Zinc mobility and speciation in soil covered by contaminated dredged sediment using micrometer-scale and bulk-averaging X-ray fluorescence, absorption and diffraction techniques     

Marie-Pierre Isaure  Alain Manceau  Nicolas Geoffroy  Nobumichi Tamura 《Geochimica et cosmochimica acta》2005,69(5):1173-1198

The mobility and solid-state speciation of zinc in a pseudogley soil (pH = 8.2-8.3) before and after contamination by land-disposition of a dredged sediment ([Zn] = 6600 mg kg⁻¹) affected by smelter operations were studied in a 50 m² pilot-scale test site and the laboratory using state-of-the-art synchrotron-based techniques. Sediment disposition on land caused the migration of micrometer-sized, smelter-related, sphalerite (ZnS) and franklinite (ZnFe₂O₄) grains and dissolved Zn from the sediment downwards to a soil depth of 20 cm over a period of 18 months. Gravitational movement of fine-grained metal contaminants probably occurred continuously, while peaks of Zn leaching were observed in the summer when the oxidative dissolution of ZnS was favored by non-flooding conditions. The Zn concentration in the <50 μm soil fraction increased from ∼61 ppm to ∼94 ppm in the first 12 months at 0-10 cm depth, and to ∼269 ppm in the first 15 months following the sediment deposition. Higher Zn concentrations and enrichments were observed in the fine (<2 μm) and very fine (<0.2 μm) fractions after 15 months (480 mg kg⁻¹ and 1000 mg kg⁻¹, respectively), compared to 200 mg kg⁻¹ in the <2 μm fraction of the initial soil. In total, 1.2% of the Zn initially present in the sediment was released to the environment after 15 months, representing an integrated quantity of ∼4 kg Zn over an area of 50 m². Microfocused X-ray fluorescence (XRF), diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) spectroscopy techniques were used to image chemical associations of Zn with Fe and Mn, and to identify mineral and Zn species in selected points-of-interest in the uncontaminated and contaminated soil. Bulk average powder EXAFS spectroscopy was used to quantify the proportion of each Zn species in the soil. In the uncontaminated soil, Zn is largely speciated as Zn-containing phyllosilicate, and to a minor extent as zincochromite (ZnCr₂O₄), ^IVZn-sorbed turbostratic birnessite (δ-MnO₂), and Zn-substituted goethite. In the upper 0-10 cm of the contaminated soil, ∼60 ± 10% of total Zn is present as ZnS inherited from the overlying sediment. Poorly-crystalline Zn-sorbed Fe (oxyhydr)oxides and zinciferous phyllosilicate amount to ∼20-30 ± 10% each and, therefore, make up most of the remaining Zn. Smaller amounts of franklinite (ZnFe₂O₄), Zn-birnessite and Zn-goethite were also detected. Further solubilization of the Zn inventory in the sediment, and also remobilization of Zn from the poorly-crystalline neoformed Fe (oxyhydr)oxide precipitates, are expected over time. This study shows that land deposition of contaminated dredged sediments is a source of Zn for the covered soil and, consequently, presents environmental hazards. Remediation technologies should be devised to either sequester Zn into sparingly soluble crystalline phases, or remove Zn by collecting leachates beneath the sediment.  相似文献   

Geochemical Features and Tectonic Setting of Greenstones from Kunimiyama, Northern Chichibu Belt, Central Shikoku, Japan     

Tatsuo Nozaki    Kentaro Nakamura  Hiroshi Osawa    Koichiro Fujinaga  Yasuhiro Kato 《Resource Geology》2005,55(4):301-310

