Ra-partitioning between phlogopite and silicate melt and 226Ra/Ba–230Th/Ba isochrons     

Alessandro Fabbrizio  Max W. Schmidt  Detlef Günther  Jost Eikenberg 《Lithos》2010,114(1-2):121-131

In this study we experimentally determine phlogopite/melt partition coefficients of Ra and other trace elements in a lamproitic system. This work was achieved using an analytical technique (LA-ICP-MS) with low detection limits (~ 0.01 fg) permitting the measurement of the very low Ra concentrations feasible in experiments (~ 1 ppb). D_Ra^{phlogopite/melt} was determined to 2.28 ± 0.44 and 2.84 ± 0.47 in two experiments, the ratio D_Ra/D_Ba is around 1.6. The compatibility of Ra in phlogopite results from an ionic radius being close to the apex of the lattice strain parabola for earth alkalis in the large XII-coordinated interlayer site of phlogopite. A re-evaluation of D_Ra and D_Ra/D_Ba for magmatic minerals containing appreciable Ra, yields D_Ra^mineral/melt ranging from ~ 2.6 for phlogopite down to 2–3 ? 10^? 5 for pyroxenes, and D_Ra/D_Ba^mineral/melt from ~ 4 for leucite to 2 ? 10^? 2 for orthopyroxene. The influence of melt composition on D_Ra/D_Ba is less than 10%. All investigated minerals have different D_Ra/D_Ba, strongly fractionating Ra from Ba. Thus, for magmatic systems, (²²⁶Ra)/Ba in the various minerals is not constant, these minerals do not form a straight line in the (²²⁶Ra)/Ba–(²³⁰Th)/Ba system at the time of crystallization and thus, there is no (²²⁶Ra)/Ba–(²³⁰Th)/Ba isochron at t₀. ²²⁶Ra–²³⁰Th–Ba mineral dating is thus applicable only to model ages calculated from mineral–glass pairs with known D_Ra.  相似文献   

Post-drought increase in regional-scale groundwater nitrate in southwest Germany     

Karuna Jutglar  Jost Hellwig  Michael Stoelzle  Jens Lange 《水文研究》2021,35(8):e14307

Elevated nitrate concentrations in groundwater are a common challenge for water management. One important factor in this context is higher frequencies and intensities of wet-dry cycles that may cause increased nitrate concentrations in groundwater due to nitrate flushes after drought termination. Yet systematic studies on regional-scale impacts of droughts on groundwater nitrate concentrations are missing so far. Here we analyzed time series of 44 shallow groundwater wells and 41 springs all across the German Federal State Baden-Wuerttemberg from 2000 to 2018 to characterize patterns of post-drought nitrate increase in groundwater. In general, half of the exceptional nitrate concentrations, which exceeded the 80th percentile of long-term nitrate measurements, could be related to droughts in the research timeframe. The 2003 drought event stood out in terms of drought severity and post-drought nitrate concentration increases in our data. The great majority (91%) of all monitoring sites showed at least one exceptionally high nitrate concentration in the 4 years following the 2003 drought event. Springs were mainly located in forests of steep low mountain ranges and wells in cropland of flat river valleys. Therefore, delay times between drought intensity and nitrate concentration increases as well as magnitudes of nitrate concentration increase were diverse among wells and springs. We derived two distinct nitrate response patterns: (i) nitrate increases immediately following drought events (more common for springs and fractured rock aquifers) and (ii) delayed nitrate increases (more common for wells and porous aquifers). Springs generally showed quicker (median of 101 days) but weaker (median of +1.3 mg/L) post-drought nitrate increases than wells (185 days, +3.4 mg/L). Only few sites exhibited no post-drought nitrate increase and post-drought mean-nitrate concentrations of groundwater reservoirs were extraordinarily high in 2006. Overall, we demonstrate that post-drought nitrate increase in groundwater is omnipresent, while different landscapes and hydrogeological characteristics create a diverse regional pattern. As severe droughts become more frequent in a changing climate, post-drought nitrate increase may intensify problems regarding water quality and supply.  相似文献   

