Aerosol characterization and optical thickness retrievalsusing GOME and METEOSAT satellite data     

M. J. Costa  M. Cervino  E. Cattani  F. Torricella  V. Levizzani  A. M. Silva  S. Melani 《Meteorology and Atmospheric Physics》2002,81(3-4):289-298

Summary ?Retrievals of atmospheric aerosol optical thickness are highly dependent on the choice of the class describing the aerosol properties leading to significant errors while using classes available in the literature. High spectral resolution measurements from GOME (Global Ozone Monitoring Experiment) between the ultraviolet and the near infrared can be used for an accurate characterization of the aerosol optical properties. The radiometer MVIRI (METEOSAT Visible and Infrared Imager) on board the geostationary satellite METEOSAT, while being equipped only with broadband VIS channel, ensures an adequate half-hourly monitoring of the atmospheric conditions over a large portion of the Earth. The present algorithm is based on a combination of data from both sensors for the retrieval of the aerosol optical thickness at the reference wavelength of 0.55 μm (AOT). A case of a desert dust outbreak from the African continent over the Atlantic Ocean is examined. AOT values obtained using a priori fixed classes taken from the literature are compared with those retrieved with this algorithm using the GOME-derived classes. Systematic differences of the order of a few tenths on average are found which remain significant also after considering the measurement errors. This represents a novelty introduced by the synergetic use of both sensors. Received March 13, 2002  相似文献   

黄骅裂谷盆地第三系水循环和渗流场形成演化的重溯     

汪珊  张宏达  郭贵平 《吉林大学学报(地球科学版)》2002,32(4):369-373

在简述盆地地质环境和含水系统、水文地质期与水压系统类型定位的基础上，通过建立数学模型，采用反演、比拟和地静压力等方法，模拟计算了各研究层在各研究时期泥岩压出水水头值（m),Es^2层的依次为2－28，2－26，2－6，2－16，0．5－3．5；Es^1层的依次为2－42，2－26，2－6，10－54，1－14；Ed层的依次为2－22，2－54，2－12；Ng层的依次为10－24，1－5；Nm层的为12－24。各研究层在各研究时期的压挤式水交替强度均小于1，累加值Es^2,Es^1,Ed层的均大于1，Ng，Nm层的小于1；Ed层渗入水交替强度为0.44。各研究层在各研究时期渗流场的高水压带位置和流动态具有相似性，并均以离心型流动型为主要特征。  相似文献   

Geochemistry of Coexisting Biotite and Muscovite of Portuguese Peraluminous Granitic Differentiation Series     

A.M.R. Neiva  M.M.V.G. Silva  M.E.P. Gomes  T.F.C. Campos 《Chemie der Erde / Geochemistry》2002,62(3):197-215

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Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition     

G. M. da Costa  E. Van San  E. De Grave  R. E. Vandenberghe  V. Barrón  L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period     

Jean‐Jacques Macaire  Saïda Bellemlih  Christian Di‐Giovanni  Patrick De Luca  Lionel Visset  Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Development of site-specific design ground motions in Western and Eastern North America     

Walter Silva  Carl Costantino   《Soil Dynamics and Earthquake Engineering》2002,22(9-12):755-764

This paper presents results recently obtained for generating site-specific ground motions needed for design of critical facilities. The general approach followed in developing these ground motions using either deterministic or probabilistic criteria is specification of motions for rock outcrop or very firm soil conditions followed by adjustments for site-specific conditions. Central issues in this process include development of appropriate attenuation relations and their uncertainties, differences in expected motions between Western and Eastern North America, and incorporation of site-specific adjustments that maintain the same hazard level as the control motions, while incorporating uncertainties in local dynamic material properties. For tectonically active regions, such as the Western United States (WUS), sufficient strong motion data exist to constrain empirical attenuation relations for M up to about 7 and for distances greater than about 10–15 km. Motions for larger magnitudes and closer distances are largely driven by extrapolations of empirical relations and uncertainties need to be substantially increased for these cases.