Abstract. We report whole‐rock chemical data for the greenstones from the Kunimiyama area in the Northern Chichibu Belt and their implications on the tectonic setting of these rocks. The Kunimiyama greenstones are associated with stratiform fer‐romanganese deposits or bedded cherts in the northern part of the study area, but are closely associated with a thick limestone block or bedded cherts in the southern part. The constituent minerals of greenstones are albitized plagioclase, clinopy‐roxene, chlorite, calcite, epidote, pumpellyite, prehnite, quartz, celadonite, sericite and opaque minerals such as iron oxyhy‐droxide and hematite. These mineral assemblages, epidote + pumpellyite + chlorite and chlorite + pumpellyite + prehnite, suggest that the metamorphic grade of greenstones from the Kunimiyama area is prehnite‐pumpellyite facies. The whole‐rock chemical compositions of greenstones associated with ferromanganese deposits are generally similar to those of normal mid‐ocean ridge basalt (N‐MORB). In contrast, the chemical compositions of the greenstones associated with the limestone block are comparable to those of ocean island alkaline basalt. Greenstones associated with bedded cherts are of enriched MORB and ocean island basalt, as well as N‐MORB origins, suggesting they probably formed as a result of plume‐related MOR volcanism in the Panthalassa Ocean in Early Permian and by tectonic mixing of ocean island basalts with oceanic ridge crustal fragments during accretion/subduction processes. These geological and geochemical lines of evidence suggest that the Kunimiyama greenstones are allochthonous blocks of accreted oceanic crust and seamounts. The ferromanganese deposits are frequently accompanied by reddish greenstones. Compared to common greenish greenstones, the reddish greenstones are characterized by high MnO and rare earth element contents and distinct negative Ce anomalies, implying a slight contribution of hydro thermal component forming the ferromanganese deposits.  相似文献   

A Simple Method for Precise Determination of 23 Trace Elements in Granitic Rocks by ICP-MS after Lithium Tetraborate Fusion   总被引：1，自引：0，他引：1  

Shunsaku Awaji    Kentaro Nakamura  Tatsuo Nozaki  Yasuhiro Kato 《Resource Geology》2006,56(4):471-478

Abstract. An improved alkali fusion method followed by HF-HNO₃-HC1O₄ treatment is performed for simultaneous determination of 23 trace elements (Sr, Y, Zr, Nb, Ba, Hf, Ta, Th, U, and REE) by ICP-MS in rock reference materials: basaltic rocks (JB-2, JB-3) and granitic rocks (JG-la, JG-2, JG-3). Our improved method offers several advantages including: (1) suppression of whitish precipitates probably composed of insoluble fluorides by addition of HCIO4, (2) simple and reliable preparation procedure, (3) instrument calibration which enables straightforward simultaneous multi-elemental analysis, and (4) the very low background levels by using pure lithium tetraborate flux. We obtained the analytical results with a reproducibility of mostly <2 % (1) for the basaltic rocks and <7 % for the granitic rocks. The higher relative standard deviation (RSD) values for granitic rocks may be attributed to sample heterogeneity of coarse-grained granitic rocks. The analytical results of the granitic rocks demonstrate that Zr and Hf abundances are consistent with the compiled values and that REE concentrations agree well with recently published data, suggesting that the Li₂B₄O₇ fusion method applied in the present study is suitable for the analysis of the granitic rocks.  相似文献   

Whole-rock Geochemistry of Basic Schists from the Besshi Area, Central Shikoku: Implications for the Tectonic Setting of the Besshi Sulfide Deposit     

Tatsuo Nozaki    Kentaro Nakamura  Shunsaku Awaji  Yasuhiro Kato 《Resource Geology》2006,56(4):423-432

Abstract. Whole-rock chemical compositions of the Besshi basic schist closely associated with the Besshi massive sulfide deposit from the Sanbagawa Belt are reported. Studied samples were collected from four outcrops around the Dozan-goe, central Shikoku. Common metamorphic mineral assemblage of the basic schist is albite + epidote + actinolite + chlorite ± muscovite ± quartz. Major element contents are similar to those of typical tholeiitic basalts. Trace element patterns of the basic schist normalized to normal mid-ocean ridge basalt (N-MORB) are generally flat, although concentrations of highly mobile large-ion lithophile elements are quite variable. Chondrite-normalized rare earth element (REE) patterns are flat to slightly light REE-depleted patterns. In the Hf-Th-Ta and Nb-Zr-Y discrimination diagrams, basic schist samples closely associated with the sulfide deposit are plotted within the N-MORB field. The Th/Nb ratios of the basic schist are also comparable to those of N-MORB. These geo-chemical lines of evidence indicate that the protolith of the Besshi basic schist is N-MORB and the Besshi sulfide deposit was formed by hydrothermal activity in conjunction with MOR volcanism.  相似文献   

