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21.
Methods that employ arrays of emitters are potentially useful in improving weak or ambiguous signals in ground penetrating radar (GPR) prospecting. As in the seismic case, the electromagnetic responses from the subsurface can be obtained by employing true composite sources or synthesized from single emitter responses that are acquired with variable offset, both possibilities leading to similar results. In this article, the synthetic emitter-array method is examined as a way of improving GPR signals. Modeling of transmitted wave-fronts is carried out to analyze how the targets can be illuminated so that the reflected signals are effectively reinforced. The method is applied to different targets. A methodology that simultaneously increases the signal to noise ratio and the lateral coherence of the events is examined in order to facilitate the interpretation of the GPR data. Finally, the synthetic emitter-array method is successfully applied in a case study to determine the width and depth of mud walls at the Palo Blanco archaeological site in Argentina.  相似文献   
22.
Pollen studies and their relationship with modern vegetation facilitate paleoecological reconstructions while changes in pollen abundance are indicators of environmental fluctuations. We analyzed the relationships between recent pollen deposits in the sediments of four Uruguayan coastal lagoons and catchment vegetation and analyzed the temporal dynamics of submerged aquatic vegetation (SAV). We mapped terrestrial vegetation, sampled SAV biomass, and analyzed the pollen record in each lagoon. The sediment samples represented the last 49–76 years of deposition, and most vegetation types were well represented in the pollen records. Pollen of Chenopodiaceae, proposed as indicators of saltmarshes, decreased in the surface samples of all lagoons, possibly due to the salinity reduction promoted by precipitation changes in the region. Pollen of SAV was found in all lagoons but with gaps in the record, and a submerged vegetated phase was recorded. Simultaneous botanical and pollen analyses better captured the large fluctuations of SAV in coastal lagoons.  相似文献   
23.
Local economic development policies have surged in Brazil over the past decade—a major shift in this regionally diverse country of 27 states, over 5000 municipalities, and the largest economy in Latin America. We review the stylized facts, expected patterns and policy recommendations from the foundational studies in regional and urban economics. We then provide a summary of a more recent stream of scholarship focused on local economic development (LED) studies in developed and developing countries that have surged in the last 20 years. Based on this review, we then systemize the findings emerging from studies focused on analyzing local economic development policies in Brazil recognizing the distinctive contributions emerging from both the empirical and the case studies literatures. We identify key lessons for (and from) the Brazilian experience and conclude that Brazil and Latin American countries need a new generation of studies that undertake more rigorous evaluations of these policy experiments. Finally, we recommend steps to advance such research.  相似文献   
24.
Palo Blanco is an approximately 1600 year old archaeological site located in Fiambalá Valley, in the Andean region of Argentina. Pioneer archaeological studies published in the 70s reported the existence of five residential units in this site. Also a small cemetery which included three circular tombs was discovered near to these buildings. Since that time, a profuse sedimentation covered the zone, so nowadays there are no evidences of most of these buildings on surface. Because of an imprecise location of the structures, most of the buildings became in fact missed. Then, in this work we aimed to re-localize two of the missed buildings, a residential unit and a tomb, by applying ground penetrating radar (GPR) methodology. We used fast fixed offset GPR configurations to investigate two areas in which these buildings could be expected. We used experimental and synthetic patterns to aid the identification of the characteristic signals due to the archaeological targets. We applied migration to the data to better define and resolve unclear anomalous signals. The employed methodology revealed the location of both buildings. Also a number of new non-reported structures were predicted and confirmed.  相似文献   
25.
