Determination of the second critical end point in silicate-H₂O systems using high-pressure and high-temperature X-ray radiography     

Kenji Mibe  Masami Kanzaki  Kyoko N. Matsukage  Shigeaki Ono 《Geochimica et cosmochimica acta》2004,68(24):5189-5195

To determine the second critical end point in silicate-H₂O systems, a new method for the direct observations of immiscible fluids has been developed using a synchrotron X-ray radiography technique. High-pressure and high-temperature experiments were carried out with a Kawai-type, double-stage, multi-anvil high-pressure apparatus (SPEED-1500) installed at BL04B1, SPring-8, Japan. The Sr-plagioclase (SrAl₂Si₂O₈)-H₂O system was used as an illustrative example. A new sample container composed of a metal (Pt) tube with a pair of lids, made of single crystal diamonds, was used under pressures between 3.0 and 4.3 GPa, and temperatures up to ∼1600°C. The sample in the container could be directly observed through the diamond lids with X-ray radiography. At around 980 to 1060°C and pressures between 3.0 and 4.0 GPa, light gray spherical bubbles moving upward through the dark gray matrix were observed. The light gray spheres that absorb less X-rays represent an aqueous fluid, whereas the dark gray matrix represents a silicate melt. These two immiscible phases (aqueous fluid and silicate melt) were observed up to 4.0 GPa. At 4.3 GPa, no bubbles were observed. These observations suggest that the second critical end point in the Sr-plagioclase-H₂O system occurs at around 4.2 ± 0.2 GPa and 1020 ± 50°C. Our new technique can be applied to the direct observations of various systems with two coexisting fluids under deep mantle conditions.  相似文献   

Factors controlling the temporal variation of fatty acids in piculate matter during a phytoplankton bloom in a marine mesocosm     

Kazuhide Hayakawa  Nobuhiko Handa  Kyoko Kawanobe  Chi Shing Wong 《Marine Chemistry》1996,52(3-4)

Fatty acids present in suspended particles were examined following the onset of a phytoplankton bloom in an experimental marine mesocosm set up in Patricia Bay, Saanich Inlet, British Columbia, Canada. The predominantly diatom bloom, triggered by the addition of nutrients at the commencement of the experiment, was succeeded by several other phytoplankton forms, which in turn led to changes in particulate chl a, and organic carbon, and nitrogen within the experimental enclosure. An examination of individual fatty acids indicated that the variation of individual fatty acids can be classified into three groups, although the variation pattern of individual fatty acids differed from one another. An attempt was made to establish the factors controlling particulate fatty acid concentrations by principal component analysis. After Varimax rotation, six factors were extracted, of which four factors contributed to 83% of the data matrix. These were mainly dependent on the source of the particles i.e., diatoms, dinoflagellates, and bacteria.Fatty acid concentrations obtained by analysis of different lipid class fractions indicated that the production of fatty acids was distinctly related to the growth stage of the phytoplankton bloom. Fatty acids in triglycerides peaked during stationary phase, whereas fatty acids in polar lipids were high during the stage of an increase of phytoplankton biomass. However, fatty acid composition in both lipid classes changed under the influence of species succession of the phytoplankton population. This strongly suggested that species succession of the phytoplankton exerted the most significant control on fatty acid composition of particulate matter.  相似文献   

Resting cells of microorganisms in the 20–100 μm fraction of marine sediments in an Antarctic coastal area     

Mutsuo Ichinomiya  Miwa Nakamachi  Mitsuo Fukuchi  Akira Taniguchi 《Polar Science》2008,2(1):27-32

We investigated the morphological features, vertical sinking fluxes, and number densities of the resting cells of ice-associated microorganisms in the 20–100 μm fraction of natural marine sediments collected from ice-covered and ice-free areas around Syowa Station, Lützow-Holm Bay, East Antarctica. We identified the resting cells of various taxonomic groups, including the spores of a diatom, cysts of three dinoflagellates, cysts of five oligotrich ciliates, and the eggs of a mesozooplankton. This is the first report of oligotrich ciliate cysts from Antarctic waters. The resting spores of Thalassiosira australis (diatom), cysts of Polarella glacialis (dinoflagellate), and egg type 1 sink to the bottom sediment during summer. Our results suggest that some planktonic and ice-associated microorganisms in Antarctic coastal areas send their resting cells to the bottom sediments as seed populations for the following generation.  相似文献   

A laboratory study of Equotip surface hardness measurements on a range of sandstones: What influences the values and what do they mean?     

