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The physical properties of bentonite-based buffer materials for nuclear waste repositories have been investigated by a number of different laboratory tests. These tests have yielded a material model that is valid for conditions close to water saturation and is useful for describing: (a) the stress, strain and volume change behaviour; (b) the pore pressure and flow of water; and (c) the thermal and thermomechanical response.

The material model is based on the Drucker-Prager Plasticity model and a Porous Elastic Model. The effective stress concept and Darcy's law are applied and the swelling/consolidation and thermomechanical processes are coupled according to the separate mechanical properties of the pore water, the solids and the clay skeleton. The model can be used by the finite-element program ABAQUS.

The model has been tested in several laboratory and field verification tests. Comparison between measured and calculated behaviour shows that the general behaviour is described properly and several calculations of different scenarios have been made for the Swedish KBS 3 concept. However, certain processes, like the hysteresis effect at consolidation/swelling, the curved stress-strain relation at shearing, and the curved failure envelope, are not modelled in a perfectly accurate way and an improved material model is proposed here. It combines the behaviour of the Cam-clay model on the wet side with the more relevant plastic behaviour of a modified Drucker-Prager model with a curved failure envelope and the possibility to introduce strain softening after failure.

The paper presents some laboratory results that are the basis of the first model. It also shows the application of the model to finite-element calculations of some laboratory tests. Comparisons between the calculations and measured results expose some disadvantages of the model and a concept for an improved model is suggested.  相似文献   

105.
Clausthalite in coal   总被引:2,自引:0,他引:2  
A lead selenide mineral, tentatively identified as clausthalite (PbSe) based on optical microscopy, scanning electron microscopy with energy-dispersive X-ray (EDAX), electron microprobe, and scanning proton microprobe (SPM), has been described in a number of coals. While clausthalite has been mentioned as a possible source of Se in coal, it is present in such small quantities and sizes, that the mineral identification has not been absolutely confirmed. The mineral specimens examined in this study would contribute, not only to the Pb and Se concentrations in the coal, but also, in at least one case, to Hg concentrations.  相似文献   
106.
Using the UNFCCC as a basis, and the objectives of estimating soil organic carbon (SOC) changes during the period 1900–2100, a spatially explicit database of climate, land cover and soil texture was compiled for a 262,000 km2 region in semi-arid Sudan. The area is characterized by low input cultivation of millet, sorghum and sesamé combined with livestock grazing. By integrating the database with the CENTURY ecosystem model, we were able to estimate historical, current and future pools of SOC as a function of land management and climate.The SOC (upper 20 cm) decrease from 1900 to 2000 was estimated to be 6·8 Mt and the maximum potential carbon sink (SOC increase) for the period 2000 to 2100 was estimated to be 17 Mt. Cropland and grassland lost 293 and 152 t SOC km−2 respectively whereas the savannahs gained 76 t SOC km−2 from 1900 to 2000. The SOC sequestration scenario simulated during 2000–2100 recovered 94, 84 and 75 t km−2 for cropland, grassland and savannah respectively.In addition to climate and soils, cropping intensity, fallow periods, fire frequency and grazing intensity also influence cropland SOC variation. Grassland and savannah SOC variations depend on grazing intensity and fire return interval. Land management may affect future amounts of SOC in semi-arid areas thereby turning them from sources into sinks of carbon. SOC estimates were reasonably consistent with measurements (r2=0·70, n=13).  相似文献   
107.
Interannual-to-interdecadal ocean-atmosphere interaction in midlatitudes is studied using an idealized coupled model consisting of eddy resolving two-layer quasi-geostrophic oceanic and atmospheric components with a simple diagnostic oceanic mixed layer. The model solutions exhibit structure and variability that resemble qualitatively some aspects of the observed climate variability over the North Atlantic. The atmospheric climatology is characterized by a zonally modulated jet. The single-basin ocean climatology consists of a midlatitude double jet that represents the Gulf Stream and Labrador currents, which are parts of the subtropical and subpolar gyres, respectively. The leading mode of the atmospheric low-frequency variability consists predominantly of meridional displacements of the zonal jet, with a local maximum over the ocean. The first basin-scale mode of sea-surface temperature has a red power spectrum, is largely of one polarity and bears qualitative similarities with the observed interdecadal mode identified by Kushnir. A warm sea-surface temperature anomaly is accompanied by anomalously low atmospheric pressure, an intensified model Gulf Stream and a weakened Labrador current. This mode is found not to be affected significantly by oceanic coupling. In the western part of the basin, this sea-surface temperature pattern is shown to be forced by the slowest components of the surface-wind anomaly through a delayed modulation of the baroclinic time-dependent boundary currents which advect mean SST, with synchronous variations in the two oceanic jets. The response in the east is found to be dominated by local atmospheric forcing. Basin-scale intrinsic oceanic variability consists of a damped oceanic oscillatory mode in the baroclinic flow field that is excited by the atmospheric noise. Its period is around 5.5 years, but it has a negligible influence on the evolution of sea-surface temperature. Important for this mode's excitation is the meridional position of the atmospheric center of action relative to the ocean gyres.  相似文献   
108.
The evolution of coronal loops in response to slow photospheric twisting motions is investigated using a variety of methods. Firstly, by solving the time-dependent equations it is shown that the field essentially evolves through a sequence of 2-D equilibria with no evidence of rapid dynamic evolution. Secondly, a sequence of 1-D equilibria are shown to provide a remarkably good approximation to the 2-D time-dependent results using a fraction of the computer time. Thus, a substantial investigation of parameter space is now possible. Finally, simple bounds on the 3-D stability of coronal loops are obtained. Exact stability bounds can be found by using these bounds to reduce the region of parameter space requiring further investigation. Twisting the loop too much shows that a 3-D instability must be triggered.  相似文献   
109.
The hydro-mechanical behaviour of a clay-based buffer material for nuclear waste disposal has been investigated in a laboratory program. In this program, the main focus was on the influence of confinement on water uptake and swelling pressure during suction decrease. The laboratory program and some of the results are presented by Dueck [Dueck, A., 2006. Laboratory results from hydro-mechanical tests on a water unsaturated bentonite. submitted for publication.].

