A Lithospheric Cross-Section Through the Swiss Alps—I. Thermokinematic Modelling of the Neoalpine Orogeny     

N. Okaya  R. Freeman  E. Kissling  St. Mueller 《Geophysical Journal International》1996,125(2):504-518

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Mercury-binding proteins in the slipper limpet,Crepidula fornicata,exposed to increased soluble mercury     

Florence L. Harrison  Kathleen Watness  David A. Nelson  James E. Miller  Anthony Calabrese 《Estuaries and Coasts》1987,10(1):78-83

Crepidula fornicata were held in a flow-through bioassay system and exposed to sand-filtered seawater to which no soluble mercury (control) was added or to which either 5, 25, or 50 μg 1^?1 soluble Hg was added. At specific intervals during the 16-week experiment, a group of limpets was removed from each tank; one subgroup was exposed for 48 h to high concentrations of Hg, and another was analyzed for Hg-binding proteins by gelpermeation chromatography and spectrometry. Mortality from exposure to Hg in the 48-h acute toxicity tests was related to concentrations of Hg experienced both during the long-term exposure period and the 48-h exposure period. Chronic exposure to low levels of Hg resulted in increased amounts of total Hg in the whole body and in the low-molecular-weight Hg-binding proteins. No evidence was found for increased tolerance to Hg with preexposure.  相似文献   

Acquisition and processing of data for isotope-ratio-monitoring mass spectrometry     

Ricci MP  Merritt DA  Freeman KH  Hayes JM 《Organic Geochemistry》1994,21(6-7):561-571

Methods are described for continuous monitoring of signals required for precise analyses of 13C, 18O, and 15N in gas streams containing varying quantities of CO2 and N2. The quantitative resolution (i.e. maximum performance in the absence of random errors) of these methods is adequate for determination of isotope ratios with an uncertainty of one part in 10(5); the precision actually obtained is often better than one part in 10(4). This report describes data-processing operations including definition of beginning and ending points of chromatographic peaks and quantitation of background levels, allowance for effects of chromatographic separation of isotopically substituted species, integration of signals related to specific masses, correction for effects of mass discrimination, recognition of drifts in mass spectrometer performance, and calculation of isotopic delta values. Characteristics of a system allowing off-line revision of parameters used in data reduction are described and an algorithm for identification of background levels in complex chromatograms is outlined. Effects of imperfect chromatographic resolution are demonstrated and discussed and an approach to deconvolution of signals from coeluting substances described.  相似文献   

Isotopic composition of surface-correlated chromium in Apollo 16 lunar soils     

B.Kathleen Kitts  Frank A. Podosek  Joyce C. Brannon  Randy L. Korotev 《Geochimica et cosmochimica acta》2003,67(24):4881-4893

We have analyzed by thermal ionization mass spectrometry (TIMS) the isotopic composition of Cr in five progressive etches of size-sorted plagioclase grains separated from lunar soils 60601 and 62281. Aliquots of the etch solutions were spiked for isotopic dilution (ID) analysis of Cr and Ca. The Ca ID data indicate that the initial etch steps represent dissolution of an average 0.1 to 0.2 μm depth from the grain surfaces, the approximate depth expected for implanted solar wind. The Cr/Ca ratio in the initial etches is several fold higher than that expected for bulk plagioclase composition, but in subsequent etches decreases to approach the bulk value. This indicates a source of Cr extrinsic to the plagioclase grains, surface-correlated and resident in the outermost fraction of a μm, which we provisionally identify as solar wind Cr. The surface-correlated Cr is isotopically anomalous and by conventional TIMS data reduction has approximately 1 permil excess ⁵⁴Cr and half as great excess ⁵³Cr. In successive etches, as the Cr/Ca ratio decreases and approaches the bulk plagioclase value, the magnitude of the apparent anomalies decreases approaching normal composition. If these results do indeed characterize the solar wind, then either the solar wind is enriched in Cr due to spallation in the solar atmosphere, or the Earth and the various parent bodies of the meteorites are isotopically distinct from the Sun and must have formed from slightly different mixes of presolar materials. Alternative interpretations include the possibility that the anomalous Cr is meteoritic rather than solar or that the observed (solar) Cr is normal except for a small admixture of spallation Cr generated on the Moon. We consider these latter possibilities less likely than the solar wind interpretation. However, they cannot be eliminated and remain working hypotheses.  相似文献   

Strontium Isotopic Signatures of the Streams and Lakes of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering in a Polar Climate     

W. B. Lyons  Carmen A. Nezat  Larry V. Benson  Thomas D. Bullen  Elizabeth Y. Graham  Jesicca Kidd  Kathleen A. Welch  James M. Thomas 《Aquatic Geochemistry》2002,8(2):75-95

