Oxygen isotope and 26Al‐26Mg systematics of aluminum‐rich chondrules from unequilibrated enstatite chondrites     

Yunbin Guan  Gary R. Huss  Laurie A. Leshin  Glenn J. MacPherson  Kevin D. McKeegan 《Meteoritics & planetary science》2006,41(1):33-47

Abstract— Correlated in situ analyses of the oxygen and magnesium isotopic compositions of aluminum‐rich chondrules from unequilibrated enstatite chondrites were obtained using an ion microprobe. Among eleven aluminum‐rich chondrules and two plagioclase fragments measured for ²⁶Al‐²⁶Mg systematics, only one aluminum‐rich chondrule contains excess ²⁶Mg from the in situ decay of ²⁶Al; the inferred initial ratio (²⁶Al/²⁷Al)_o = (6.8 ± 2.4) × 10^?6 is consistent with ratios observed in chondrules from carbonaceous chondrites and unequilibrated ordinary chondrites. The oxygen isotopic compositions of five aluminum‐rich chondrules and one plagioclase fragment define a line of slope ?0.6 ± 0.1 on a three‐oxygen‐isotope diagram, overlapping the field defined by ferromagnesian chondrules in enstatite chondrites but extending to more ¹⁶O‐rich compositions with a range in δ¹⁸O of about ?12‰. Based on their oxygen isotopic compositions, aluminum‐rich chondrules in unequilibrated enstatite chondrites are probably genetically related to ferromagnesian chondrules and are not simple mixtures of materials from ferromagnesian chondrules and calcium‐aluminum‐rich inclusions (CAIs). Relative to their counterparts from unequilibrated ordinary chondrites, aluminum‐rich chondrules from unequilibrated enstatite chondrites show a narrower oxygen isotopic range and much less resolvable excess ²⁶Mg from the in situ decay of ²⁶Al, probably resulting from higher degrees of equilibration and isotopic exchange during post‐crystallization metamorphism. However, the presence of ²⁶Al‐bearing chondrules within the primitive ordinary, carbonaceous, and now enstatite chondrites suggests that ²⁶Al was at least approximately homogeneously distributed across the chondrite‐forming region.  相似文献   

Computations and estimates of rate coefficients for hydrocarbon reactions of interest to the atmospheres of the outer solar system     

A.H. Laufer  E.P. Gardner  T.L. Kwok  Y.L. Yung 《Icarus》1983,56(3):560-567

The rate coefficients, including Arrhenius parameters, have been computed for a number of chemical reactions involving hydrocarbon species for which experimental data are not available and which are important in planetary atmospheric models. The techniques used to calculate the kinetic parameters include the Troe and semiempirical bond energy-bond order (BEBO) or bond strength-bond length (BSBL) methods.  相似文献   

Conceptual model of leachate migration in a granular aquifer derived from the integration of multi-source characterization data (St-Lambert,Canada)     

Laurie Tremblay  René Lefebvre  Daniel Paradis  Erwan Gloaguen 《Hydrogeology Journal》2014,22(3):587-608

Numerical models encompassing source zones and receptors, based on representative conceptual models and accounting for aquifer heterogeneity, are needed to understand contaminant migration and fate; however, aquifer characterization seldom provides the necessary data. This study aimed to develop a workflow for field characterization and data integration, which could: (1) be adapted to the definition of subwatershed-scale aquifer heterogeneity (over 10 km²) and (2) adequately support mass transport model development. The study involved the field investigation of a shallow granular aquifer in a 12-km² subwatershed in Saint-Lambert-de-Lauzon, Canada, in which a decommissioned landfill is emitting a leachate plume managed by natural attenuation. Using proven field methods, the characterization sequence was designed to optimize each method in terms of location, scale of acquisition, density and quality. The emphasis was on the acquisition of detailed indirect geophysical data that were integrated with direct hydraulic and geochemical data. This report focuses on the first qualitative and geostatistical data integration steps of the workflow leading to the development of a hydrogeological conceptual model. This is a prerequisite for further integration steps: prediction of hydrofacies and hydraulic conductivity (K), geostatistical simulations of K, studies of geochemical processes and numerical modeling.  相似文献   

Vertical profiling of SO2 and SO above Venus’ clouds by SPICAV/SOIR solar occultations     

