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21.
A microflow of free ascending gas has been observed in 26 out of 30 tested boreholes at three different sites. The flow rates vary between 60 × 10−4 and 4 cm3/min m2 horizontally projected borehole area. Sampling has been made in ground boreholes as well as in holes drilled downwards from the lowest levels in two mines. The composition of the gas varies considerably. The main components of the gas are nitrogen, argon, oxygen and methane. Traces of heavier hydrocarbons are observed. At the site of the ground holes, only traces of methane are observed. In all sampled holes the existence of free oxygen is observed. The nitrogen/argon quotient is close to the atmospheric quotient in all sampled holes, indicating a partly atmospheric origin of the gas. The existence of methane and traces of heavier hydrocarbons indicates the existence of a second source. 相似文献
22.
Temperature dependence of calcite dissolution kinetics between 1 and 62°C at pH 2.7 to 8.4 in aqueous solutions 总被引:1,自引:0,他引:1
The kinetics of calcite dissolution in aqueous KCl-solutions far from equilibrium, between 1 and 62°C in the pH-range 2.7 to 8.4 have been investigated using a rotating disc apparatus. At neutral and alkaline pH in the mixed kinetic regime the empirical apparent activation energy (EAAE) for the surface chemical reaction rate constant is 54 ± 4 kJ mole?1 for Carrara marble and 46 ± 4 kJ mole?1 for Iceland spar. Under similar conditions the EAAE of the transport rate constant increases with decreasing temperature, but has a mean value of 27 ± 2 kJ mole?1. The corresponding diffusion coefficient has a mean EAAE of 37 ± 3 kJ mole?1 and this high EAAE is consistent with transport dependence on product diffusion in this H+-independent regime.In contrast, in acid solutions, where the rate approaches end-member transport control, the EAAE of the diffusion coefficient is 16 kJ mole?1, also decreasing with increasing temperature. This is compatible with H+-diffusion to the surface being rate-controlling.In inhibitor-free natural systems, calcite dissolution kinetics far from equilibrium can be described in terms of three regimes: an H+-dependent regime (pH < 4 at 25°C), a transition regime (4 < pH < 5.5 at 25°C) and an H+-independent regime (pH > 5.5 at 25°C). At lower temperatures these boundaries move to higher pH values. The presence of inhibitors in natural systems may enhance surface controlled kinetics. 相似文献
23.
Ten sites near the Snake River Plain have consistent differences in their climatic histories. Sites at low elevation reflect the “early Holocene xerothermic” of the Pacific Northwest, whereas most climatic chronologies at high elevation indicate maximum warmth or aridity somewhat later, ca. 6000 yr ago. This elevational contrast in climatic histories is duplicated at three sites from the central Snake River Plain. For sites in such close proximity, the different chronologies cannot be explained by changes in atmospheric circulation during the late Quaternary. Rather, the differences are best explained by the autecology of the plants involved and the changing seasonal climate. The seasonal climatic sequence predicted by multiple thermal maxima explains the high- and low-elevation chronologies. During the early Holocene, maximum insolation and intensified summer drought in July forced low-elevation vegetation upward. However, moisture was not a limiting factor at high elevation, where vegetation moved upward in response to increased length of growing season coincident with maximum September insolation 6000 yr ago. 相似文献
24.
Double-packer injection tests have been carried out in a borehole in the Chalk of Hampshire and a borehole in the Permian Penrith Sandstone of Cumbria, England. The tests have been supplemented by borehole logging and television inspections and by laboratory measurements on cores. A new mathematical treatment has enabled results to be calculated for injection test intervals containing fissures. In both formations, transmissivity immediately around the borehole is dominated by a few major fissures. In the Penrith Sandstone there is good agreement between intergranular hydraulic conductivity measurements and packer-test results in the portions of the borehole which do not contain major fissures. In the Chalk, the packer-test values are always higher than the intergranular measurements, suggesting that some degree of fissuring is present throughout. 相似文献
25.
R.R. Brooks J. Holzbecher D.J. Robertson D.E. Ryan 《Journal of Geochemical Exploration》1982,16(3):189-195
Ashed twigs of Picea rubens (red spruce) collected over an area of uranium mineralization in central Nova Scotia were analyzed for uranium in the course of biogeochemical prospecting for this element. Uranium levels in background samples were significantly lower than in those collected from areas with mineralization either at depth or on the surface. Scintillometric data were useful only to differentiate background and surface mineralization. Uranium levels in soils showed no correlation whatsoever with mineralization or with radiometry. There was a very high degree of correlation between the scintillometric data and uranium concentrations in ashed twigs and it is considered that twigs of Picea rubens might be successfully used for biogeochemical prospecting for uranium in this area. 相似文献
26.