For the Eastern United States (CEUS), due to the paucity of strong motion data for cratonic regions worldwide, estimation of strong ground motions for engineering design is based entirely on calibrated models. The models are usually calibrated and validated in the WUS where sufficient strong motion data are available and then recalibrated for applications to the CEUS. Recalibration generally entails revising parameters based on available CEUS ground motion data as well as indirect inferences through intensity observations. Known differences in model parameters such as crustal structure between WUS and CEUS are generally accommodated as well. These procedures are examined and discussed.  相似文献   

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers     

Axel K Schmitt  Jan M Lindsay  Shan de Silva  Robert B Trumbull 《Journal of Volcanology and Geothermal Research》2003,120(1-2):43-53

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.  相似文献   

Oxygen isotope composition and geothermometry of granulite to greenschist facies metamorphic rocks: a study from the Neoproterozoic collision-related nappe system, south of São Francisco Craton, SE Brazil     

Maria da Glria M. Garcia  Mrio C. Campos Neto  Anthony E. Fallick 《Journal of South American Earth Sciences》2003,15(8):871-883

Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ¹⁸O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ¹⁸O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ¹⁸O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ¹⁸O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ¹⁸O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites.  相似文献   

Early Cretaceous planktonic foraminifera from the Tethys: the large, many-chambered representatives of the genus Globigerinelloides     

D. Verga  I. Premoli Silva 《Cretaceous Research》2003,24(6):661-690

This paper deals with the taxonomic revision of the Early Cretaceous large, many-chambered planispiral planktonic foraminifera, historically assigned to the genus Globigerinelloides or alternatively assigned in the 1990s to the genera Globigerinelloides Cushman and ten Dam, Biglobigerinella Lalicker, Blowiella Krechmar and Gorbachik and Alanlordella BouDagher-Fadel. In a previous paper we demonstrated that the morphological and microstructural features used in the literature for distinguishing Blowiella from Globigerinelloides have value only at species level, and the former genus was thus invalidated (being the junior synonym). Moreover, the Late Aptian specimens assigned to Biglobigerinella by some authors, based on the presence of twin last chamber(s), are also included in Globigerinelloides because individuals sharing the same features (number of chambers, growth rate, size of umbilicus, and a finely perforate wall) may or may not possess twin last chamber(s). Meanwhile, Moullade et al. questioned the taxonomic value of Alanlordella, erected by BouDagher-Fadel to accommodate planispiral taxa possessing a macroperforate wall. All the species analysed here possess a finely perforate wall and consequently cannot be assigned to this taxon.The large species of Globigerinelloides retained here, with six or more chambers in the outer whorl, are G. algerianus Cushman and ten Dam, G. aptiensis Longoria, G. barri (Bolli, Loeblich and Tappan) and G. ferreolensis (Moullade).In the sections studied, Globigerinelloides aptiensis was first found close to the Barremian/Aptian boundary, even though this species was recorded in Spain (Rio Argos) in the mid Upper Barremian; very rare, small, seven-chambered individuals here assigned to Globigerinelloides ferreolensis are recorded in the Lower Aptian (just below and within the Selli Level, OAE1a), while a few specimens belonging to Globigerinelloides barri occur in the Globigerinelloides ferreolensis Zone (Upper Aptian). Globigerinelloides aptiensis and G. ferreolensis range up to the Ticinella bejaouaensis Zone while Globigerinelloides barri disappears at the top of the Globigerinelloides algerianus Zone; finally, Globigerinelloides algerianus obviously spans the eponymous total range zone.From an evolutionary point of view, two lineages within the many-chambered Globigerinelloides have been recognized. In the first, already known in the literature, Globigerinelloides aptiensis gave rise to G. ferreolensis, which evolved into G. algerianus; the latter in turn gave rise to Pseudoplanomalina cheniourensis as the final evolutionary member. In the second lineage Globigerinelloides barri originated from G. blowi.  相似文献