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921.
Philippe E. Raison Stephen Heathman Gilles Wallez Carmen E. Zvoriste Denis Bykov Ga?l Ménard Emmanuelle Suard Karin Popa Nicolas Dacheux Rudy J. M. Konings Roberto Caciuffo 《Physics and Chemistry of Minerals》2012,39(8):685-692
The crystal structure of the cheralite—CaTh(PO4)2—has been revisited by neutron diffraction and its behaviour under high pressure investigated by X-ray diffraction up to 36?GPa. The neutron diffraction data at ambient pressure gave a more accurate determination of the Ca/Th cation position than previous XRD data, taking advantage that the neutron scattering lengths of calcium and thorium are of same order of magnitude. The nuclear density distribution was also determined using the maximum entropy method (MEM) confirming that the two cations are not located at the same position in the unit cell but are slightly displaced from one another along a specific direction in order to minimize the electrostatic repulsion with the surrounding phosphorus atoms. At high pressure, the compound did not show any phase transition or amorphization. From the evolution of the unit-cell volume as a function of the pressure, the zero-pressure bulk modulus B0 and its pressure derivative B0 ′ have been determined by fitting the experimental compressibility curve to the Birch–Murnaghan equation of state. The results are B0?=?140(2) GPa and B 0 ′ ?=?4.4(4) GPa. 相似文献
922.
923.
Heather Michelle Wright Charles R. Bacon Jorge A. Vazquez Thomas W. Sisson 《Contributions to Mineralogy and Petrology》2012,164(6):1027-1052
The well-documented eruptive history of Mount Mazama, Oregon, provides an excellent opportunity to use pre-eruptive volatile concentrations to study the growth of an explosive silicic magmatic system. Melt inclusions (MI) hosted in pyroxene and plagioclase crystals from eight dacitic–rhyodacitic eruptive deposits (71–7.7?ka) were analyzed to determine variations in volatile-element concentrations and changes in magma storage conditions leading up to and including the climactic eruption of Crater Lake caldera. Temperatures (Fe–Ti oxides) increased through the series of dacites, then decreased, and increased again through the rhyodacites (918–968 to ~950 to 845–895?°C). Oxygen fugacity began at nickel–nickel-oxide buffer (NNO) +0.8 (71?ka), dropped slightly to NNO +0.3, and then climbed to its highest value with the climactic eruption (7.7?ka) at NNO +1.1 log units. In parallel with oxidation state, maximum MI sulfur concentrations were high early in the eruptive sequence (~500?ppm), decreased (to ~200?ppm), and then increased again with the climactic eruption (~500?ppm). Maximum MI sulfur correlates with the Sr content (as a proxy for LREE, Ba, Rb, P2O5) of recharge magmas, represented by basaltic andesitic to andesitic enclaves and similar-aged lavas. These results suggest that oxidized Sr-rich recharge magmas dominated early and late in the development of the pre-climactic dacite–rhyodacite system. Dissolved H2O concentrations in MI do not, however, correlate with these changes in dominant recharge magma, instead recording vapor solubility relations in the developing shallow magma storage and conduit region. Dissolved H2O concentrations form two populations through time: the first at 3–4.6 wt% (with a few extreme values up to 6.1 wt%) and the second at ≤2.4 wt%. CO2 concentrations measured in a subset of these inclusions reach up to 240?ppm in early-erupted deposits (71?ka) and are below detection in climactic deposits (7.7?ka). Combined H2O and CO2 concentrations and solubility models indicate a dominant storage region at 4–7?km (up to 12?km), with drier inclusions that diffusively re-equilibrated and/or were trapped at shallower depths. Boron and Cl (except in the climactic deposit) largely remained in the melt, suggesting vapor–melt partition coefficients and gas fractions were low. Modeled Li, F, and S vapor–melt partition coefficients are higher than those of B and Cl. The decrease in maximum MI CO2 concentration following the earliest dacitic eruptions is interpreted to result from a broadening of the shallow storage region to greater than the diameter of subjacent feeders, so that greater proportions of reservoir magma were to the side of CO2-bearing vapor bubbles ascending vertically from the locus of recharge magma injection, thereby escaping recarbonation by streaming vapor bubbles. The Mazama melt inclusions provide a picture of a growing magma storage region, where chemical variations in melt and magma occur due to changes in the nature and supply rate of magma recharge, the timing of degassing, and the possible degree of equilibration with gases from below. 相似文献
924.