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different ⁸⁷Sr/⁸⁶Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system could be either the Cenozoic volcanic rocks that make up a small portion of the till deposited in the valley during the Last Glacial Maximum or from marble derived from the local basement rocks. The more radiogenic ratios from Lake Bonney originate from ancient salt deposits that flow into the lake from Taylor Glacier and the weathering of minerals with more radiogenic Sr isotopic ratios within the tills. The Sr isotopic data from the streams and lakes of Taylor Valley strongly support the notion documented by previous investigators that chemical weathering has been, and is currently, a major process in determining the overall aquatic chemistry of these lakes in this polar desert environment.  相似文献   

Comet Tago-Sato-Kosaka 1969 IX: Tail structure 25 December 1969 to 12 January 1970     

Freeman D. Miller 《Icarus》1979,37(2):443-456

On photographs taken between 25 December 1969 and 12 January 1970 with the Michigan Curtis Schmidt on Cerro Tololo and the Hamburg Schmidt at the Boyden Observatory, Comet 1969 IX is seen projected on planes nearly perpendicular to its orbit. During this period the Type I tail was free of major structural disturbances, and the faintness of the Type II tail facilitated study of the Type I tail near the lead. Characteristics of the main Type I tail are described in Part II. A classification of the tail forms according as the tail had the form of a fan of rays or a wedge, the orientation of the tail axis, and the angular width of the tail are discussed in Section IIA. In Section IIB the structure of the tail from 26 to 31 December, a period within which a disconnection of the tail took place, is viewed as the possible result of the passage across the comet of an interplanetary magnetic sector boundary, as proposed by Niedner and Brandt (1977, Bull. Amer. Astron. Soc. 4). In Sections IIC and IID waves in rays and the onset of turbulence are considered. Section IIIA is devoted to unusually long and bright off-axis rays; data on longitudinal forms, closing rate to the axis, and photometry of a ray are presented. In Section IIIB the structure of a “plume” of seven nearly parallel rays is related to the configuration of magnetic field lines predicted by Schmidt and Wegmann (1976, IPP Report 6/147). The orientations of the plume rays are consistent with those of the calculated field lines; the inferred rate of generation of the rays is about 1/hr.  相似文献   

Interaction of wind and cold-season hydrologic processes on erosion from complex topography following wildfire in sagebrush steppe     

Samantha P. Vega  C. Jason Williams  Erin S. Brooks  Frederick B. Pierson  Eva K. Strand  Peter R. Robichaud  Robert E. Brown  Mark S. Seyfried  Kathleen A. Lohse  Kayla Glossner  Jennifer L. Pierce  Clay Roehner 《地球表面变化过程与地形》2020,45(4):841-861

Wildfire is a natural component of sagebrush (Artemisia spp.) steppe rangelands that induces temporal shifts in plant community physiognomy, ground surface conditions, and erosion rates. Fire alteration of the vegetation structure and ground cover in these ecosystems commonly amplifies soil losses by wind- and water-driven erosion. Much of the fire-related erosion research for sagebrush steppe has focused on either erosion by wind over gentle terrain or water-driven erosion under high-intensity rainfall on complex topography. However, many sagebrush rangelands are geographically positioned in snow-dominated uplands with complex terrain in which runoff and sediment delivery occur primarily in winter months associated with cold-season hydrology. Current understanding is limited regarding fire effects on the interaction of wind- and cold-season hydrologic-driven erosion processes for these ecosystems. In this study, we evaluated fire impacts on vegetation, ground cover, soils, and erosion across spatial scales at a snow-dominated mountainous sagebrush site over a 2-year period post-fire. Vegetation, ground cover, and soil conditions were assessed at various plot scales (8 m² to 3.42 ha) through standard field measures. Erosion was quantified through a network of silt fences (n = 24) spanning hillslope and side channel or swale areas, ranging from 0.003 to 3.42 ha in size. Sediment delivery at the watershed scale (129 ha) was assessed by suspended sediment samples of streamflow through a drop-box v-notch weir. Wildfire consumed nearly all above-ground live vegetation at the site and resulted in more than 60% bare ground (bare soil, ash, and rock) in the immediate post-fire period. Widespread wind-driven sediment loading of swales was observed over the first month post-fire and extensive snow drifts were formed in these swales each winter season during the study. In the first year, sediment yields from north- and south-facing aspects averaged 0.99–8.62 t ha⁻¹ at the short-hillslope scale (~0.004 ha), 0.02–1.65 t ha⁻¹ at the long-hillslope scale (0.02–0.46 ha), and 0.24–0.71 t ha⁻¹ at the swale scale (0.65–3.42 ha), and watershed scale sediment yield was 2.47 t ha⁻¹. By the second year post fire, foliar cover exceeded 120% across the site, but bare ground remained more than 60%. Sediment yield in the second year was greatly reduced across short- to long-hillslope scales (0.02–0.04 t ha⁻¹), but was similar to first-year measures for swale plots (0.24–0.61 t ha⁻¹) and at the watershed scale (3.05 t ha⁻¹). Nearly all the sediment collected across all spatial scales was delivered during runoff events associated with cold-season hydrologic processes, including rain-on-snow, rain-on-frozen soils, and snowmelt runoff. Approximately 85–99% of annual sediment collected across all silt fence plots each year was from swales. The high levels of sediment delivered across hillslope to watershed scales in this study are attributed to observed preferential loading of fine sediments into swale channels by aeolian processes in the immediate post-fire period and subsequent flushing of these sediments by runoff from cold-season hydrologic processes. Our results suggest that the interaction of aeolian and cold-season hydrologic-driven erosion processes is an important component for consideration in post-fire erosion assessment and prediction and can have profound implications for soil loss from these ecosystems. © 2019 John Wiley & Sons, Ltd.  相似文献   

