Lipids of marine Archaea: Patterns and provenance in the water-column and sediments   总被引：1，自引：0，他引：1  

Courtney Turich  Katherine H. Freeman  Maureen Conte  Stuart G. Wakeham 《Geochimica et cosmochimica acta》2007,71(13):3272-3291

We measured archaeal lipid distributions from globally distributed samples of freshwater, marine, and hypersaline suspended particulate matter. Cluster analysis of relative lipid distributions identified four distinct groups, including: (1) marine epipelagic (<100 m) waters, (2) marine mesopelagic (200-1500 m) and upwelling waters, (3) freshwater/estuarine waters, and (4) hypersaline waters. A pronounced difference in lipid composition patterns is the near absence of ring-containing glycerol dialkyl glycerol tetraethers (GDGTs) at high salinity. Different archaeal communities populate marine (mesophilic Crenarchaeota and Euryarchaeota), and hypersaline environments (halophilic Euryarchaeota) and community shifts can regulate differences in lipid patterns between marine and hypersaline waters. We propose that community changes within meosphilic marine Archaea also regulate the lipid patterns distinguishing epipelagic and mesopelagic/upwelling zones. Changes in the relative amounts of crenarchaeol and caldarchaeol and low relative abundances of ringed structures in surface waters differentiate lipids from the epipelagic and mesopelagic/upwelling waters. Patterns of lipids in mesopelagic (and upwelling) waters are similar to those expected of the ammonia-oxidizing Group I Crenarchaeota, with predominance of crenarchaeol and abundant cyclic GDGTs; non-metric multidimensional analysis (NMDS) shows this pattern is associated with high nitrate concentrations. In contrast, limited culture evidence indicates marine Group II Euryarchaeota may be capable of producing mainly caldarchaeol and some, but not all, of the ringed GDGTs and we suggest that these organisms, along with the Crenarchaeota, contribute to lipids in epipelagic marine waters. Calculated TEX₈₆ temperatures in mesopelagic samples (reported here and in published data sets) are always much warmer than measured in situ temperatures. We propose lipids used in the temperature proxy derive from both Euryarchaeaota and Crenarchaeota, and observed values of TEX₈₆ are subject to changes in their ecology as influenced by nutrient fluctuations or other perturbations. Applications of published core-top TEX₈₆-SST correlations require that (1) the surface waters are always composed of similar communities with the same temperature response and (2) that deeper water GDGT production is not transported to the sediments. Our lipid distribution patterns demonstrate both surface-water archaeal community differences (which accompany greater nutrient influxes, shoaling of mesopelagic Crenarchaeota during upwelling periods, and possibly due to an influx of terrestrial Archaea), and changes in organic matter transport through the water column can affect the distribution of lipids recorded in sediments. We therefore suggest that reported temperature shifts in ancient applications indicate TEX₈₆ lipids recorded not only temperature changes, but also changes in archaeal ecology, nutrient concentrations, and possibly oceanographic conditions.  相似文献   

I/I ratios in surface waters of the English Lake District     

M. Atarashi-Andoh  C. Schnabel  G. Cook  A.B. MacKenzie  A. Dougans  R.M. Ellam  S. Freeman  C. Maden  V. Olive  H.-A. Synal  S. Xu 《Applied Geochemistry》2007

Accelerator Mass Spectrometry (AMS) was used to measure ¹²⁹I/¹²⁷I ratios in surface sea, lake, and river water samples collected in 2004 and 2005 from the English Lake District and from SW Scotland, areas which are in relatively close proximity to the Sellafield nuclear fuel reprocessing plant in NW England. The ¹²⁹I/¹²⁷I ratios in surface water collected from the shore of the Irish Sea were in the range 2.8 × 10⁻⁶ to 8.2 × 10⁻⁶. These ratios are one order of magnitude higher than that of seawater collected from the Irish Sea in 1992, correlating with the increase in ¹²⁹I content of the Sellafield liquid effluent discharge over the last decade. The ¹²⁹I/¹²⁷I ratios in lakes in the Lake District were in the range 0.7 × 10⁻⁶ to 6.4 × 10⁻⁶ and decreased exponentially as a function of distance from Sellafield. Consideration of the relative variation of stable I concentrations and ¹²⁹I/¹²⁷I ratios suggests that Sellafield gaseous discharges may be the dominant source of ¹²⁹I to the lakes.  相似文献   