Denis A. Belyaev  Franck Montmessin  Jean-Loup Bertaux  Arnaud Mahieux  Anna A. Fedorova  Oleg I. Korablev  Emmanuel Marcq  Yuk L. Yung  Xi Zhang 《Icarus》2012,217(2):740-751

New measurements of sulfur dioxide (SO₂) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO₂ (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO₂ of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO₂ layers. In the lower layer SO₂ mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO₂ increasing with the altitude from 0.05 to 2 ppmv, and the [SO₂]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SO_x species could be explained by H₂SO₄ photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO₂ production by the evaporation of H₂SO₄ from droplets and its subsequent photolysis at around 100 km.  相似文献   

Sulfur chemistry in the middle atmosphere of Venus     

Xi Zhang  Mao Chang Liang  Franklin P. Mills  Denis A. Belyaev  Yuk L. Yung 《Icarus》2012,217(2):714-739

Venus Express measurements of the vertical profiles of SO and SO₂ in the middle atmosphere of Venus provide an opportunity to revisit the sulfur chemistry above the middle cloud tops (～58 km). A one dimensional photochemistry-diffusion model is used to simulate the behavior of the whole chemical system including oxygen-, hydrogen-, chlorine-, sulfur-, and nitrogen-bearing species. A sulfur source is required to explain the SO₂ inversion layer above 80 km. The evaporation of the aerosols composed of sulfuric acid (model A) or polysulfur (model B) above 90 km could provide the sulfur source. Measurements of SO₃ and SO (a¹Δ → X³Σ^-) emission at 1.7 μm may be the key to distinguish between the two models.  相似文献   

Generation of Power by Microbial Fuel Cell with Ferricyanide in Biodegradation of Benzene     

Chih‐Hung Wu  Chi‐Yung Lai  Chi‐Wen Lin  Min‐Hsiu Kao 《洁净——土壤、空气、水》2013,41(4):390-395

The power generation potential of a microbial fuel cell (MFC) during the process of benzene biodegradation with potassium ferricyanide (0–200 mM) as the terminal electron acceptor was evaluated. Experimental results demonstrate that benzene was used as the sole carbon source in generating electricity by a mixed culture. The power density increased from 0.0276 to 2.1 mW m^?2 as the concentration of potassium ferricyanide in the cathode chamber was increased from 0 to 200 mM. With a benzene concentration of 10.87 mg L^?1 and a potassium ferricyanide concentration of between 0 and 150 mM, complete degradation of benzene was achieved in 22–24.5 h. However, when the concentration of potassium ferricyanide was raised to 200 mM, the time required for complete benzene degradation was prolonged to 35 h. The results of this investigation can be used as a basis for future assessments of the power generation capacity of MFCs that are used to treat benzene‐contaminated wastewater.  相似文献   

A method to dynamically subdivide parcels in land use change models   总被引：1，自引：0，他引：1  

Rohan Wickramasuriya  Laurie A. Chisholm  Marji Puotinen  Nicholas Gill  Peter Klepeis 《International journal of geographical information science》2013,27(8):1497-1513

Spatial simulation models have become a popular tool in studying land use/land cover (LULC) change. An important, yet largely overlooked process in such models is the land subdivision, which is known to govern LULC change and landscape restructuring to a large extent. To fill this gap, we propose an efficient and straightforward method to simulate dynamic land subdivision in LULC change models. Key features in the proposed method are implementing a hierarchical landscape where adjacent cells of the same LULC type form patches, patches form properties, and properties form the landscape and incorporating real subdivision layouts. Furthermore, we use a queue-based modified flood-fill algorithm to dynamically reset LULC patches following a subdivision. The proposed subdivision method is demonstrated in action using a prototype agent-based LULC model developed for an amenity landscape in Australia. Results show that it is computationally feasible to run the subdivision method even as spatial resolution is increased, thus providing a proven means for spatial simulation models to dynamically split parcel land.  相似文献   

Design and functions of floating architecture – a review     

Yuan-Ho Lin  Yung Chih Lin  Han-Shih Tan 《Marine Georesources & Geotechnology》2013,31(7):880-889