Julie Desarnaud  Kyoko Kiriyama  Beril Bicer Simsir  Katrin Wilhelm  Heather Viles 《地球表面变化过程与地形》2019,44(7):1419-1429

The Equotip rebound tester is a simple, non-destructive technique to measure the surface hardness of materials. Having a low impact energy gives the Equotip advantages over the commonly used Schmidt Hammer on weathered rock and stone. In this study we have investigated the influence of different parameters (sample size, moisture content and surface roughness) on the surface hardness values obtained from freshly cut blocks of four types of sandstone. In a series of laboratory experiments both Single Impacts (SIM) and Repeat Impacts (RIM) methods have been used with C and D probes (which have different impact energies). Our results show that whilst sample size is of great importance we find that smaller samples can be reliably evaluated than previously reported. Moisture contents are also found to exert a more important influence on both SIM and RIM results than previously thought, with up to 26% lower hardness values recorded on saturated vs dry sandstone. Conversely, we find that surface roughness (over Sz values of 100 to 800 microns) does not have a significant impact on SIM measurements collected using the D probe. Both SIM and RIM data are found to be good proxies for compressive strength and open porosity, with SIM data collected with the C probe showing the best fits. Data collected using 3D microscopy helps visualize and quantify the small impact marks created by the Equotip and confirms that these are much reduced when using the C vs D probe. The results highlight the benefits of the Equotip to studies of the nature and deterioration of sandstone, the need for careful evaluation of any confounding factors which might influence the values obtained, and illustrate the different advantages of C and D probes. © 2019 John Wiley & Sons, Ltd.  相似文献   

Recent advances in researches on physiologically active substances in holothurians     

Hirata Takashi Zaima Nobuhiro Yamashita Kyoko Noguchi Ryoko XUE Changhu Sugawara Tatsuya 《中国海洋大学学报(英文版)》2005,4(3):193-197

In this report, we reviewed recent literature on physiologically active substances from sea cucumbers （SCs） and their activities together with results obtained from our study. Preventive properties against lipid metabolism were reported in rats using a whole SC preparation with no particular constituent specified. Administration of the preparation lowered serum and hepatic cholesterol levels and improved the HDL/LDL ratio. These functions may be attributed to the stimulatory effect of the extract on the secretion of cholesterol in feces. Novel fucosylated chondroitin sulfates （FCSs） from Ludwigothurea grisea significantly induced fibroblast growth factor 2-dependent angiogenesis in human umbilical vein endothelial cells （HUVECs）. The proangiogenetic activity seemed attributable to the action of the sulfated fucose branches on the polysaccharide. SCs contain mycosporine-like amino acids （MAAs） that are capable of absorbing UV. A biogenetic precursor of MAAs was first reported in SCs. The anti-proliferative effects of a branched chain fatty acid from a sea cucumber on prostate cancer cells was reported with the activity of 5-lipoxygenase. Glycosphingolipid constituents in SCs have been systematically analyzed over the past ten years. The results showed that the gangliosides in several SCs differed from those of mammals in that a sialic acid of SC gangliosides directly binded to glucose of cerebroside. Neuritogenic activity of the glycosphingolipids was demonstrated in vitro experiments and may lead to the development of therapeutic products for neurological disorders. Our study also showed that sphingoid bases, the hydrolyzed products of glycosphingolipids from SCs, induced significant apoptosis in several tumor cell lines.  相似文献   

Great earthquake at 7.3 ka inferred from tsunami deposits in the Sukumo Bay area,Southwestern Japan     

Futoshi Nanayama  Tomohiro Tsuji  Tatsuhiko Yamaguchi  Yasuo Kondo  Michiharu Ikeda  Toshimichi Nakanishi  Michiko Miwa  Chuki Hongo  Akira Furusawa  Mitsuhiro Kuwahata 《Island Arc》2021,30(1):e12422