Fault plane solutions of microearthquakes and small events in the Hellenic arc     

Michael L. Jost  Olaf Knabenbauer  Jin Cheng  Hans-Peter Harjes   《Tectonophysics》2002,356(1-3)

The Hellenic arc is the most active seismic region of the transition zone between the African and Eurasian plates. In this rapidly deforming region, the physical state of the crust and upper mantle may vary laterally and vertically. However, a detailed 3D model of the region is lacking. The reliable determination of fault plane solutions is crucial if such a model is to be produced. On this basis, fault plane solutions have been determined from recent microearthquakes and small events to assess their reliability for use in tectonic interpretation. A search algorithm on first motion data and amplitude ratios and also a waveform-matching scheme were employed on data from our temporal network, operated on the western part of the island of Crete. There, a network of 47 three-component digital stations with an aperture of 60 km and an average station spacing of 5 km was operated in 1997. The majority of the shallow microearthquakes under Crete for which fault plane solutions were determined have a near horizontal T-axis oriented essentially E–W. Differences between well determined fault plane solutions from the search algorithm and the waveform-matching technique were significant (strike up to 45°, dip up to 10°, and slip up to 50°). Second, data of small events within the Hellenic subduction zone were obtained from recently installed broadband stations at local and regional distances and inverted for a deviatoric seismic moment tensor. Available solutions from other sources such as the Harvard group, EMSC, or SED show drastic differences in part. Owing to still limited azimuthal station coverage, the resulting fault plane solutions of small events have generally not been well constrained. The observed large variation of fault plane solutions for micoearthquakes and small events poses a caveat to tectonic interpretation in case of using data from a few stations only.  相似文献   

Precise two chronometer dating of Pleistocene travertine: The Th/U and Ra_ex/Ra(0) approach     

Jost Eikenberg  Guido Vezzu  Irene Zumsteg  Sixto Bajo  Max Ruethi  Georg Wyssling 《Quaternary Science Reviews》2001,20(18):129

In order to determine the geochemical evolution of a freshwater limestone cave system located in central Switzerland (Hell Grottoes at Baar/Zug,) young postglacial tufaceous limestone and travertine precipitates were investigated using the ²³⁰Th/²³⁴U ingrowth system. Additional analyses of further radionuclides within the ²³⁸U decay chain, i.e. ²²⁶Ra and ²¹⁰Pb, showed that the Th/U chronometer started with insignificant inherited ²³⁰Th over the entire formation period of the travertine setting (i.e. ²³⁰Th(0)=0). A contribution from detrital impurities with ²³⁰Th/²³⁴U in secular equilibrium could be precisely subtracted by applying isochron dating of cogenetic phases and recently formed travertine. The resulting precise ²³⁰Th/²³⁴U formation ages were found to be consistent with the geological stratigraphy and were furthermore used to demonstrate the applicability of the next geologically important chronometer in the ²³⁸U-decay series, based on decay of excess ²²⁶Ra normalized to the initial, i.e.²²⁶Ra_ex/²²⁶Ra(0). This system is suitable for dating phases younger than 7000 yr when the correction of a detritus component increasingly limits the precision of the ²³⁰Th/²³⁴U chronometer. Analytical solutions of the coupled ²³⁴U/²³⁰Th/²²⁶Ra radionuclide system predicted that the ²²⁶Ra_ex/²²⁶Ra(0) chronometer is independent of the actual ²³⁰Th activity build up from decay of ²³⁴U, if the systems starts with zero inherited ²³⁰Th(0). The data set confirmed this hypothesis and showed furthermore that the initially incorporated ²²⁶Ra excess must have remained almost uniform in all limestone over a period of at least 7000 yr, i.e. 4–5 half-lives of ²²⁶Ra. This is concluded because (i) the ²²⁶Ra_ex/²²⁶Ra(0) ages agreed well with those derived from ²³⁰Th/²³⁴U, (ii) all data plot within uncertainty on the ²²⁶Ra_ex/²²⁶Ra(0) decay curve and (iii) the atomic Ba/Ca ratio was found to be constant in the travertine material independent of the sample ages. Provided that such boundary conditions hold, ²²⁶Ra_ex/²²⁶Ra(0) should be applicable to materials which are suitable for ²³⁰Th/²³⁴U dating in sedimentology and oceanography, i.e. travertine, corals, phosphorites, etc., and should strongly support ²³⁰Th/²³⁴U for samples that have been formed a few thousand years ago.  相似文献   