The premise of the Wilson et al. comment is that the Ti-in-quartz solubility calibration (Thomas et al. in Contrib Mineral
Petrol 160:743–759, 2010) is fundamentally flawed. They reach this conclusion because P–T estimates using the Ti-in-quartz calibration differ from their previous interpretations for crystallization conditions of
the Bishop and Oruanui rhyolites. If correct, this assertion has far-reaching implications, so a careful assessment of the
Wilson et al. reasoning is warranted. Application of the Ti-in-quartz calibration as a thermobarometer in rutile-free rocks
requires an estimation of TiO2 activity in the liquid ( (liquid–rutile); referenced to rutile saturation) and an independent constraint on either P or T to obtain the crystallization temperature or pressure, respectively. The foundation of Wilson et al.’s argument is that temperature
estimates obtained from Fe–Ti oxide thermometry accurately reflect crystallization conditions of quartz in the two rhyolites
discussed. We maintain that our experimental approach is sound, the thermodynamic basis of the Ti-in-quartz calibration is
fundamentally correct, and our experimental results are robust and reproducible. We suggest that the reason Wilson et al.
obtain implausible pressure estimates is because estimates for T and they used as input values for the Ti-in-quartz calibration are demonstrably too high. Numerous studies show that Fe–Ti oxide
temperature estimates of some rhyolites are substantially higher than those predicted by well-constrained phase equilibria.
In this reply, we show that when reasonable input values for T and (liquid–rutile) are used, pressure estimates obtained from the Ti-in-quartz calibration are well aligned with phase equilibria
and essentially identical to melt inclusion volatile saturation pressures. 相似文献
925.
Mountain Lake in Giles County, Virginia, USA, has a documented history of severe natural lake-level changes involving groundwater seepage that extends over the past 4,200?years. The natural lake was full during a large part of the twentieth century but dried up completely in September 2008 and levels have yet to recover. The objective of the study was to understand the hydrogeologic factors that influence lake-level changes using a daily water balance, electrical resistivity, water sampling and geochemical analysis, and well logging. Results from the water balance demonstrate the seasonal response to precipitation of a forested first-order drainage system in fractured rock. The resistivity surveys suggest discrete high-permeability areas may provide pathways for lake drainage. Imagery, well logs, and field observations appear to confirm the presence of a fault which crosses the Eastern Continental Divide to the east of the lake that had not previously been discussed in literature on the lake; the position of the lake within local and intermediate groundwater flow systems is considered. Historical data suggest that either significant precipitation or artificial intervention to mitigate seepage would be required for lake-level recovery in the near future. 相似文献
926.
Ilia Rochlin Mary-Jane James-Pirri Susan C. Adamowicz Mary E. Dempsey Thomas Iwanejko Dominick V. Ninivaggi 《Estuaries and Coasts》2012,35(3):727-742
An integrated marsh management (IMM) project in an urbanized watershed on Long Island, New York, USA, aimed to mitigate salt marsh degradation and to reduce mosquito production by an innovative combination of restoration and open marsh water management methods. The grid ditch network at two treatment marshes was replaced with naturalized tidal channels and ponds. Effects of the hydrologic alterations were monitored utilizing a before–after–control–impact approach. The treatment marshes experienced a number of beneficial outcomes including a fourfold reduction in the invasive Phragmites australis and increased native vegetation cover in the most degraded portions of the marsh, increased abundance and diversity of marsh killifish and estuarine nekton species, higher shorebird and waterfowl densities, and increased avian species diversity. The successful implementation of IMM concept led to improved marsh health and diminished mosquito production. Therefore, this study may serve as a template for similar large-scale integrated salt marsh restoration projects. 相似文献
927.
928.