The results from the laboratory tests were used to find a relationship between water content, void ratio, swelling pressure and suction. Two equations for swelling pressure represent the outline of the model.

In the first equation, the swelling pressure developed during water uptake is normalised by a pressure corresponding to the swelling pressure at saturation. This is done in order to be independent of void ratio. A relationship between the normalised swelling pressure and the degree of saturation is suggested.

The second equation describes a relationship between the swelling pressure, the water content and the actual suction (or relative humidity). The equation is based on a thermodynamic relationship and includes the retention curve (i.e. water content vs. suction under free swelling conditions).

The model can be used for a state where two of the four variables; water content, void ratio, swelling pressure and suction are known and can thus be useful to evaluate field measurements and model late stages of the wetting process. An example of an application is given. The equations are mainly based on results from tests with increasing degrees of saturation under constant void ratio but are also suggested for use with increasing void ratio.  相似文献   

110.
Early geographies focussed on children have recorded their environmental and spatial perceptions. Contemporary theoretical and methodological advances in, and beyond, children’s geographies have supported a more complex engagement with environmental topics. Complementing this work, a study of young people’s experience and knowledge of a river in southern New Zealand is presented. Data were gathered from four contrasting locations within one, 5650 sq. km, catchment, employing child-oriented, multi-method approaches. Data analysis confirms existing literature highlighting how young people are competent knowledge producers with varying experiences and understandings. Some of this variation can be appreciated by focussing on factors of age, gender and catchment location. Together these findings are relevant to both academic and planning circles and implications for young people’s participation in catchment management are noted as a key area for further development of work of this kind.  相似文献   
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