Tsunami deposits in Kyushu Island, Southwestern Japan, have been attributed to the 7.3 ka Kikai caldera eruption, but their origin has not been confirmed. We analyzed an 83-cm-thick Holocene event deposit in the SKM core, obtained from incised valley fill in the coastal lowlands near Sukumo Bay, Southwestern Shikoku Island. We confirmed that the event deposit contains K-Ah volcanic ash from the 7.3 ka eruption. The base of the event deposit erodes the underlying inner-bay mud, and the deposit contains material from outside the local terrestrial and marine environment, including angular quartz porphyry from a small inland exposure, oyster shell debris, and a coral fragment. Benthic foraminifers and ostracods in the deposit indicate various habitats, some of which are outside Sukumo Bay. The sand matrix contains low-silica volcanic glass from the late stage of the Kikai caldera eruption. We also documented the same glass in an event deposit in the MIK1 core, from the incised Oyodo River valley in the Miyazaki Plain on Southeastern Kyushu. These two 7.3 ka tsunami deposits join other documented examples that are widely distributed in Southwestern Japan including the Bungo Channel and Beppu Bay in Eastern Kyushu, Tachibana Bay in Western Kyushu, and Zasa Pond on the Kii Peninsula as well as around the caldera itself. The tsunami deposits near the caldera have been divided into older and younger 7.3 ka tsunami deposits, the younger ones matching the set of widespread deposits. We attribute the younger 7.3 ka tsunami deposits to a large tsunami generated by a great interplate earthquake in the Northern part of the Ryukyu Trench and (or) the Western Nankai Trough just after the late stage of the Kikai caldera eruption and the older 7.3 ka tsunami deposits to a small tsunami generated by an interplate earthquake or Kikai caldera eruption.  相似文献   

Middle Miocene to Pleistocene magneto-biostratigraphy of ODP Sites 1150 and 1151, northwest Pacific: Sedimentation rate and updated regional geological timescale     

Isao Motoyama  Nobuaki Niitsuma  Toshiaki Maruyama  Hiroki Hayashi  Shin-ichi Kamikuri  Masamichi Shiono  Toshiya Kanamatsu  Kaori Aoki  Chikako Morishita  Kyoko Hagino  Hiroshi Nishi  Motoyoshi Oda 《Island Arc》2004,13(1):289-305

Abstract Shipboard and shore‐based investigation on siliceous and calcareous microfossil biostratigraphy, magneto‐stratigraphy and tephrostratigraphy identified numerous datum events from the sedimentary sequences of Sites 1150 and 1151 drilled on the forearc basin of northern Japan by the Ocean Drilling Program Leg 186. Some 83 datum events were selected to construct new age–depth models for the sites. Based on the reliable magneto‐stratigraphy from the Pleistocene to the Upper Miocene, which were correlated to the standard geomagnetic polarity timescale, and on excellent records of diatom and radiolarian biostratigraphy throughout the sequences, the shipboard age model was revised. Major revisions referred to stratigraphic position of the Miocene–Pliocene boundary that has been shifted more than 200 m downward in each sequence. The age–depth relations of the forearc sites represent drastic changes in the sedimentation rate—extremely high (40 cm/k.y. on average) in the Early Pliocene and low (less than 2 cm/k.y. on average) in the Middle Miocene—and several hiatuses exist throughout the sequence. The drastic changes can be related mostly to changes in diatom sedimentation and the tectonics of the Japanese Island Arc. Local ages for some foraminiferal, calcareous nannofossil and radiolarian bioevents are estimated from the age–depth models at each site. These newly calibrated bioevents and biozones as well as established diatom biostratigraphy are incorporated into the updated magneto‐biochronologic timescale, which will contribute to an improvement in biochronologic accuracy of Neogene sediments in northern Japan and adjacent areas.  相似文献   

Preliminary analysis of the Knipovich Ridge segmentation: influence of focused magmatism and ridge obliquity on an ultraslow spreading system   总被引：2，自引：0，他引：2  

Kyoko Okino  Daniel CurewitzMiho Asada  Kensaku TamakiPeter Vogt  Kathleen Crane 《Earth and Planetary Science Letters》2002,202(2):275-288

Bathymetry, gravity and deep-tow sonar image data are used to define the segmentation of a 400 km long portion of the ultraslow-spreading Knipovich Ridge in the Norwegian-Greenland Sea, Northeast Atlantic Ocean. Discrete volcanic centers marked by large volcanic constructions and accompanying short wavelength mantle Bouguer anomaly (MBA) lows generally resemble those of the Gakkel Ridge and the easternmost Southwest Indian Ridge. These magmatically robust segment centers are regularly spaced about 85-100 km apart along the ridge, and are characterized by accumulated hummocky terrain, high relief, off-axis seamount chains and significant MBA lows. We suggest that these eruptive centers correspond to areas of enhanced magma flux, and that their spacing reflects the geometry of underlying mantle upwelling cells. The large-scale thermal structure of the mantle primarily controls discrete and focused magmatism, and the relatively wide spacing of these segments may reflect cool mantle beneath the ridge. Segment centers along the southern Knipovich Ridge are characterized by lower relief and smaller MBA anomalies than along the northern section of the ridge. This suggests that ridge obliquity is a secondary control on ridge construction on the Knipovich Ridge, as the obliquity changes from 35° to 49° from north to south, respectively, while spreading rate and axial depth remain approximately constant. The increased obliquity may contribute to decreased effective spreading rates, lower upwelling magma velocity and melt formation, and limited horizontal dike propagation near the surface. We also identify small, magmatically weaker segments with low relief, little or no MBA anomaly, and no off-axis expression. We suggest that these segments are either fed by lateral melt migration from adjacent magmatically stronger segments or represent smaller, discrete mantle upwelling centers with short-lived melt supply.  相似文献   