Untersuchung über die Verteilung von Spurengasen in der freien Atmosphäre     

Hans-Walter Georgii  Dieter Jost 《Pure and Applied Geophysics》1964,59(1):217-224

Zusammenfassung Die vorliegende Arbeit behandelt die Ergebnisse von Messflügen zur Bestimmung der Konzentrationsverteilung von Spurengasen in der freien Atmosphäre. Auf Grund dieser Aufstiege war es erstmals möglich, den Gehalt der Atmosphäre an Schwefeldioxyd und Stickstoffdioxyd bis in Höhen von 6000 m zu erfassen. Die gewonnene mittelere Konzentrations-verteilung bietet die Basis zu Abschätzungen über den Haushalt und die mittlere Verweilzeit von SO₂ und NO₂ in der Troposphäre.

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Summary This paper deals with the results of aircraft ascents for the measurement of the vertical distribution of atmospheric trace gases in the free atmosphere. The aircraft ascents permitted for the first time to measure the SO₂- and NO₂-concentration up to 6000 m. On the basis of the average distribution assumptions on the tropospheric budget of SO₂ and NO₂ as well as on the average tropospheric residence time of these gases were made.

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High resolution simulation of recent Arctic and Antarctic stratospheric chemical ozone loss compared to observations     

Om Prakash Tripathi  Sophie Godin-Beekmann  Franck Lefèvre  Marion Marchand  Andrea Pazmiño  Alain Hauchecorne  Florence Goutail  Hans Schlager  C. Michael Volk  B. Johnson  G. König-Langlo  Stefano Balestri  Fred Stroh  T. P. Bui  H. J. Jost  T. Deshler  Peter von der Gathen 《Journal of Atmospheric Chemistry》2006,55(3):205-226

Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1^∘ × 1^∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1^∘ × 1^∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO₃, N₂O, and NO _y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10⁻³ to 10⁻² cm⁻³) refines the agreement with in situ ozone, N₂O and NO _y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl₂O₂ absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl₂O₂ absorption cross-sections.  相似文献   

Vergleich von marokkanischen Kreide-Küstenaufschlüssen und Tiefseebohrungen (DSDP): Stratigraphie,Paläoenvironment und Subsidenz an einem passiven Kontinentalrand     

Jost Wiedmann  Arif Butt  Gerhard Einsele 《International Journal of Earth Sciences》1978,67(2):454-508

In comparison to other regions round the North Atlantic, good exposures in the Moroccan coastal basins offer an excellent opportunity to study the Mesozoic development of a passive continental margin including the relationship between oceanic and coastal sediments and datum levels of the pelagic fossils. From south to north, the Cretaceous sediments of the coastal basins of Tarfaya, Agadir, Essaouira and at the margin of the Meseta are described and compared with each other regarding macro- and microfauna, sedimentology, and paleoenvironment. For the mainly marine 2500 m resp. 1700 thick Cretaceous sequences of Agadir and Essaouira, a correlation of ammonite and foraminiferal zones is proposed. Probably both sections were formed in one basin, but certain facies differences were caused by different water depths since Middle Cretaceous times. Most of the early Cretaceous sediments of the Tarfaya region in the south and of the Meseta in the north are of continental origin. Late Cretaecous sediments of these regions reveal, however, principal differences, especially in view of the macrofauna. On the Meseta, the macrofauna is typical of the Mediterranean faunal province, whereas the Tarfaya fauna is characterized by north-boreal elements. This is explained by the influence of upwelling in connection with the initiation of an oceanic deep-sea circulation, which also can be traced into the Agadir section. As a result, already during Turonian times, here bituminous marls with chert layers are deposited. These are missing farther to the north, but later nannomarls, chalk, chert layers and, in addition, locally phosphates are formed there, too. Generally, during the Cretaceous period, a tendency towards decreasing sedimentation rates and a relative increase of the percentage of pelagic components such as planktonic foraminifera in the local sediment can be observed, indicating a sharp decrease of the terrigeneous influx and a landward transgression of the oceanic water mass. If the global eustatic curve for the Cretaceous oceans is compared to the local bathymetric curves of the Moroccan coastal basins, one can distinguish between local phenomena and global events (Turonian and Campanian transgressions). In comparing the Cretaceous sections of DSDP sites 370 and 137 with the Agadir sequence on the continent, an attempt is made to reveal the development of the marginal North Atlantic, related to an increase of the paleodepth and the influence of the CCD. At Cape Bojador, in a transect across the continental margin from inland wells to the upper rise (DSDP site 397), the subsidence history of the uniformly subsiding ?marginal basin“ is derived. In the Jurassic, the rates of subsidence as well as those of sedimentation reach the order of magnitude of about 100 m/million years. The early Cretaceous subsidence increases up to 140 m/million years. As a result, sedimentation soon cannot keep pace, the water depth at the outer margin increases, and the shelf edge and continental slope are formed. In the last 100 million years, the subsidence decreases more or less exponentially. For the well subdivided Cretaceous sequences of the coastal basins described above, the interrelationship between subsidence, paleowaterdepth, and sedimentation rate has been worked out in more detail.  相似文献   