Abstract

Floating facilities such as, floating islands, floating houses, industries and, entire cities are constructions for habitation, entertainment, industrial or commercial purposes, and infrastructures are built to float on fresh- or seawater. They can be floating on air-filled or light materials. Recent developments in the ocean show a trend of offshore constructions, which can be situated above deeper waters, further offshore. These can replace the development of reclaimed lands close to shore. Floating architecture provides certain advantages for the planning of sustainable design, such as: (a) a number of viable responses to the problem of rising sea level, (b) much-needed space replacing the lack of land for agriculture, for housing, and for commercial growth, (c) the creation of new and innovative tourist destinations, (d) a much smaller ecological footprint than land-based constructions, (e) the extension of city centers that are built near the coast; (f) the possibility of green planning at an unclaimed plot. We present here a review of existing floating architecture with different functions, from housing, entertainment, and food production to industrial purposes such as wind parks and desalinization plants.  相似文献   

Denudation intensity and control in the Chinese Tian Shan: new constraints from mass balance on catchment‐alluvial fan systems          下载免费PDF全文

Laure Guerit  Laurie Barrier  Marc Jolivet  Bihong Fu  François Métivier 《地球表面变化过程与地形》2016,41(8):1088-1106

Tectonics and climate are usually seen as the main controlling factors of denudation rates, which seem to rise with the tectonic activity and to decrease when the climate becomes drier. However, the low denudation rates observed in semi‐arid to arid contexts are generally measured on orogenic plateaus where the respective influence of the flat relief and the dry climate cannot really be unravelled. The Chinese Tian Shan was chosen as a case study. In the northern piedmont of this mountain range, a series of well‐preserved Quaternary alluvial fans offer the opportunity to perform a mass balance study at the scale of several catchment areas and several hundreds of thousands of years. Based on a geometrical reconstruction of these fans, the volumes of sediments exported out of 10 drainage basins during the Middle–Late Pleistocene (from ～300 to ～12 kyr) and the Holocene (from ～12 kyr to present) have been estimated. From these volumes, an average denudation rate of ～135 m/Myr was determined in the Tian Shan Range for the last 300 kyr. In agreement with other mass balances performed in the same area, the typical denudation intensity of the northern Tian Shan is thus of a few hundred meters per million years at most, regardless of the space and time scales considered. From a comparison with denudation rates in other mountain ranges throughout the world, we suggest that a dry climate can dramatically limit the denudation intensity even in active orogenic systems with a high topographic gradient like the Tian Shan. As a result, the time required to reach equilibrium between denudation and rock uplift in these systems could be extremely long (i.e. of more than several million years). Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

澳大利亚寒武系生物地层研究新进展(英文)   总被引：1，自引：1，他引：0  

Peter D.Kruse  James B.Jago  John R.Laurie 《地层学杂志》2009,33(1)

澳大利亚寒武系集中分布在一南北向分布的从澳大利亚的北部、中部直到南澳大利亚克拉通地块上,少量寒武纪地层分布在新南威尔士、维多利亚和塔斯马尼亚。寒武系的底在中澳大利亚的Amadeus盆地出露得最好。下寒武统(大致相当于纽芬兰统和第二统)在澳大利亚北部大多数是不含化石的火山岩,而在澳大利亚中部和南澳大利亚的盆地中,其中最有名的是南澳大利亚的Arrowie和Stansbury盆地则是各种含化石的巨厚沉积序列。澳大利亚的下寒武统没有分阶方案,尽管在生物地层研究上最近取得很大进展,现在可以利用疑源类、遗迹化石、古杯类、三叶虫、腕足类、软体动物和其他小壳化石进行化石带的划分。很长一段时间内澳大利亚中部和北部的Ord-ian阶被认为是中寒武世最早期的,现在证明它可能相当于第二统的全部或者一部分;含化石的中寒武统和芙蓉统(或上寒武统)在Georgina盆地东部发育非常完整,在中澳大利亚、新南威尔士、维多利亚和塔斯马尼亚也可见到,都可以划分到阶。芙蓉统的底大致与Idamean阶的底相当。化石带的建立主要综合考虑球接子三叶虫、多节类三叶虫,自Iverian期晚期起再加上牙形类化石。寒武系的顶大致相当于Warendan阶的底,相关地层在Georgina盆地东部发育得很好。  相似文献