Cosmic-ray exposure age of Martian meteorite GRV 99027     

Kong Ping  D. Fabel  R. Brown  S. Freeman 《中国科学D辑(英文版)》2007,50(10):1521-1524

We have determined the concentrations of 10Be and 26Al in GRV 99027 recovered by the 16th Chinese Antarctic expedition team, which are 14.1 ± 0.6 dpm/kg and 67.5 ± 3.4 dpm/kg, respectively. From the concentration of 10Be, we calculate a cosmic-ray exposure age of 4.4 ± 0.6 Ma for GRV 99027. The concentration of 26Al is too high compared to the 10Be exposure age, indicating extra production from solar ray. The exposure ages, petrologic and geochemical characteristics of mantle-derived Martian meteorites GRV 99027, LEW 88516, Y-793605, NWA 1950 and ALHA77005 are very similar, suggesting that these meteorites most probably were ejected from Mars in the same impact event.  相似文献   

Monitoring Changes of Ice Streams Using Time Series of Satellite-Altimetry-Based Digital Terrain Models     

Ute C. Herzfeld  Craig S. Lingle  Cecily Freeman  Chris A. Higginson  Michael P. Lambert  Li-Her Lee  Vera A. Voronina 《Mathematical Geology》1997,29(7):859-890

The Antarctic Ice Sheet plays a major role in the global system, and the large ice streams discharging into the circumpolar sea represent its gateways to the world's oceans. Satellite radar altimeter data provide an opportunity for mapping surface elevation at kilometer-resolution with meter-accuracy. Geostatistical methods have been developed for the analysis of these data. Applications to Seasat data and data from the Geosat Exact Repeat Mission indicate that the grounding line of Lambert Glacier/Amery Ice Shelf, the largest ice stream in East Antarctica, has advanced 10–12 km between 1978 and 1987–89. The objectives of this paper are to explore possibilities and limitations of satellite-altimetry-based mapping to capture changes for shorter time windows and for smaller areas, and to investigate some methodological aspects of the data analysis. We establish that one season of radar altimeter data is sufficient for constructing a map. This allows study of interannual variation and is the key for a time-series analysis approach to study changes in ice streams. Maps of the lower Lambert Glacier and the entire Amery Ice Shelf are presented for austral winters 1978, 1987, 1988, and 1989. As a first step toward understanding the dynamics of the ice-stream/ice-shelf system, elevation changes are calculated for grounded ice, the grounding zone, and floating ice. In the absence of (sufficient) surface gravity control for the Lambert Glacier/Amery Ice Shelf area, altimetry-based maps may facilitate improvement of geoid models as they provide constraints on the terrain correction in the inverse gravimetric problem.  相似文献   

Ranking and Winnowing Gross Earth Data for Inversion and Resolution     

Freeman Gilbert 《Geophysical Journal International》1971,23(1):125-128

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Infrared spectroscopy of interplanetary dust in the laboratory     

P. Fraundorf  R.I. Patel  J.J. Freeman 《Icarus》1981,47(3):368-380

Diagnostic infrared spectra of individual nanogram-sized interplanetary dust particles (IDPs) collected in the Earth's stratosphere have been obtained. A mount containing three crushed “chondritic” IDPs shows features near 1000 and 500 cm^?1, suggestive of crystalline pyroxene, and different from those of crystalline olivine, amorphous olivine, or meteoritic clay minerals. The structural diversity of chondritic IDPs and possible effects of atmospheric heating must be considered when comparing this spectrum with astrophysical spectra of interplanetary and cometary dust. Transmission electron microscope (TEM) and infrared observations are also reported on one member of the rare subset of IDPs which resemble hydrated carbonaceous chondrite matrix material. The infrared spectrum of this particle between 4000 and 400 cm^?1 closely matches that of the C2 meteorite Murchison. TEM observations suggest that this class of particles might serve as a thermometer for the process of heating on atmospheric entry.  相似文献   