The Batinah mélange which overlies the late Cretaceous Semail ophiolite in the northern Oman Mountains comprises mostly sedimentary rocks of deep-water facies, alkalic lavas and intrusives, all of continental margin affinities, together with smaller volumes of Semail ophiolitic and metamorphic rocks. Four intergradational textural types of mélange can be recognized. Sheet mélange has large (>1 km) intact sheets either with little intervening matrix or set in other mélange types, and with an organised sheet orientation fabric. Slab mélange is finer textured (>100 m) and more disrupted. Block mélange has smaller (> m) blocks with some matrix and a weak to random block fabric. Clast mélange is matrix-supported rudite with a weak depositional clast fabric. Structural relationships, particularly the absence of tectonic fabrics, the decreasing strength of fragment fabrics with increasing fragmentation, and the abundance of brittle fragmentation, suggest that these mélange types formed by either gravity-driven sedimentary processes or superficial sliding or thrusting of individual rock slabs.In the slab mélange, long sequences can be pieced together, passing up from Upper Triassic mafic sub-marine extrusives and sediments into radiolarian cherts, hemipelagic and redeposited limestones, and terminating in non-calcareous radiolarities with Mn-deposits of early Cretaceous age. Mafic sills are numerous. These sequences can be matched with sub-ophiolite rocks now exposed in fault corridors through the Semail. These sequences become progressively disrupted upwards in the corridors and can be traced continuously into overlying mélange, which then thins away from the corridors.We argue that, during late Cretaceous emplacement over the Arabian margin, active fault corridors split the Semail slab and acted as conduits up which sub-ophiolite rocks were supplied to the ophiolite surface. There the rocks were redisributed by superficial processes. 相似文献
27.
Analysis of the vapor in passive vapor samplers retrieved from a streambed in fractured rock terrain implied that volatile organic carbon (VOC) discharge from ground water to surface water substantially increased following installation of a contaminant recovery well using air rotary drilling. The air rotary technique forced air into the aquifer near the stream. The injection produced an upward hydraulic gradient that appears to have transported water and contaminants from deeper parts of the aquifer through fractures into shallow parts of the aquifer. Once in the shallow flow regime, the contamination was transported to the stream, where it discharged during the next several weeks following well installation. After the recovery well was activated and began continuously pumping contaminated ground water to a treatment facility, the VOC concentrations in the stream bottom passive vapor samplers decreased to below detectable concentrations, suggesting that the withdrawal had captured the contaminated ground water that previously had discharged to the stream. 相似文献
28.
Richard E. A. Robertson 《Natural Hazards》1995,11(2):163-191
The Soufriere volcano is a 1220 m high stratovolcano which occupies the northern part of the island of St. Vincent. It is one of the most active centres of volcanism in the Caribbean and has a record of activity dating back to the Pleistocene. Historic eruptions (since 1718) have caused over 1600 deaths and resulted in damage to property valued in excess of 4.8 million USD. In addition, current development plans for the area point towards increased risk of disastrous consequences from future activity at the volcano.All aspects of risk relevant to the volcano, are discussed, with particular emphasis on the manner in which these are perceived and on the question of acceptable risk. A method is presented for use in risk assessment of volcanic hazard and a number of risk zones are defined for the Soufriere volcano. Numerical estimates of the relative loss expected within each zone are obtained from a consideration of the value of property at risk, its vulnerability to the hazardous volcanic events and the expected spatial impact of volcanic events. Such estimates suggest that the northern-most third of the island is at least ten times more at risk than areas further south. The likelihood of death and destruction is extreme in such high risk areas, while the most feasible method of loss reduction is evacuation before an eruption occurs.Formerly at Department of Earth Sciences, University of Leeds, Leeds LS2 9JT, United Kingdom. 相似文献
29.
P.B. Robertson L.C. Coleman E.J. Olsen S.A. Kissin 《Meteoritics & planetary science》1982,17(3):163-170
The recovery of several thousand meteorite fragments from Antarctica has led to speculation that accumulations may occur on the Earth's other major ice caps. Meteorites falling over the past 80,000 years on the Devon Island ice cap in the Canadian Arctic may be exposed at the surface near the ice cap margin. From the terrestrial meteorite flux, ice movement rates, and fragmentation factors it is calculated that 12,560 samples of 150 g mass are potentially concentrated in a 65 km2 zone along the northwest margin. A search of this region on foot and by helicopter in July, 1981, failed to recover any specimens. Although metre-sized gneissic boulders, plucked from the underlying Precambrian basement, were concentrated in this zone it is postulated that the unseasonal 30 cm snow cover on the ice prohibited the recognition of possible meteorite specimens, which may average only 5 cm in diameter. 相似文献
30.