Assessing the spatial variability of the ~3 μm OH/H2O absorption feature in CM2 carbonaceous chondrites     

Cody Schultz  Brendan A. Anzures  Ralph E. Milliken  Taki Hiroi  Kevin Robertson 《Meteoritics & planetary science》2023,58(2):170-194

H₂O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body.  相似文献   

Biochemical biomarkers in adult female perch (Perca fluviatilis) in a chronically polluted gradient in the Stockholm recipient (Sweden)     

Hansson T  Schiedek D  Lehtonen KK  Vuorinen PJ  Liewenborg B  Noaksson E  Tjärnlund U  Hanson M  Balk L 《Marine pollution bulletin》2006,53(8-9):451-468

A battery of biochemical biomarkers and the SigmaPCB concentration in adult female perch (Perca fluviatilis) verified an aquatic pollution gradient with the city of Stockholm (Sweden) as a point source of anthropogenic substances. The investigation included both an upstream gradient, 46 km westwards through Lake M?laren, and a downstream gradient, 84 km eastwards through the Stockholm archipelago. Besides the main gradient from Stockholm, there were strong indications of pollution coming from the Baltic Sea. The results indicated a severe pollution situation in central Stockholm, with poor health status of the perch, characterised by increased specific EROD activity in the liver, increased liver EROD somatic index, decreased AChE activity in the muscle, increased amount of DNA adducts in the liver, and a high concentration of biliary 1-pyrenol. In addition, laboratory exposure to common EROD inducers elicited an abnormal response, suggestive of chronic intoxication.  相似文献   

Systematic Errors Induced by the Elliptical Power-law model in Galaxy-Galaxy Strong Lens Modeling     

Xiaoyue Cao  Ran Li  J.W.Nightingale  Richard Massey  Andrew Robertson  Carlos S.Frenk  Aristeidis Amvrosiadis  Nicola C.Amorisco  Qiuhan He  Amy Etherington  Shaun Cole  Kai Zhu 《天文和天体物理学研究(英文版)》2022,(2):143-172

The elliptical power-law model of the mass in a galaxy is widely used in strong gravitational lensing analyses.However,the distribution of mass in real galaxies...  相似文献   

Palaeozoic-Recent geological development and uplift of the Amanos Mountains (S Turkey) in the critically located northwesternmost corner of the Arabian continent     

Tamer Y. Duman  Alastair H. F. Robertson  Hasan Elmacı  Meryem Kara 《Geodinamica Acta》2017,29(1):103-138

We have carried out a several-year-long study of the Amanos Mountains, on the basis of which we present new sedimentary and structural evidence, which we combine with existing data, to produce the first comprehensive synthesis in the regional geological setting. The ca. N-S-trending Amanos Mountains are located at the northwesternmost edge of the Arabian plate, near the intersection of the African and Eurasian plates. Mixed siliciclastic-carbonate sediments accumulated on the north-Gondwana margin during the Palaeozoic. Triassic rift-related sedimentation was followed by platform carbonate deposition during Jurassic-Cretaceous. Late Cretaceous was characterised by platform collapse and southward emplacement of melanges and a supra-subduction zone ophiolite. Latest Cretaceous transgressive shallow-water carbonates gave way to deeper-water deposits during Palaeocene-Eocene. Eocene southward compression, reflecting initial collision, resulted in open folding, reverse faulting and duplexing. Fluvial, lagoonal and shallow-marine carbonates accumulated during Late Oligocene(?)-Early Miocene, associated with basaltic magmatism. Intensifying collision during Mid-Miocene initiated a foreland basin that then infilled with deep-water siliciclastic gravity flows. Late Miocene-Early Pliocene compression created mountain-sized folds and thrusts, verging E in the north but SE in the south. The resulting surface uplift triggered deposition of huge alluvial outwash fans in the west. Smaller alluvial fans formed along both mountain flanks during the Pleistocene after major surface uplift ended. Pliocene-Pleistocene alluvium was tilted towards the mountain front in the west. Strike-slip/transtension along the East Anatolian Transform Fault and localised sub-horizontal Quaternary basaltic volcanism in the region reflect regional transtension during Late Pliocene-Pleistocene (<4 Ma).  相似文献   

Phosphate Plume Persistence at Two Decommissioned Septic System Sites   总被引：5，自引：1，他引：4  

