transient landscapes, i.e. initially unincised low‐relief surfaces that experience a pulse of rapid base‐level drop followed by relative base‐level stasis. Parallel drainage networks formed on incised alluvial‐fan surfaces tend to have a drainage spacing that is approximately proportional to the magnitude of the base‐level drop. Numerical experiments suggest that this observed relationship between the magnitude of base‐level drop and mean drainage spacing is the result of feedbacks among the depth of valley incision, mass wasting and nonlinear increases in the rate of colluvial sediment transport with slope gradient on steep valley side slopes that lead to increasingly wide valleys in cases of larger base‐level drop. We identify a threshold magnitude of base‐level drop above which side slopes lengthen sufficiently to promote increases in contributing area and fluvial incision rates that lead to branching and encourage drainage networks to transition from systems of first‐order valleys to systems of higher‐order, branching valleys. The headward growth of these branching tributaries prevents the development of adjacent, ephemeral drainages and promotes a higher mean valley spacing relative to cases in which tributaries do not form. Model results offer additional insights into the response of initially unincised landscapes to rapid base‐level drop and provide a preliminary basis for understanding how varying amounts of base‐level change influence valley network morphology. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Mapping and detection of land use change in a coal mining area using object-based image analysis     

Wenming Pei  Suping Yao  Joseph F. Knight  Shaochun Dong  Keith Pelletier  Lian P. Rampi  Yan Wang  Jim Klassen 《Environmental Earth Sciences》2017,76(3):125

Object-based image analysis was used to map land use in the Panxie coal mining area, East China, where long-term underground coal mines have been exploited since the 1980s. A rule-based classification approach was developed for a Pleiades image to identify the desired land use classes, and the same rule-based classification strategies, after the threshold values had been modified slightly, were applied to the Landsat series images. Five land use classes were successfully captured with overall accuracies of between 80 and 94%. The classification approach was validated for its flexibility and robustness. Multitemporal classification results indicated that land use changed considerably in the Panxie coal mining area from 1989 to 2013. The urban, coal and coal gangue, and water areas increased rapidly in line with the growth in mine production. Urban areas increased from 9.38 to 20.92% and showed a tendency to increase around the coal mines. From 1989 to 2013 the coal and coal gangue area increased by 40-fold, from 0.02 to 0.58%. Similarly, the water area increased from 2.77 to 7.84% over this time period, mainly attributable to the spread of waterlogged areas. The waterlogged areas increased to about 2900 ha in 2013, which was about 80 times more than their area in 1989. In contrast, the area of cultivated land was negatively related to the increase in mine production and decreased from 73.11 to 57.25%. The results of this study provide a valuable basis for sustainable land management and environmental planning in the Panxie coal mining area.  相似文献