Granite Systems with Rare-Metal Pegmatites     

Beskin  S. M.  Marin  Yu. B. 《Geology of Ore Deposits》2020,62(7):554-563

Geology of Ore Deposits - For most rare-metal pegmatite fields, two generations of granitic pegmatites are documented, namely, beryll-bearing (often with tantaloniobates and muscovite, which are...  相似文献   

Lethal and estrogenic effects of 4-nonylphenol in the cockle Cerastoderma glaucum   总被引：1，自引：1，他引：0  

Maria Gabriella Marin  Stefano Rigato  Francesco Ricciardi  Valerio Matozzo 《Marine pollution bulletin》2008,57(6-12):552

The lethal and sublethal effects of the xenoestrogen 4-nonylphenol (NP) were evaluated in the cockle Cerastoderma glaucum. In a 96-h lethality test, bivalves were exposed to 0, 0+ acetone, 0.19, 0.38, 0.75, 1.5 and 3.0 mg NP/l. The 96-h LC₅₀ value was 0.3 mg NP/l. No mortality was observed at 0.1 mg NP/l. The potential estrogenicity of NP was studied in both sexually undifferentiated (resting phase) and differentiated (pre-spawning phase) cockles, exposed for 7 and 14 days to 0, 0+ acetone, 0.0125, 0.025, 0.05, and 0.1 mg NP/l. Vitellogenin (Vg)-like protein levels were determined in both haemolymph and digestive gland by the alkali-labile phosphate (ALP) assay. In the resting phase, exposure for 7 days to 0.1 mg NP/l resulted in significant increases in ALP in both haemolymph and digestive gland, compared with controls. A significant increase was also observed in digestive gland of animals exposed to 0.0125 mg NP/l-exposed animals. After 14 days of exposure, haemolymph ALP levels were significantly increased in exposed animals at all NP concentrations tested, whereas no difference was recorded in digestive gland. In the pre-spawning phase, exposure for 7 days to NP significantly increased ALP levels in haemolymph from males exposed at all NP concentrations tested, whereas no significant variations were found in haemolymph from females. NP (0.05 and 0.1 mg/l) was also shown to increase ALP concentrations significantly in digestive gland of males, but not in those of females. Likewise, after 14 days’ exposure, ALP levels significantly increased in haemolymph from males only at 0.1 mg NP/l. Conversely, NP caused significant increases in ALP levels in digestive gland from both males (at all NP concentrations tested) and females (at 0.025 and 0.1 mg NP/l). These results demonstrate that NP induces Vg synthesis in C. glaucum. Interestingly, males were more responsive to NP than females.  相似文献   

Volatile element signatures in the mantles of Earth,Moon, and Mars: Core formation fingerprints from Bi,Cd, In,and Sn     

K. Righter  K. Pando  N. Marin  D. K. Ross  M. Righter  L. Danielson  T. J. Lapen  C. Lee 《Meteoritics & planetary science》2018,53(2):284-305

Volatile element concentrations in planets are controlled by many factors such as precursor material composition, core formation, differentiation, magma ocean and magmatic degassing, and late accretionary processes. To better constrain the role of core formation, we report new experiments defining the effect of temperature, and metallic S and C content on the metal-silicate partition coefficient (or D(i) metal/silicate) of the volatile siderophile elements (VSE) Bi, Cd, In, and Sn. Additionally, the effect of pressure on metal-silicate partitioning between 1 and 3 GPa, and olivine-melt partitioning at 1 GPa have been studied for Bi, Cd, In, Sn, As, Sb, and Ge. Temperature clearly causes a decrease in D(i) metal/silicate for all elements. Sulfur and C have a large influence on activity coefficients in metallic Fe liquids, with C causing a decrease in D(i) metal/silicate, and S causing an increase. Pressure has only a small effect on D(Cd), D(In), and D(Ge) metal/silicate. Depletions of Bi, Cd, In, and Sn in the terrestrial and Martian mantles are consistent with high PT core formation and metal-silicate equilibrium at the high temperatures indicated by previous studies. A late Hadean matte would influence Bi the most, due to its high D(sulfide/silicate) ~2000, but segregation of a matte would only reduce the mantle Bi content by 50%; all other less chalcophile elements (e.g., Sn, In, and Cd) would be minimally affected. The lunar depletions of highly VSE require a combination of core formation and an additional depletion mechanism—most likely the Moon-forming giant impact, or lunar magma ocean degassing.  相似文献   