The huge sculptures placed outdoors in the Valley of the Fallen Memorial Park (El Escorial, Madrid) made with blocks of Black-Limestone from Calatorao-Zaragoza, Spain (BLCZ) and disposed on a concrete core exhibit weathering traces, flaking, saline efflorescence and falling fragments, currently represent a danger for visitors. Frost action is important in the Valley of the Fallen by the large number of freeze–thaw cycles produced during Sculptures‘live under a temperate Mediterranean climate with severe seasonality. The formation of fissures facilitates the water transport within the rock and the salt- and ice-induced deterioration. Temperate climates with frequent freezing and thawing cycles can be the most effective drivers of the visible physical weathering. In order to propose a suitable weathering model, collected black-limestones from sculptures and Calatorao quarries were analyzed by optical microscopy, environmental scanning electron microscopy with energy dispersive spectrometry (ESEM-EDS), inductively coupled mass spectrometry (ICP-MS) and X-ray diffraction. Mercury intrusion porosimetry (MIP), nitrogen absorption and helium pycnometry techniques were used for pore analyses of the BLCZ micro-blocks (10 × 10 × 10 cm) described in terms of pore size distribution, pore volume and specific surface area. The appreciable amount of organic matter was isolated by solvent extraction, acid treatment, flotation and perborate degradation followed by Gas Chromatography–Mass Spectrometry (GC–MS), Analytical Pyrolysis (Py-GC/MS), Fourier Transformed Infrared Spectroscopy and Raman techniques. Both weathered and fresh BLCZ samples contained more than 90 % calcite shells with circa 10 % of pyrite (fresh samples) or iron hydroxides (weathered samples), quartz grains, claystone and fossil organic matter consisting of a condensed matrix with polyalkyl chains and polycyclic methoxyl-lacking aromatic structures. The petrophysical analyses revealed volumes of pores, sized <0.025 μm obtained by N2 adsorption, of 3.18 × 10?3 cm3 g?1 while the measured porosity by MIP in the pore range from 0.005 to 200 μm was 3.30 × 10?3 cm3 g?1. These data could be explained by the existence of clay minerals and organic matter in the pore system less than 50 nm of diameter. Concerning BLCZ deterioration it was found that the porous framework of BLCZ was filled with sulphates formed from artificial cement observed in the sculptures inside trough a testing hole and from its intrinsic pyrite. The results suggested that although biological processes were not major agents in rock deterioration, there was also weak compatibility between sculptures‘constituents, (limestone, concrete and oxidized iron clamps) which under, continental Mediterranean conditions, were continuously releasing weathering compounds accelerating disruption of the cut-stone sculptures.  相似文献   
26.
Irradiation techniques are often applied to gem minerals for color enhancement purposes. Natural green, blue and colorless specimens of rare gemological quality euclase, BeAlSiO4(OH), from Brazil were irradiated with gamma rays in the dose range from 10 to 500 kGy. Although the colors of the different specimens were not strongly influenced, two different irradiation-induced paramagnetic defect centers were found by electron paramagnetic resonance (EPR). The first one is an O hole center interacting with one Al neighbor and the second is a Ti3+ electron center. The EPR angular rotation patterns of both irradiation-induced defects were measured and analyzed. The results suggest that O hole centers are formed by dissociation of the hydroxyl ions, similar as in topaz crystals. In euclase the OH ions interconnect distorted Al octahedra and Be tetrahedra in O5 positions. During irradiation, the electrons are captured by titanium ions (Ti4+ + e), leading to the formation of paramagnetic Ti3+ ions. From the EPR rotation patterns it is clear that these ions substitute for Al ions. The spin Hamiltonian parameters of the irradiation-induced defects are analyzed and compared to similar defect centers in other mineral specimens. Thermal annealing experiments show that the O hole centers and Ti3+ electron centers are directly connected through the radiation process.  相似文献   
27.