New records of Ediacaran Acraman ejecta in drillholes from the Stuart Shelf and Officer Basin,South Australia     

Andrew C. Hill  Peter W. Haines  Kathleen Grey  Sebastian Willman 《Meteoritics & planetary science》2007,42(11):1883-1891

Abstract— New occurrences of the Acraman impact ejecta layer were recently discovered in two South Australian drillholes, SCYW‐79 1a (Stuart Shelf) and Munta 1 (Officer Basin) using lithostratigraphy, acritarch biostratigraphy, carbon isotope stratigraphy, and biomarker anomalies to predict the stratigraphic position. The ejecta layer is conspicuous because it consists of pink, sandsized, angular fragments of volcanic rock distributed along the bedding plane surface of green marine siltstone. In SCYW‐79 1a it forms a layer 5 mm thick; in Munta 1 the ejecta layer is thin and discontinuous because of its distance (?550 km) from the impact structure. Palynological, biomarker, and carbon isotope anomalies can now be shown to coincide with the ejecta layer in SCYW‐79 1a and Munta 1 suggesting the Acraman impact event may have had far reaching influences on the rapidly evolving Ediacaran biological and geochemical cycles.  相似文献   

The use of bromide and chloride mass ratios to differentiate salt-dissolution and formation brines in shallow groundwaters of the Western Canadian Sedimentary Basin     

James T. Freeman 《Hydrogeology Journal》2007,15(7):1377-1385

In the Western Canadian Sedimentary Basin, the petroleum industry handles two geochemically distinctive brines that are traceable in the environment: formation brines extracted along with hydrocarbons from the basin, and salt-dissolution brines, produced by dissolving deep halite formations to create caverns for petroleum product storage. The concentrations of the conservative ions chloride (Cl) and bromide (Br) in many formation brines plot closely to the seawater evaporation trajectory of previous studies. These brines contain Cl/Br mass ratios of around 300, while salt-dissolution brines are relatively Br depleted, having Cl/Br mass ratios in excess of 20,000. An oilfield site in central Alberta had experienced nearby releases of both salt-dissolution and formation brines. Geochemical mixing trends were defined by theoretically mixing samples of local salt-dissolution and formation brine sources with background shallow groundwater. Most site monitoring wells and local surface water samples plotted directly on a salt-dissolution brine dilution trend, while results from four monitoring wells, all located directly downgradient of formation brine spills, suggested the mixing of formation brines into shallow groundwater. This work indicates that there is a large-scale salt-dissolution brine plume beneath the site and reinforces the use of Cl and Br concentrations and mass ratios as environmental tracers.  相似文献   

Metrics for the comparative analysis of geospatial datasets with applications to high-resolution grid-based population data     

Aarthy Sabesan  Kathleen Abercrombie  Auroop R. Ganguly  Budhendra Bhaduri  Eddie A. Bright  Phillip R. Coleman 《GeoJournal》2007,69(1-2):81-91

Geospatial data sciences have emerged as critical requirements for high-priority application solutions in diverse areas, including, but not limited to, the mitigation of natural and man-made disasters. Three sets of metrics, adopted or customized from geo-statistics, applied meteorology and signal processing, are tested in terms of their ability to evaluate geospatial datasets, specifically two population databases commonly used for disaster preparedness and consequence management. The two high-resolution, grid-based population datasets are the following: The LandScan dataset available from the Geographic Information Science and Technology (GIST) group at the Oak Ridge National Laboratory (ORNL), and the Gridded Population of the World (GPW) dataset available from the Center for International Earth Science Information Network (CIESIN) group at Columbia University. Case studies evaluate population data across the globe, specifically, the metropolitan areas of Washington DC, USA, Los-Angeles, USA, and Houston, USA, and London, UK, as well as the country of Iran. The geospatial metrics confirm that the two population datasets have significant differences, especially in the context of their utility for disaster readiness and mitigation. While this paper primarily focuses on grid based population datasets and disaster management applications, the sets of metrics developed here can be generalized to other geospatial datasets and applications. Future research needs to develop metrics for geospatial and temporal risks and associated uncertainties in the context of disaster management. The U. S. Government’s right to retain a non-exclusive, royalty-free license in and to any copyright is acknowledged.  相似文献