Henry's law and hydrolysis-rate constants for peroxyacyl nitrates (PANs) using a homogeneous gas-phase source     

Jost Kames  Ulrich Schurath 《Journal of Atmospheric Chemistry》1995,21(2):151-164

The solubilities and hydrolysis rates of PAN (peroxyacetyl nitrate) and its homologues PPN (peroxypropionyl nitrate), PnBN (peroxy-n-butyl nitrate), PiBN (peroxy-isobutyl nitrate) and MPAN (peroxymethacryloyl nitrate) in liquid water have been studied at 20 °C. Temperature dependencies were measured for PAN and PPN. The solubilities of peroxyacyl nitrates decrease smoothly with increasing carbon-chain length fromH (293 K)=4.1 M atm^–1 (PAN) toH (293 K)=1.0 M atm^–1 (PiBN). Hydrolysis-rate constants, which cover the range fromk _h (293 K)=(2.4–7.4)×10^–4 s^–1, do not show a systematic chain-length dependency. Solubilities of PAN and PPN in solutions which mimic the composition and ionic strength of sea water are 15% and 20% lower than in pure water. The hydrolysis rate constants are not affected.  相似文献   

Impact of the Bergeron–Findeisen process on the release of aerosol particles during the evolution of cloud ice     

A. Schwarzenbck  S. Mertes  J. Heintzenberg  W. Wobrock  P. Laj 《Atmospheric Research》2001,58(4)

The paper focuses on the redistribution of aerosol particles (APs) during the artificial nucleation and subsequent growth of ice crystals in a supercooled cloud. A significant number of the supercooled cloud droplets during icing periods (seeding agents: C₃H₈, CO₂) did not freeze as was presumed prior to the experiment but instead evaporated. The net mass flux of water vapour from the evaporating droplets to the nucleating ice crystals (Bergeron–Findeisen mechanism) led to the release of residual particles that simultaneously appeared in the interstitial phase. The strong decrease of the droplet residuals confirms the nucleation of ice particles on seeding germs without natural aerosol particles serving as ice nuclei. As the number of residual particles during the seedings did not drop to zero, other processes such as heterogeneous ice nucleation, spontaneous freezing, entrainment of supercooled droplets and diffusion to the created particle-free ice germs must have contributed to the experimental findings. During the icing periods, residual mass concentrations in the condensed phase dropped by a factor of 1.1–6.7, as compared to the unperturbed supercooled cloud. As the Bergeron–Findeisen process also occurs without artificial seeding in the atmosphere, this study demonstrated that the hydrometeors in mixed-phase clouds might be much cleaner than anticipated for the simple freezing process of supercooled droplets in tropospheric mid latitude clouds.  相似文献   

Field studies of anoxic conditions in the Baltic Sea during the cruise of R/V <Emphasis Type="Italic">Professor Albrecht Penck</Emphasis> in July 2006     

G. Jost  B. Clement  S. V. Pakhomova  E. V. Yakushev 《Oceanology》2007,47(4):590-593

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