W.D. Robertson  J. Harman 《Ground water》1999,37(2):228-236

  相似文献   

Emission within a damped Lyman α absorption trough: the complex sightline towards Q2059−360     

Bruno Leibundgut  J. Gorden Robertson 《Monthly notices of the Royal Astronomical Society》1999,303(4):711-720

  相似文献   

A numerical representation of fracturing granular materials     

D. Robertson  M. D. Bolton  G. R. McDowell 《国际地质力学数值与分析法杂志》1997,21(12):825-843

This paper describes the computer algorithms used in a numerical simulation of the compression of an aggregate of crushable grains. It has been used in a model for the evolution of a granular medium under one-dimensional compression, in which the probability of fracture for individual particles is a function of applied stress, particle-size and co-ordination number. The information relating to the particles is represented in a compact way on the computer which allows the number of particles produced to become sufficiently large for satisfactory comparisons to be made with experimental data and which allows information, such as the positions and sizes of the particles, to be easily extracted. An algorithm based on the representation is used to locate neighbouring particles in a way which does not deteriorate unacceptably in terms of speed as the number of particles increases. © 1997 by John Wiley & Sons, Ltd.  相似文献   

Probabilistic seasonal streamflow forecasts of the Citarum River,Indonesia, based on general circulation models     

Netrananda?SahuEmail authorView author&#;s OrcID profile  Andrew?W.?Robertson  Rizaldi?Boer  Swadhin?Behera  David?G.?DeWitt  Kaoru?Takara  Manish?Kumar  R.?B.?Singh 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(7):1747-1758

In this study we discuss probabilistic forecasts of Citarum River streamflow, which supplies 80 % of the water demands in Jakarta, Indonesia, based on general circulation model (GCM) output, for the September–November (SON) season. Retrospective forecasts of precipitation made over the period 1982–2010 with two coupled-ocean atmosphere GCMs, initialized in August, are used in conjunction historical streamflow records, with a cross-validated regression model. Pearson’s product moment correlation skill values of 0.58–0.67 are obtained, with relative operating characteristic scores of 0.67–0.84 and 0.74–0.92 for the lower and upper tercile categories of flows respectively. Both GCMs thus demonstrate promising ability to forecast below/above normal streamflow for the Citarum River flow during the SON season.  相似文献   

Long-term evapotranspiration rates for rainfed corn versus perennial bioenergy crops in a mesic landscape     

Michael Abraha  Jiquan Chen  Stephen K. Hamilton  G. Philip Robertson 《水文研究》2020,34(3):810-822

Perennial cellulosic crops are promoted for their potential contributions to a sustainable energy future. However, a large-scale perennial bioenergy production requires extensive land use changes through diversion of croplands or conversion of uncultivated lands, with potential implications for local and regional hydrology. To assess the impact of such land use conversions on ecosystem water use, we converted three 22 year-old Conservation Reserve Program (CRP) grasslands and three 50+ year-old conventionally tilled corn-soybean crop fields (AGR) to either no-till continuous maize (corn) or perennial (switchgrass or restored prairie) bioenergy crops. We also maintained one CRP grassland without conversion. We measured evapotranspiration (ET) rates on all fields for 9 years using eddy covariance methods. Results show that: (a) mean growing-season ET rates for perennial crops were similar to the ET rate of the corn they replaced at the previously cultivated (AGR) field but ET rates for perennial crops at CRP fields were 5–9% higher than ET rate for corn on former CRP fields; and (b) mean nongrowing season ET rates for perennial fields were 11–15% lower than those for corn fields, regardless of land use history. On an annual basis, mean ET rates for perennial crops tended to be lower (4–7%) than ET rate of the corn that they replaced at AGR fields but ET rates for perennial crops and corn at CRP fields were similar. Over 9 years, mean ET rates for the same crop across land use histories were remarkably similar for corn, whereas for the perennial crops they were 4–10% higher at former CRP than at former AGR fields, mainly due to differences in growing season ET. Over the 9 years and across all fields, ET returned ~60% of the precipitation back to the atmosphere. These findings suggest that large-scale substitution of perennial bioenergy crops for rainfed corn in mesic landscapes would have little if any (0 to −3%) impact on terrestrial water balances.  相似文献