Granite magma migration and emplacement along thrusts 总被引:1,自引:0,他引:1
Eric C. Ferré Olivier Galland Domenico Montanari Thomas J. Kalakay 《International Journal of Earth Sciences》2012,101(7):1673-1688
This paper investigates the influence exerted by brittle tectonic structures in the emplacement of granite plutons in contractional settings. We address both cases where contractional tectonics and magma intrusion are (1) coeval, to study how active contractional tectonics controls the transport of magma, and (2) diachronous, to study the role of pre-existing structures on the transport of magma. In light of new experimental models, we show that magma can rise along thrusts ramps and flats. This phenomenon occurs for both low-viscosity magma (basalts to andesite) and high-viscosity magma (dry granite). The experimental results also allow the evaluation of the role played by magma viscosity in determining pluton geometries. In addition, a review of literature demonstrates a spatial and causal relationship between granites and thrusts and highlights the geometric control of magma pathways in the pluton final shape. The abundance of subhorizontal and tabular granitic intrusions indicates that the location of inflating granitic sills along thrust flats can be common. We argue that active and pre-existing flats-and-ramps thrusts provide a preferential continuous planar anisotropy susceptible to become a granitic magma migration pathway. 相似文献
929.
Microstructural and magnetic investigations (anisotropy of magnetic susceptibility, AMS) on sections across basement–cover interfaces (BCI) revealed a complex evolution in the crystalline basement rocks beneath and in the basal units of the Caledonian fold-and-thrust belt: (1) Pre-Caledonian mylonitic fabrics in basement granite relate to steep shear zones. (2) Palaeoweathering formed smectite and illite at the expense of feldspar and mica. Secondary Fe-bearing clay minerals and the intensity of the chemical weathering control the bulk susceptibility. Changing susceptibility and AMS relate to a (time) sequence from primary magnetite to secondary paramagnetic clay to pyrite and ferrimagnetic pyrrhotite. (3) Burial compaction with BCI-parallel fabrics. (4) Caledonian cleavage, overprinted by décollement zones with S–C–C′ fabrics. Décollement cataclasis overprinted pre-existing magnetic fabrics and produced horizontal magnetic lineations and subhorizontal foliations defined by the S–C–C′ fabrics. Clay mineral enrichment, together with subsequent, BCI-parallel compaction fabrics, decreased the shear strength in the basement rocks beneath the BCI. Detachments initiated at such low-strength zones and produced allochthonous units with their footwall within crystalline basement rocks, an observation of general importance for orogenic fold-and-thrust belts. 相似文献
930.
Stability analysis of the 2007 Chehalis lake landslide based on long-range terrestrial photogrammetry and airborne LiDAR data 总被引:1,自引:1,他引:0
Marc-André Brideau Matthieu Sturzenegger Doug Stead Michel Jaboyedoff Martin Lawrence Nicholas J. Roberts Brent C. Ward Thomas H. Millard John J. Clague 《Landslides》2012,9(1):75-91
On December 4th 2007, a 3-Mm3 landslide occurred along the northwestern shore of Chehalis Lake. The initiation zone is located at the intersection of the
main valley slope and the northern sidewall of a prominent gully. The slope failure caused a displacement wave that ran up
to 38 m on the opposite shore of the lake. The landslide is temporally associated with a rain-on-snow meteorological event
which is thought to have triggered it. This paper describes the Chehalis Lake landslide and presents a comparison of discontinuity
orientation datasets obtained using three techniques: field measurements, terrestrial photogrammetric 3D models and an airborne
LiDAR digital elevation model to describe the orientation and characteristics of the five discontinuity sets present. The
discontinuity orientation data are used to perform kinematic, surface wedge limit equilibrium and three-dimensional distinct
element analyses. The kinematic and surface wedge analyses suggest that the location of the slope failure (intersection of
the valley slope and a gully wall) has facilitated the development of the unstable rock mass which initiated as a planar sliding
failure. Results from the three-dimensional distinct element analyses suggest that the presence, orientation and high persistence
of a discontinuity set dipping obliquely to the slope were critical to the development of the landslide and led to a failure
mechanism dominated by planar sliding. The three-dimensional distinct element modelling also suggests that the presence of
a steeply dipping discontinuity set striking perpendicular to the slope and associated with a fault exerted a significant
control on the volume and extent of the failed rock mass but not on the overall stability of the slope. 相似文献