Hydrogen and Carbon Groups in the Structures of Rock-Forming Minerals of Rocks of the Lithospheric Mantle: FTIR and STA + QMS Data     

M. S. Babushkina  V. L. Ugolkov  Yu. B. Marin  L. P. Nikitina  A. G. Goncharov 《Doklady Earth Sciences》2018,479(2):456-459

Using IR–Fourier spectrometry (FTIR) and simultaneous thermal analysis combined with quadrupole mass spectrometry of thermal decomposition products (STA + QMS), olivines and clinopyroxene from xenolites of spinel and garnet lherzolites contained in kimberlites and alkaline basalts were studied to confirm the occurrence of hydrogen and carbon within the structure of the minerals, as well as to specify the forms of H and C. The presence of hydroxyl ions (OH–) and molecules of crystal hydrate water (H₂Ocryst) along with CO₂, CH, CH₂, and CH₃ groups was detected, which remained within the structures of mantle minerals up to 1300°C (by the data of both techniques). The total water (OH–and H2Ocryst) was the prevailing component of the C–O–H system.  相似文献   

Organic waste impact of capture-based Atlantic bluefin tuna aquaculture at an exposed site in the Mediterranean Sea     

Luigi Vezzulli  Mariapaola Moreno  Valentina Marin  Elisabetta Pezzati  Marco Bartoli  Mauro Fabiano 《Estuarine, Coastal and Shelf Science》2008

A variety of pelagic and benthic parameters were measured at an aquaculture farm used for the fattening of Atlantic bluefin tuna (Thunnus thynnus) which is located at an exposed site (700 m from the coast, average bottom depth of 45 m and average current speed of 6 cm s⁻¹) in the Mediterranean Sea. The objective was to test whether modern off-shore tuna fattening industries can exert a sustainable organic waste impact on the receiving environment as has been reported for the offshore culture of more traditional Mediterranean species such as sparids. In the water column, the concentration of phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of mesozooplankton (at the species level) were assessed. In the sediment, we assessed the concentration of reduced sulphur pools, phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of meiofauna (at the taxa level) and nematodes (at the genus level). For most parameters, we found no substantial differences between farm and control sites. Deviations of farm values from control values, when they occurred, were small and did not indicate any significant impact on either the pelagic and benthic environment. Deviations were more apparent in the benthic compartment where lower redox potential values, higher bacterial production rates and a change in nematode genus composition pointed out to early changes in the sediment's metabolism. In addition, indigenous potential pathogenic bacteria showed higher concentration at the fish farm stations and were a warning of an undesirable event that may become established following aquaculture practice in oligotrophic environments. The overall data from this study provide extensive experimental evidence to support the sustainability of modern offshore farming technology in minimizing the hypertrophic-dystrophic risks associated with the rapidly-expanding tuna-fattening industry in the Mediterranean Sea.  相似文献   

Trace elements in zircon from rocks of the Katugin rare-metal deposit     

E. V. Levashova  S. G. Skublov  Yu. B. Marin  T. N. Lupashko  E. A. Ilchenko 《Geology of Ore Deposits》2015,57(7):579-590

The Katugin deposit of economic Ta, Nb, Zr, U, REE, Y, and cryolite (Na₃AlF₆) ores is located in the Kalar district of the Chita region and classified as unique in Nb, Ta, and Y reserves hosted in rare-metal alkali granite. The distribution of trace elements (including REE) in zircon was studied for ore-bearing arfvedsonite–aegirine, biotite–riebeckite rocks, and zones of late recrystallization with nodular zircon clusters. The outer rims and marginal zones of zircon grains are depleted in almost all trace elements except for hafnium as compared with cores and central zones. Compositional features of zircon cores indicate their magmatic origin and do not prove metasomatic nature of the deposit. The similar REE patterns of zircon rims and cores, as well as other attributes assume postmagmatic or metamorphic origin of the rims.  相似文献   

