Hydrogen isotope ratios of leaf wax n-alkanes in grasses are insensitive to transpiration     

Francesca A. McInerney  Brent R. Helliker  Katherine H. Freeman 《Geochimica et cosmochimica acta》2011,75(2):541-554

We analyzed hydrogen isotope ratios of high-molecular weight n-alkanes (δD_l) and oxygen isotope ratios of α-cellulose (δ¹⁸O_C) for C₃ and C₄ grasses grown in the field and in controlled-environment growth chambers. The relatively firm understanding of ¹⁸O-enrichment in leaf water and α-cellulose was used to elucidate fractionation patterns of δD_l signatures. In the different relative humidity environments of the growth chambers, we observed clear and predictable effects of leaf-water enrichment on δ¹⁸O_C values. Using a Craig-Gordon model, we demonstrate that leaf water in the growth chamber grasses should have experienced significant D-enriched due to transpiration. Nonetheless, we found no effect of transpirational D-enrichment on the δD_l values. In field samples, we saw clear evidence of enrichment (correlating with relative humidity of the field sites) in both δ¹⁸O_C and δD_l. These seemingly contrasting results could be explained if leaf waxes are synthesized in an environment that is isotopically similar to water entering plant roots due to either temporal or spatial isolation from evaporatively enriched leaf waters. For grasses in the controlled environment, there was no enrichment of source water, whereas enrichment of grass source water via evaporation from soils and/or stems was likely for grass samples grown in the field.Based on these results, evaporation from soils and/or stems appears to affect δD_l, but transpiration from leaves does not. Further evidence for this conclusion is found in modeling expected net evapotranspirational enrichment. A Craig-Gordon model applied to each of the field sites yields leaf water oxygen isotope ratios that can be used to accurately predict the observed δ¹⁸O_C values. In contrast, the calculated leaf water hydrogen isotope ratios are more enriched than what is required to predict observed δD_l values. These calculations lend support to the conclusion that while δ¹⁸O_C reflects both soil evaporation and transpiration, δD_l appears to only record evaporation from soils and/or stems. Therefore, the δD of n-alkanes can likely be used to reconstruct the δD of water entering a leaf, supporting the soil-enrichment model of Smith and Freeman (2006). In both the field and controlled studies, we found significant photosynthetic pathway effects on n-alkane δD suggesting that biochemical pathways or plant phylogeny have a greater effect on leaf wax δD than leaf-water enrichment in grasses.  相似文献   

Clues from Current High CO2 Environments on the Effects of Ocean Acidification on CaCO3 Preservation     

Andreas J. Andersson  Nicholas R. Bates  Marlene A. Jeffries  Kyra Freeman  Charles Davidson  Shaun Stringer  Evan Betzler  Fred T. Mackenzie 《Aquatic Geochemistry》2013,19(5-6):353-369

Acidification of surface seawater owing to anthropogenic activities has raised serious concerns on its consequences for marine calcifying organisms and ecosystems. To acquire knowledge concerning the future consequences of ocean acidification (OA), researchers have relied on incubation experiments with organisms exposed to future seawater conditions, numerical models, evidence from the geological record, and recently, observations from aquatic environments exposed to naturally high CO₂ and low pH, e.g., owing to volcanic CO₂ vents, upwelling, and groundwater input. In the present study, we briefly evaluate the distribution of dissolved CO₂–carbonic acid parameters at (1) two locations in the Pacific and the Atlantic Ocean as a function of depth, (2) a mangrove environment in Bermuda, (3) a seasonally stratified body of water in a semi-enclosed sound in Bermuda, and (4) in temporarily isolated tide pools in Southern California. We demonstrate that current in situ conditions of seawater pCO₂, pH, and CaCO₃ saturation state (Ω) in these environments are similar or even exceed the anticipated changes to these parameters in the open ocean over the next century as a result of OA. The observed differences between the Pacific and Atlantic Oceans with respect to seawater CO₂–carbonic acid chemistry, preservation of CaCO₃ minerals, and the occurrence and distribution of deep-sea marine calcifiers, support the hypothesized negative effects of OA on the production and preservation of CaCO₃ in surface seawater. Clues provided from shallow near-shore environments in Bermuda and Southern California support these predictions, but also highlight that many marine calcifiers already experience relatively high seawater pCO₂ and low pH conditions.  相似文献   

Physical sedimentology experiments with sulfuric acid solutions: Implications for Mars?     

Kathleen C. Benison  Deidre LaClair  Jessica Walker   《Earth and Planetary Science Letters》2008,270(3-4):330-337

Physical sedimentology experiments have shown that sulfuric acid solutions may have formed some surface features seen on Mars. Recent data returned from Mars show the presence of jarosite, sulfate salts, hematite, phyllosilicates, and opaline silica, all of which precipitate from some terrestrial sulfuric acid solutions. There is a plethora of geochemical, mineralogical, and sedimentological data indicative of past sulfuric acid systems on Mars, but there has never been a comprehensive study published regarding sulfuric acid as a physical sedimentological agent. In the laboratory, we ran liquids of various compositions over sediments in order to test how these liquids entrain, transport, and deposit sediments. Pure water and concentrated sulfuric acid solutions produced the same general features, such as channels, gullies, and alluvial fans. However, sulfuric acid solutions yielded some distinct sedimentary features not produced by pure water runs. These features, narrow, deeply incised channels of consistent widths, rounded discrete fans, and air bubble “craters”, are similar to some Martian landscape features. These experimental results indicate that acid solutions should be considered a possible sedimentological agent on Mars.  相似文献   