Generation of granitic melt is believed to occur predominantly by melting through the breakdown of hydrous minerals. However, melting due to the influx of H2O has been recognized in anatectic amphibolite facies tonalitic grey gneisses, metagreywackes and low-P metapelites, and has consequently been proposed as an alternative mechanism for the generation of granitic melt. Melting induced by H2O addition is recognized from voluminous melt production at relatively low temperature, where hydrous minerals are stable and anhydrous minerals are preferentially consumed during melting. Mineral equilibrium modelling to determine the PT conditions, melt volumes, melting reactions and viable H2O sources reveals that the process is not restricted to specific compositions or PT conditions, although lower pressure and lithologies with a low hydrous mineral content are more favourable. Melting reactions in all lithologies primarily consume quartz and feldspars to yield 5–6 mol.% melt for each mol.% of H2O added. remains constant at ~0.70 to 0.77 during progressive melting as long as alkali feldspar is present. Once alkali feldspar is exhausted, plagioclase becomes the main reactant, producing more tonalitic melt compositions with gradually higher . Our results demonstrate that, at the site of melting, melting is driven by diffusion of H2O into the target rock along chemical potential gradients, rather than the advective flow of a mechanically distinct water-rich fluid phase. Melting will initiate and proceed as long as a gradient exists between the H2O source and target lithology. Our calculations show that an ordinary magma, such as an I-type magma with typical H2O content, has a high enough to be a viable H2O source, allowing diffusive H2O-fluxed melting to produce melt proportions and fertility comparable to that of dehydration melting. However, high degrees of partial melting require a considerable amount of H2O, which necessitates a continuously advecting H2O source such as a magma conduit or melt-bearing shear zone. A magmatic H2O source at emplacement level will undergo a similar amount of crystallization as the melt fraction produced in the target rock such that there will be no net melt production. Considering that shear-zone hosted magma conduits are localized features, diffusive H2O-fluxed melting is likely to only be viable in a small fraction of the anatectic orogenic crust. Although it may play an important role in locally raising melt volumes and modifying magma chemistry through mingling and hybridization, it does not appear to, of itself, be able to generate significant volumes of granitic melt.  相似文献   
28.
29.
This paper describes the changes in soil water repellency and soil hydrological and erosional responses to rainfall at small‐plot scale, arising from a prescribed fire immediately following burning and one year later in a Mediterranean heathland in the area of the Strait of Gibraltar (southern Spain). Very little research has been carried out about the modifications on the ground surface after fire immediately after burning. A prescribed fire was conducted to study short‐term changes of the ground surface immediately and one year following burning. After a prescribed fire, a homogeneous charred litter layer and ash‐bed covered the mineral soil surface. This cover stayed stable on the soil surface during a period of seven days, until strong winds redistributed litter and ashes. The hydrophobicity of the exposed surface (litter and ashes) decreased considerably in relation with the litter layer properties before the fire. Ponding, runoff coefficients and soil loss were determined using simulated rainfall over the litter layer, the ash‐bed and the bare soil. Significant differences were not detected between pre‐ and post‐fire soil loss rates while a charred litter and thick ash layer were present on the ground surface. Runoff and erosion rates increased and time to ponding and runoff decreased when the charred litter and ash layers were artificially removed and the bare soil was exposed. Although wildfires will increase soil erodibility, the trends observed in this study suggest that this increased susceptibility to erosion from rainsplash processes may be limited to some degree while an intact ash and charred litter layer is still present. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
30.
This paper introduces a new geostatistical model for counting data under a space-time approach using nonhomogeneous Poisson processes, where the random intensity process has an additive formulation with two components: a Gaussian spatial component and a component accounting for the temporal effect. Inferences of interest for the proposed model are obtained under the Bayesian paradigm. To illustrate the usefulness of the proposed model, we first develop a simulation study to test the efficacy of the Markov Chain Monte Carlo (MCMC) method to generate samples for the joint posterior distribution of the model’s parameters. This study shows that the convergence of the MCMC algorithm used to simulate samples for the joint posterior distribution of interest is easily obtained for different scenarios. As a second illustration, the proposed model is applied to a real data set related to ozone air pollution collected in 22 monitoring stations in Mexico City in the 2010 year. The proposed geostatistical model has good performance in the data analysis, in terms of fit to the data and in the identification of the regions with the highest pollution levels, that is, the southwest, the central and the northwest regions of Mexico City.  相似文献   
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