Precise Determination of Ultra-Low (sub-ng g^-1) Level Rare Earth Elements in Ultramafic Rocks by Quadrupole ICP-MS     

Kentaro Nakamura  Qing Chang 《Geostandards and Geoanalytical Research》2007,31(3):185-197

We present a new method that determines precisely and accurately rare earth elements (REE) at the sub-ng g^-1 level in ultramafic rocks based on acid dissolution and quadrupole ICP-MS with systematic interference corrections on each sample. The method is demonstrated by analyses of the international geochemical reference materials, PCC-1 (peridotite), DTS-1 (dunite) and DTS-2 (dunite) provided by the United States Geological Survey (USGS), and JP-1 (peridotite) issued by the Geological Survey of Japan (GSJ). Detection limits, as rock equivalent, were calculated to be 0.01-0.08 ng g^-1 for our instrument, which is sufficiently low compared to the REE concentrations of ultramafic rocks. In addition, procedural blanks of the proposed method were 0.2-5 pg, which is negligible even for the ultra-low level REE determinations. Reproducibility obtained from separate dissolutions and measurements of USGS DTS-2 and GSJ JP-1 was 3-6%, which corresponds to the high-precision data obtained by ID-TIMS or magnetic sector field ICP-MS with a desolvating nebuliser. The REE data determined exhibit smooth chondrite-normalised REE patterns for all of the tested geochemical reference materials, and the abundances are in good agreement with recently published data.  相似文献   

Damage to buildings and structures due to recent devastating wind hazards in East Asia   总被引：1，自引：0，他引：1  

Qingshan Yang  Rong Gao  Fan Bai  Tian Li  Yukio Tamura 《Natural Hazards》2018,92(3):1321-1353

Extreme wind events such as typhoons and tornadoes can cause devastating damage to structures and huge losses to human societies. This paper introduces recent devastating wind-related disasters in East Asia, including disasters in Japan, the Philippines and China, from 2013 to 2016. In particular, it describes several post-disaster investigations including those on Typhoon Haiyan in 2013 in the Philippines; typhoon Mujigae and two typhoon-associated tornadoes in October, 2015, in Guangdong, China; and a tornado in June, 2016 in Yancheng, China. Meteorological features, damage details and failure mechanisms of structures, factors related to damage generation and spread, scales to evaluate storms, estimations of tornado wind speeds and so on are discussed, with the aim of mitigating future wind-related disasters and to create safer and sustainable societies. Lessons derived from aerodynamic effects, cladding and component performances, debris impacts, building arrangements, fatigue effects, construction methods, etc. together with suggestions for wind-resistant design of buildings are given.  相似文献   

Primary productivity in the fast ice area near syowa station,Antarctica, during spring and summer 1983/84     

Hiroo Satoh  Kentaro Watanabe 《Journal of Oceanography》1988,44(6):287-292

In situ measurements of the primary productivity of ice algae and phytoplankton were carried out in the fast ice area near Syowa Station (69°00S, 39°35E) during the austral spring and summer of 1983/84. Standing stock of ice algae reached a maximum of 45.1 mg chla m^–2 in late October. Phytoplankton standing stock attained a value of 3.57 mg chla m^–2 in mid-January. Primary production of ice algae in late October (7.64 mgC m^–2 hr^–1) was 14 times greater than that in mid-January (0.54 mgC m^–2 hr^–1). Production in the water column in mid-January (3.46 mgC m^–2 hr^–1) was 50 times greater than that in late October (0.07 mgC m^–2 hr^–1). These results indicate a substantial production by ice algae in the spring and by phytoplankton in the summer period.  相似文献   

Two Modes of Salinity and Temperature Variation in the Surface Layer of the Pacific Warm Pool     