Volcanic tsunamis and prehistoric cultural transitions in Cook Inlet,Alaska     

James Begét  Cynthia Gardner  Kathleen Davis 《Journal of Volcanology and Geothermal Research》2008

The 1883 eruption of Augustine Volcano produced a tsunami when a debris avalanche traveled into the waters of Cook Inlet. Older debris avalanches and coeval paleotsunami deposits from sites around Cook Inlet record several older volcanic tsunamis. A debris avalanche into the sea on the west side of Augustine Island ca. 450 years ago produced a wave that affected areas 17 m above high tide on Augustine Island. A large volcanic tsunami was generated by a debris avalanche on the east side of Augustine Island ca. 1600 yr BP, and affected areas more than 7 m above high tide at distances of 80 km from the volcano on the Kenai Peninsula. A tsunami deposit dated to ca. 3600 yr BP is tentatively correlated with a southward directed collapse of the summit of Redoubt Volcano, although little is known about the magnitude of the tsunami. The 1600 yr BP tsunami from Augustine Volcano occurred about the same time as the collapse of the well-developed Kachemak culture in the southern Cook Inlet area, suggesting a link between volcanic tsunamis and prehistoric cultural changes in this region of Alaska.  相似文献   

The whaling issue: [Marine Policy 2000;24(3):179–91]     

William Aron  William Burke  Milton M.R. Freeman 《Marine Policy》2000,24(6):501

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Determination of structure coefficients from splitting matrices     

Freeman Gilbert  & John H. Woodhouse 《Geophysical Journal International》2000,142(1):1-3

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Distribution of deep near-inertial waves observed in the Kuroshio Extension     

Jae-Hun Park  Kathleen A. Donohue  D. Randolph Watts  Luc Rainville 《Journal of Oceanography》2010,66(5):709-717

The distribution of deep near-inertial waves (NIWs) is investigated using data mainly from an array of 46 near-bottom acoustic current meter sensors spanning a 600 km × 600 km region as part of the Kuroshio Extension System Study during 2004–2006. The deep NIW distribution is interpreted in the context of both upper-layer and near-bottom mapped circulations. The wintertime-mean mixed-layer NIW energy input, modeled from observed wind stress, has the same range of values north and south of the Kuroshio Extension in this region. Yet, the wintertime-mean deep NIW energy distribution reveals a sharp factor-of-5 decrease from north to south of the Kuroshio jet. This direct observational evidence shows that the Kuroshio Extension blocks the equatorward propagation of NIWs. The NIW energy that does reach the sea floor within the subset of wintertime observations in the subtropical gyre arrives with patchy spatial and temporal distribution. Elevated NIW energy in deep water is associated with anticyclones in the deep barotropic flow and unassociated with upper layer eddies.  相似文献   

Out of new stocks in 2020: A comment on “Not all fisheries will be collapsed in 2048”     

Rainer Froese  Amanda Stern-Pirlot  Kathleen Kesner-Reyes 《Marine Policy》2009

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High resolution absorption cross-section measurements of ozone at 195 K in the wavelength region 240–350 nm     

D.E. Freeman  K. Yoshino  J.R. Esmond  W.H. Parkinson 《Planetary and Space Science》1984,32(2):239-248

Cross-sections of the Hartley-Huggins bands of 03 at the temperature 195 K have been obtained from photoabsorption measurements at column densities in the range 2 × 10¹⁷?1 × 10²¹ cm^?2 throughout the wavelength region 240–350 nm with a 6.65 m photoelectric scanning spectrometer equipped with a 2400 lines mm^?1 grating and operated at an instrumental width (FWHM) of 0.003 nm. The assumptions made in putting the measured relative cross-sections on an absolute basis are discussed. Fine structure in the cross-section observed in the Huggins bands is illustrated in the region 323–327 nm where shallow features of width 0.01–0.02 nm occur superposed on a stronger apparent continuum exhibiting broader wavy structure.  相似文献   

Automatic change detection in lane-level road networks using GPS trajectories   总被引：1，自引：0，他引：1  

Xue Yang  Kathleen Stewart  Zhen Dong  Xia Zhang  Qingquan Li 《International journal of geographical information science》2018,32(3):601-621

Lane-level road network updating is crucial for urban traffic applications that use geographic information systems contributing to, for example, intelligent driving, route planning and traffic control. Researchers have developed various algorithms to update road networks using sensor data, such as high-definition images or GPS data; however, approaches that involve change detection for road networks at lane level using GPS data are less common. This paper presents a novel method for automatic change detection of lane-level road networks based on GPS trajectories of vehicles. The proposed method includes two steps: map matching at lane level and lane-level change recognition. To integrate the most up-to-date GPS data with a lane-level road network, this research uses a fuzzy logic road network matching method. The proposed map-matching method starts with a confirmation of candidate lane-level road segments that use error ellipses derived from the GPS data, and then computes the membership degree between GPS data and candidate lane-level segments. The GPS trajectory data is classified into successful or unsuccessful matches using a set of defuzzification rules. Any topological and geometrical changes to road networks are detected by analysing the two kinds of matching results and comparing their relationships with the original road network. Change detection results for road networks in Wuhan, China using collected GPS trajectories show that these methods can be successfully applied to detect lane-level road changes including added lanes, closed lanes and lane-changing and turning rules, while achieving a robust detection precision of above 80%.  相似文献