Wolframoixiolite and niobian ferberite from zinnwaldite granitic rocks of the Chukchi Peninsula   总被引：1，自引：0，他引：1  

V. I. Alekseev  I. M. Gembitskaya  Yu. B. Marin 《Geology of Ore Deposits》2011,53(7):639-648

The finding of wolframoixiolite with inclusions of niobian ferberite is described from zinnwaldite granite and ongonite of the Severny pluton of the Chukchi Peninsula. The optical, morphological, and chemical properties of minerals are characterized and compared with their analogues from other regions. The petrologic and mineragenic index implications of the minerals are discussed with allowance for our contemporary mineralogical knowledge on W-bearing Ta-Nb minerals.  相似文献   

Structural and chemical heterogeneity of natural crystals and microgeochemical line of research in ontogeny of minerals     

V. I. Alekseev  Yu. B. Marin 《Geology of Ore Deposits》2012,54(8):589-601

A review of the current state of genetic mineralogy in the field of the chemical heterogeneity of mineral individuals is presented. Due to advances in the local analysis of matter, the ontogenetic approach is now being focused on the chemical anatomy of minerals. A new line of research, microgeochemistry, deals with the migration of chemical elements in natural crystals caused by defects in the crystal lattice. It becomes evident that structural and chemical heterogeneity is an intrinsic property of mineral individuals. Phenomenological laws of this heterogeneity and the interaction of atoms with lattice defects are stated.  相似文献   

Comprehensive systematics of tantalum and tantalo-niobium deposits     

S. M. Beskin  Yu. B. Marin 《Geology of Ore Deposits》2016,58(7):536-541

A comprehensive systematics of tantalum and tantalo-niobium deposits has been elaborated in form of a table, where three granitoid and one syenitoid igneous series crucial for forecasting of rare-metal-bearing territories are displayed in four columns, and mineralized volcanic and plutonic rocks, pegmatites, and placers critical to ore processing technology are shown in rows. The known and inferred geological and economic types of deposits and their mineralogical subtypes are placed in cells at intersections of rows and columns. The proposed systematics, which combines many attributes, contains a new quality and makes it possible to forecast economic mineralization, including new types that correspond to so far empty cells of the table. Ordinary geological maps and maps of mineral resources are used for this purpose.  相似文献   

First evidence of altered vitellogenin-like protein levels in clam Tapes philippinarum and in cockle Cerastoderma glaucum from the Lagoon of Venice     

Matozzo V  Marin MG 《Marine pollution bulletin》2007,55(10-12):494-504

Possible xenoestrogenic effects were investigated, for the first time, in two bivalve species from the Lagoon of Venice (Italy): the clam Tapes philippinarum and the cockle Cerastoderma glaucum. Bivalves were collected far from their reproductive phase at the very early stage of gametogenesis (January), and in the pre-spawning period (June) in six sites. Vitellogenin (Vg)-like proteins (a biomarker of exposure to estrogenic compounds) were measured by the alkali-labile phosphate method (ALP), in both haemolymph and digestive gland from males and females (when it was possible to distinguish sex by microscopic observation of gonadal tissue). Haemolymph calcium concentrations (a parameter considered closely related to the presence of Vg-like proteins) and the bivalve condition index (CI) were also measured. In both seasons, bivalves collected at Campalto (near a sewage treatment plant) and Marghera (a highly contaminated area) had higher Vg-like protein levels, particularly in haemolymph, than animals from the other sampling sites. Interestingly, CI had high values in these polluted sites. In June only, Vg-like proteins and Ca(2+) levels in haemolymph exhibited similar trends in both bivalve species at most sampling sites. The responsiveness of bivalves to environmental xenoestrogens was higher in June, allowing better discrimination among sites. The present study demonstrates that animals from highly polluted areas have increased Vg-like protein levels. As endocrine disruption due to exposure to estrogenic compounds may cause fertility reduction, alterations in the sex ratio, and a decrease in reproductive rate, a condition of potential risk for bivalve populations in estuarine areas is highlighted.  相似文献