Aspects of Proterozoic stromatolite biostratigraphy in Western Australia     

Kathleen Grey 《Precambrian Research》1982,18(4):347-365

Stromatolites are abundant at many horizons in the Proterozoic of Western Australia. Recent advances in knowledge of Proterozoic stratigraphy of the state have provided a more detailed framework for interpreting the stromatolite data than has been available previously. In the 1.7 Ga Earaheedy Group of the Nabberu Basin a characteristic stromatolite assemblage occurs, and within the basin a biostratigraphic succession can be recognized. The assemblage contains several new forms which belong to new groups. The need to erect new groups for these early Proterozoic stromatolites is in agreement with recent studies in Canada, northern Europe and South Africa, and suggests that the problem of ‘younger’ or late Proterozoic stromatolite groups in early Proterozoic rocks mentioned by previous workers is a result of a lack of rigour in defining taxa. Examination of type material is necessary to determine how closely the Earaheedy forms resemble those described from these other regions.In Western Australia some stromatolite forms have a restricted vertical range and similar taxa occur in beds of approximately the same age in widely-separated areas: e.g. Kimberley Group and Earaheedy Group; Scorpion Group and Limbunya, Birrindudu, McArthur, Mt. Rigg and Mt. Albert Groups and Bungle Bungle Dolomite; Tolmer and Bullita Groups; Moora and Bangemall Groups; Kai Ki Beds, Louisa Downs, Mount House and Albert Edward Groups.Stromatolite diversity shows a decline in the number of taxa at about 1.1. Ga in the Bangemall Group. More data are required to determine whether this decline is universal or specific to the Bangemall Group. This study indicates that a stromatolite biostratigraphy for Western Australia is feasible and is consistent with data from other parts of Australia. Thus emphasis on correlation should be placed on the stromatolite form rather than the group, and intercontinental correlations should be attempted only when local biostratigraphic schemes have been firmly established.  相似文献   

Some Asymptotic Properties of the Normal Modes of the Earth     

Freeman Gilbert 《Geophysical Journal International》1975,43(3):1007-1011

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The galilean satellites and the Jovian magnetic field     

John W. Freeman 《Earth, Moon, and Planets》1978,18(3):325-326

Alfvén and Arrhenius have proposed that satellites may form from the condensation of plasma suspended in the dipole magnetic field of a central body. Further, they predict that the condensed material will appear at an orbit distance of two-thirds the distance of the plasma. Recent spacecraft measurements have defined the radial extent of the stable quasi-dipole Jovian magnetic field. In support of the Alfvén and Arrhenius hypothesis, we note that all the Galilean satellites lie within two-thirds of this distance.Paper dedicated to Professor Hannes Alfvén on the occasion of his 70th birthday, 30 May 1978.  相似文献   

Oxyanion Concentrations in Eastern Sierra Nevada Rivers – 3. Boron, Molybdenum, Vanadium, and Tungsten     

Kevin H. Johannesson  W. Berry Lyons  Elizabeth Y. Graham  Kathleen A. Welch 《Aquatic Geochemistry》2000,6(1):19-46

Water samples were collected from 10 locations along the Truckee River system, 14 locations along the Walker River system, and 12 locations along the Carson River, and analyzed for B, Mo, V, W, Na, Cl, and pH. Boron concentrations ranged from approximately 2 mol/kg in the upper reaches of the Truckee River to almost 1,200 mol/kg in Pyramid Lake. Molybdenum, V, and W had concentrations in the nanomolal range; Mo varied from a low of about 12 nmol/kg to a high of 3,200 nmol/kg (Walker Lake); V ranged from 9 nmol/kg to approximately 470 nmol/kg; and W varied from a low value around 0.8 nmol/kg (West Walker River) to 1,030 nmol/kg. The high concentrations of these oxyanion-forming trace elements in the rivers reflects (1) the relative stability of these oxyanions (e.g., MoO₄ ^2-, HVO₄ ^2-, WO₄ ^2-, B(OH)₃, and/or B(OH)₄ ^-) in the alkaline, well oxygenated river and lake waters, (2) contributions of hydrothermal waters (especially for B), and (3) weathering of rocks/regolith with high concentrations of these elements. In the case of Mo, V, and W, each exhibited relatively conservative behavior in the upper, oxygenated reaches of all three rivers. During the study period the region experienced a prolonged drought such that the lower reaches of each river were typified by no flow or stagnant waters and probably low oxygen and/or anoxic conditions (although not measured). Reductive processes occurring in the low flow to stagnant reaches of each river could have led to removal of Mo, V, and W from solution as coprecipitates with Fe monosulfides, or via sorption to Fe oxides/oxyhydroxides and/or organic matter. Boron, however, exhibited essentially no or minor removal from these rivers, and instead was added to each river via B-rich hydrothermal waters (e.g., Steamboat Creek from Steamboat Hot Springs), or by B-rich groundwaters via base-flow during the extensive drought.  相似文献