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31.
The conversion of bedrock to regolith marks the inception of critical zone processes, but the factors that regulate it remain poorly understood. Although the thickness and degree of weathering of regolith are widely thought to be important regulators of the development of regolith and its water‐storage potential, the functional relationships between regolith properties and the processes that generate it remain poorly documented. This is due in part to the fact that regolith is difficult to characterize by direct observations over the broad scales needed for process‐based understanding of the critical zone. Here we use seismic refraction and resistivity imaging techniques to estimate variations in regolith thickness and porosity across a forested slope and swampy meadow in the Southern Sierra Critical Zone Observatory (SSCZO). Inferred seismic velocities and electrical resistivities image a weathering zone ranging in thickness from 10 to 35 m (average = 23 m) along one intensively studied transect. The inferred weathering zone consists of roughly equal thicknesses of saprolite (P‐velocity < 2 km s?1) and moderately weathered bedrock (P‐velocity = 2–4 km s?1). A minimum‐porosity model assuming dry pore space shows porosities as high as 50% near the surface, decreasing to near zero at the base of weathered rock. Physical properties of saprolite samples from hand augering and push cores are consistent with our rock physics model when variations in pore saturation are taken into account. Our results indicate that saprolite is a crucial reservoir of water, potentially storing an average of 3 m3 m?2 of water along a forested slope in the headwaters of the SSCZO. When coupled with published erosion rates from cosmogenic nuclides, our geophysical estimates of weathering zone thickness imply regolith residence times on the order of 105 years. Thus, soils at the surface today may integrate weathering over glacial–interglacial fluctuations in climate. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
32.
The continuous measurement of molecular hydrogen (H2) emissions from passively degassing volcanoes has recently been made possible using a new generation of low-cost electrochemical sensors. We have used such sensors to measure H2, along with SO2, H2O and CO2, in the gas and aerosol plume emitted from the phonolite lava lake at Erebus volcano, Antarctica. The measurements were made at the crater rim between December 2010 and January 2011. Combined with measurements of the long-term SO2 emission rate for Erebus, they indicate a characteristic H2 flux of 0.03?kg s–1 (2.8?Mg? day–1). The observed H2 content in the plume is consistent with previous estimates of redox conditions in the lava lake inferred from mineral compositions and the observed CO2/CO ratio in the gas plume (~0.9 log units below the quartz–fayalite–magnetite buffer). These measurements suggest that H2 does not combust at the surface of the lake, and that H2 is kinetically inert in the gas/aerosol plume, retaining the signature of the high-temperature chemical equilibrium reached in the lava lake. We also observe a cyclical variation in the H2/SO2 ratio with a period of ~10?min. These cycles correspond to oscillatory patterns of surface motion of the lava lake that have been interpreted as signs of a pulsatory magma supply at the top of the magmatic conduit.  相似文献   
33.
Representative images of split sediment cores document geological records, serve as visual aids for multimedia, and provide samples for image analysis. Existing core imaging systems, often containing integrated hardware and software, are capable of providing excellent images; unfortunately these systems are also bulky and expensive, and are therefore limited to labs that process large volumes of core and those actively involved in image analysis. For most research groups such systems are unfeasible to buy and maintain. Producing good quality core images with a hand-held digital camera is very difficult without a consistent lighting source, and changes in camera angle (in all three spatial dimensions) between photographs may prevent accurate image compositing. Tripods allow for camera stability, but typically do not accommodate downward-facing photography. Presented here is an easily constructed core-imaging system that minimizes many of the drawbacks of personal digital cameras. Software necessary for using this system is readily available and can be run from a personal computer.  相似文献   
34.
35.
A Kalman filter-based method combining the energy of both L1 C/A and L2C GPS signals in a combined tracking loop method to enhance performance under adverse conditions is developed. Standard tracking methods and the ionospheric effect on GPS signals are reviewed and compared to a new Kalman filter that simultaneously estimates delay, phase and total electron content by combining L1 C/A and L2C code and phase discriminator outputs. The new filter is tested and compared to standard methods for tracking L1 C/A and L2C using both simulated and real data. The new method is found to have improved sensitivity of 3 dB compared to standard L1 tracking and 4.5 dB compared to standard L2C tracking while at the same time providing an accurate estimate of the total electron content along the signal path.  相似文献   
36.
Here we present results from a suite of laboratory experiments that highlight the influence of channel sinuosity on the depositional mechanics of channelized turbidity currents. We released turbidity currents into three channels in an experimental basin filled with water and monitored current properties and the evolution of topography via sedimentation. The three channels were similar in cross-sectional geometry but varied in sinuosity. Results from these experiments are used to constrain the run-up of channelized turbidity currents on the outer banks of moderate to high curvature channel bends. We find that a current is unlikely to remain contained within a channel when the kinetic energy of a flow exceeds the potential energy associated with an elevation gain equal to the channel relief; setting an effective upper limit for current velocity. Next we show that flow through bends induces a vertical mixing that redistributes suspended sediment back into the interiors of depositional turbidity currents. This mixing counteracts the natural tendency for suspended sediment concentration and grain size to stratify vertically, thereby reducing the rate at which sediment is lost from a current via deposition. Finally, the laboratory experiments suggest that turbidity currents might commonly separate from channel sidewalls along the inner banks of bends. In some cases, sedimentation rates and patterns within the resulting separation zones are sufficient to construct bar forms that are attached to the channel sidewalls and represent an important mechanism of submarine channel filling. These bar forms have inclined strata that might be mistaken for the deposits of point bars and internal levees, even though the formation mechanism and its implications to channel history are different.  相似文献   
37.