Kentaro Ando  Yoshifumi Kuroda 《Journal of Oceanography》2002,58(4):599-609

The characteristics of temperature and salinity variation in the Pacific warm pool were investigated using Empirical Orthogonal Function (EOF) analysis on one year's temperature and salinity data in the surface layer (0–50 m) obtained from the Triangle Trans-Ocean Buoy Network (TRITON) buoy array. Two dominant modes of surface temperature and salinity variation were found. One is a positive correlation mode where temperature and salinity were scattered almost parallel to isopycnal lines in a T-S diagram, which has little effect on the density field. The other is a negative correlation mode where temperature and salinity were distributed across isopycnal lines, which has a substantial impact on the density field. In particular, we found that the negative correlation mode at 5°N, 156°E was predominant on a seasonal time scale and contributed to the surface dynamic height variation, and therefore to surface geostrophic current. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Pre-Japan-ARGO: Experimental Observation of Upper and Middle Layers South of the Kuroshio Extension Region Using Profiling Floats     

Naoto Iwasaka  Toshio Suga  Kensuke Takeuchi  Keisuke Mizuno  Yasushi Takatsuki  Kentaro Ando  Taiyo Kobayashi  Eitarou Oka  Yasuko Ichikawa  Motoki Miyazaki  Hiroshi Matsuura  Kenji Izawa  Chan-Su Yang  Nobuyuki Shikama  Momoko Aoshima 《Journal of Oceanography》2003,59(1):119-127

We deployed two profiling floats in the region south of the Kuroshio Extension in March 2000. Temperature and salinity profiles from a depth of 1500 × 10⁴ Pa to the surface are reported every two and four weeks, respectively. The floats performed very well for first four months after deployment. Later they failed in surfacing for a few months when the sea surface temperature in the region was high. The salinity sensors seemed to suffer from some damage during their failure-in-surfacing period. Despite this trouble, the results clearly demonstrate that the profiling float is a very useful and cost-effective tool for physical oceanographic observation in the open sea. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Morphology and tectonics of the Yap Trench   总被引：5，自引：0，他引：5  

Fujiwara  Toshiya  Tamura  Chiori  Nishizawa  Azusa  Fujioka  Kantaro  Kobayashi  Kazuo  Iwabuchi  Yo 《Marine Geophysical Researches》2000,21(1-2):69-86

We conducted swath bathymetry and gravity surveys the whole-length of the Yap Trench, lying on the southeastern boundary of the Philippine Sea Plate. These surveys provided a detailed morphology and substantial insight into the tectonics of this area subsequent the Caroline Ridge colliding with this trench. Horst and graben structures and other indications of normal faulting were observed in the sea-ward trench seafloor, suggesting bending of the subducting oceanic plate. Major two slope breaks were commonly observed in the arc-ward trench slope. The origin of these slope breaks is thought to be thrust faults and lithological boundaries. No flat lying layered sediments were found in the trench axis. These morphological characteristics suggest that the trench is tectonically active and that subduction is presently occurring. Negative peaks of Bouguer anomalies were observed over the arc-ward trench slope. This indicates that the crust is thickest beneath the arc-ward trench slope because the crustal layers on the convergent two plates overlap. Bouguer gravity anomalies over the northern portion of the Yap Arc are positive. These gravity signals show that the Yap Arc is uplifted by dynamic force, even though dense crustal layers underlie the arc. This overlying high density arc possibly forces the trench to have great water depths of nearly 9000 m. We propose a tectonic evolution of the trench. Subduction along the Yap Trench has continued with very slow rates of convergence, although the cessation of volcanism at the Yap Arc was contemporaneous with collision of the Caroline Ridge. The Yap Trench migrated westward with respect to the Philippine Sea Plate after collision, then consumption of the volcanic arc crust occurred, caused by tectonic erosion, and the distance between the arc and the trench consequently narrowed. Lower crustal sections of the Philippine Sea Plate were exposed on the arc-ward trench slope by overthrusting. Intense shearing caused deformation of the accumulated rocks, resulting in their metamorphism in the Yap Arc.  相似文献