Impacts of explosive volcanism on distal alluvial sedimentation: Examples from the Pliocene–Holocene volcaniclastic successions of Japan     

Kyoko S. Kataoka  Vern Manville  Takeshi Nakajo  Atsushi Urabe 《Sedimentary Geology》2009,220(3-4):306

Volcanic activities can create cataclysmic hazards to surrounding environments and human life not only during the eruption but also by hydrologic remobilisation (lahar) processes after the cessation of eruptive activity. Although there are many studies dealing with the assessment and mitigation of volcanic hazards, these are mostly concentrated on primary eruptive processes in areas proximal to active volcanoes. However, the influence of volcaniclastic resedimentation may surpass the impacts of primary eruptive activity in terms of both extent and persistence, and can ultimately result in severe hazards in downstream areas.Examination of the volcaniclastic successions of non-marine Pliocene–Holocene sedimentary basins in Japan has revealed hydrological volcaniclastic sedimentation in fluvial and lacustrine environments hundreds of kilometres from the inferred source volcano. Impacts on these distal and often spatially separated basins included drastic changes in depositional systems caused by sudden massive influxes of remobilised pyroclastic material. Typical volcaniclastic beds comprise centimetre- to decimetre-thick primary pyroclastic fall deposits overlain by metre- to 10s of metres-thick resedimented volcaniclastic deposits, intercalated in sedimentary successions of non-volcanic provenance. The relatively low component of primary pyroclastic fall deposits in the volcaniclastic beds suggests that: 1) potential volcanic hazards would be underestimated on the basis of primary pyroclastic fall events alone; and 2) the majority of resedimented material was likely derived from erosion of non-welded pyroclastic flow deposits in catchment areas rather than remobilisation of local fallout deposits from surrounding hillslopes.The nature, distribution and sequence of facies developed by distal volcaniclastic sediments reflect the influence of: 1) proximity to ignimbrite, but not directly with the distance to the eruptive centre; 2) ignimbrite nature (non-welded or welded) and volume; 3) temporal changes in sediment flux from the source area; 4) the physiography and drainage patterns of the source area and the receiving basin, and any intervening areas; and 5) the formation of ephemeral dam-lakes and intra-caldera lakes whose potential catastrophic failure can impact distal areas. Models of the styles and timing of distal volcaniclastic resedimentation are thus more complicated than those developed for proximal settings of stratovolcanoes and their volcaniclastic aprons and hence present different challenges for hazard assessment and mitigation.  相似文献   

Temporal variations in the abundance and sinking flux of diatoms under fast ice in summer near Syowa Station, East Antarctica     

Mutsuo Ichinomiya  Yasushi Gomi  Miwa Nakamachi  Masaki Honda  Mitsuo Fukuchi  Akira Taniguchi 《Polar Science》2008,2(1):33-40

To investigate the fate of ice algae released from sea ice, we investigated the abundance, species composition, and sinking flux of diatoms in the water column under fast ice near Syowa Station, Antarctica during the summer of 2005/2006. The diatom assemblage in the water column consisted of chain-forming planktonic species, in contrast to the under-ice assemblage dominated by pennate species reported from this site in the past; this dissimilarity suggests the presence of an unconsolidated platelet ice layer under the congelation ice, within which planktonic species can bloom. Among the dominant diatoms, Porosira pseudodenticulata and Pseudo-nitzschia cf. turgiduloides were dominant in the water column, and their water column stocks were higher than their mass sedimentation. These species apparently maintain their populations in the surface layer, as their production remains in the water column. In contrast, Fragilariopsis kerguelensis and Thalassiosira australis were scarce in the water column but rich in the flux, indicating active sinking and export of their production to the benthic ecosystem. This distinction in buoyancy control and sinking characteristics of the dominant diatoms on release from the fast ice influences the diatom species composition and carbon flow under the ice.  相似文献