Six new 40Ar/39Ar and three cosmogenic 36Cl age determinations provide new insight into the late Quaternary eruptive history of Erebus volcano. Anorthoclase from 3 lava flows on the caldera rim have 40Ar/39Ar ages of 23 ± 12, 81 ± 3 and 172 ± 10 ka (all uncertainties 2σ). The ages confirm the presence of a second, younger, superimposed caldera near the southwestern margin of the summit plateau and show that eruptive activity has occurred in the summit region for 77 ± 13 ka longer than previously thought. Trachyte from “Ice Station” on the eastern flank is 159 ± 2 ka, similar in age to those at Bomb Peak and Aurora Cliffs. The widespread occurrences of trachyte on the eastern flank of Erebus suggest a major previously unrecognized episode of trachytic volcanism. The trachyte lavas are chemically and isotopically distinct from alkaline lavas erupted contemporaneously in the summit region < 5 km away.  相似文献   
38.
Volcanic emission rates of As, Sb, Pb, Hg, Se, Cl, and F were determined at Erebus volcano, Antarctica and White Island, New Zealand, using chemical traps. The trace metal fluxes were determined by combining the species to S ratios in the solutions with SO2 emission rates measured by correlation spectrometry at the two volcanoes. At Erebus volcano, fluxes for the metals Pb and Hg were 2.0 × 10− 4 and 8.1 × 10− 6 kg s− 11, respectively. Fluxes for Cl, F, As, Sb and Se (0.35, 0.15, 2.5 × 10− 4, 1.2 × 10− 5, and 4.5 × 10− 6 kg s− 1, respectively) agreed within error limits for values determined previously by the LiOH impregnated filter method [Zreda-Gostynska, G., Kyle, P., Finnegan, D., Prestbo, K., 1997. Volcanic gas emissions from Mount Erebus and their impact on the Antarctic environment. Journal of Geophysical Research, 102(B7): 15039–15055.], demonstrating the utility of the chemical trap method. A fall in the As/S ratio from 7 × 10− 4 in 1997/1999 to 3 × 10− 4 in 2000 at Erebus coincided with a change in the frequency and style of eruptive activity that may have been due to injection of magma into the system. At White Island, chemical trap data indicated fluxes of Cl = 0.90, F = 0.0079, Pb = 2.7 × 10− 4, Hg = 1.1 × 10− 5, As = 1.3 × 10− 4, Sb = 1.9 × 10− 5 and Se = 1.5 × 10− 5 kg s− 1. Samples collected 600 m downwind of the active crater were comparable to samples collected adjacent to the main gas vent, showing that this method can still be used at some distance from a degassing vent.  相似文献   
39.
Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations.  相似文献   
40.
Accurate and realistic characterizations of flood hazards on desert piedmonts and playas are increasingly important given the rapid urbanization of arid regions. Flood behavior in arid fluvial systems differs greatly from that of the perennial rivers upon which most conventional flood hazard assessment methods are based. Additionally, hazard assessments may vary widely between studies or even contradict other maps. This study's chief objective was to compare and evaluate landscape interpretation and hazard assessment between types of maps depicting assessments of flood risk in Ivanpah Valley, NV, as a case study. As a secondary goal, we explain likely causes of discrepancy between data sets to ameliorate confusion for map users. Four maps, including three different flood hazard assessments of Ivanpah Valley, NV, were compared: (i) a regulatory map prepared by FEMA, (ii) a soil survey map prepared by NRCS, (iii) a surficial geologic map, and (iv) a flood hazard map derived from the surficial geologic map, both of which were prepared by NBMG. GIS comparisons revealed that only 3.4% (33.9 km2) of Ivanpah Valley was found to lie within a FEMA floodplain, while the geologic flood hazard map indicated that ~ 44% of Ivanpah Valley runs some risk of flooding (Fig. 2D). Due to differences in mapping methodology and scale, NRCS data could not be quantitatively compared, and other comparisons were complicated by differences in flood hazard class criteria and terminology between maps. Owing to its scale and scope of attribute data, the surficial geologic map provides the most useful information on flood hazards for land-use planning. This research has implications for future soil geomorphic mapping and flood risk mitigation on desert piedmonts and playas. The Ivanpah Valley study area also includes the location of a planned new international airport, thus this study has immediate implications for urban development and land-use planning near Las Vegas, NV.  相似文献   
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